公开(公告)号：US20160248082A1

公开(公告)日：2016-08-25

申请号：US15026195

申请日：2014-09-30

Applicant: THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODY CORPORATE

Inventor： Thomas A. YERSAK ,  Tyler EVANS ,  Se-Hee LEE ,  Justin Michael WHITELEY

IPC: H01M4/36 ,  H01M4/136 ,  H01M10/0525 ,  H01M4/58 ,  H01M10/0562

CPC classification number: H01M4/364 ,  C01B17/22 ,  H01M4/136 ,  H01M4/5815 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0563 ,  H01M2004/028

Abstract: Described herein are various embodiments of methods of making an all-solid-state electrode material for a rechargeable battery comprising in a first mixing step, mixing one of a transition metal phosphide, a transition metal oxide, and a transition metal sulfide with sulfur to produce a first mixture, in a first heat-treating step, heating the first mixture to a temperature ranging between about 250 degrees C. and about 450 degrees C. to produce a heat-treated second mixture comprising an active material and a glass former/electrolyte precursor, in a second mixing step, mixing the second mixture with a glass/electrolyte modifier to produce a third mixture, and permitting the third mixture to react to produce the cathode material, the cathode material comprising the active material and a solid state electrolyte. Electrode materials, electrodes, and batteries made using the foregoing and similar methods are also described.

Abstract translation: 本文描述了制备用于可再充电电池的全固态电极材料的方法的各种实施方案，其包括在第一混合步骤中，将过渡金属磷化物，过渡金属氧化物和过渡金属硫化物中的一种与硫混合以产生 第一混合物，在第一热处理步骤中，将第一混合物加热至约250摄氏度至约450摄氏度的温度，以产生热处理的第二混合物，其包含活性物质和玻璃形成物/电解质 前体，在第二混合步骤中，将第二混合物与玻璃/电解质改性剂混合以产生第三混合物，并允许第三混合物反应以产生阴极材料，阴极材料包含活性材料和固态电解质。 还描述了使用上述方法制造的电极材料，电极和电池。