摘要:
A separator for a nonaqueous electrolyte secondary battery that at least includes a resin (A) having a crosslinked structure, which is obtained by irradiating with an energy ray an oligomer polymerizable by irradiation with an energy ray. The separator has an average pore size of 0.005 to 0.5 μm, an air permeability of 50 sec/100 mL or more and less than 500 sec/100 mL, where the air permeability is expressed as a Gurley value, and a thermal shrinkage of less than 2% at 175° C. The separator for a nonaqueous secondary battery can be produced by the production method of the present invention, which includes the steps of: applying to a substrate a separator forming composition containing the oligomer, two or more kinds of solvents having different polarity from each other, and the like; irradiating the applied composition with an energy ray; and drying the energy ray-irradiated composition.
摘要:
The method for producing a separator for an electrochemical device of the present invention includes: obtaining a separator forming composition, wherein the separator forming composition contains a resin raw material including a monomer or an oligomer, a solvent (a) capable of dissolving the resin raw material; and a solvent (b) capable of causing the resin raw material to agglomerate by solvent shock, and Vsb/Vsa as a ratio between the volume Vsa of the solvent (a) and the volume Vsb of the solvent (b) is 0.04 to 0.2; applying the composition to a substrate; irradiating with energy rays a coating of the applied composition to form a resin (A) having a crosslinked structure; and drying the coating after the formation of the resin (A) to form pores. The separator for an electrochemical device of the present invention is produced by the production method of the present invention.
摘要:
The separator for non-aqueous electrolyte secondary batteries according to the present invention includes at least a resin (A) having a crosslinked structure. The resin having the crosslinked structure is obtained by applying energy rays to at least an oligomer that is capable of being polymerized by irradiation with energy rays, and the resin (A) has a glass transition temperature higher than 0° C. and lower than 80° C. The separator for non-aqueous electrolyte secondary batteries according to the present invention can be produced using a method of the present invention including the steps of applying a separator-forming composition containing an oligomer and a solvent to a base substrate, forming a resin (A) by irradiation with energy rays, and forming pores by drying a coating film after the resin (A) has been formed. Furthermore, the non-aqueous electrolyte secondary battery of the present invention includes the separator for non-aqueous electrolyte secondary batteries according to the present invention.
摘要:
A non-aqueous electrolyte secondary battery of the present invention includes a positive electrode, a negative electrode, and a non-aqueous electrolyte. An insulating layer is provided between the positive electrode and the negative electrode. The insulating layer contains at least one type of hydrogen carbonate selected from a sodium hydrogen carbonate and a potassium hydrogen carbonate. The hydrogen carbonate has an average particle size of 2 to 20 μm. A content of the hydrogen carbonate is 5 to 80 vol % of the total volume of the insulating layer. The insulating layer has a thickness of 4 to 40 μm.
摘要:
A production method for producing a separator for an electrochemical device including the steps of: applying, to a base material, a separator forming composition containing a monomer or an oligomer and a solvent; irradiating the thus formed coating with an energy ray to form a resin (A) having a cross-linked structure; and drying the coating after formation of the resin (A) to form pores, wherein, as a solvent of the separator forming composition, a solvent (a) having a solubility parameter (SP value) of 8.1 or more and less than 8.9 is used, or a solvent (b) having an SP value of 7 or more and 8 or less and a solvent (c) having an SP value of 8.9 or more and 9.9 or less are used in combination. A separator for an electrochemical device produced by the production method, and an electrochemical device of the invention including the separator.
摘要:
An energy ray-curable inkjet ink composition comprising polymerizable compounds containing a monofunctional monomer, (A) a reactive oligomer having a rate of elongation of 130% or more and a weight average molecular weight of not less than 800 and less than 3,000 and (B) a reactive oligomer having a rate of elongation of 130% or more and a weight average molecular weight of not less than 3,000 and not more than 8,000, provided that one of the reactive oligomers (A) and (B) is not more than difunctional and the other is not less than difunctional, at least one polymerization initiator selected from the group consisting of (C) an acylphosphine oxide initiator and (D) an α-aminoalkylphenone initiator, a surface tension modifier, and a colorant.
摘要:
The present invention provides an energy ray-curable inkjet ink composition which is excellent in stretchability for a printed film and, at the same time, is excellent in curability, adherability and the continuous discharge property. The present invention relates to an energy ray-curable inkjet ink composition containing at least a coloring material, 8 to 60% by mass of a monofunctional monomer (A) having a glass transition temperature of lower than −25° C., 25 to 40% by mass of a difunctional oligomer (B) having an elongation rate of 130% or more at 25° C. when a single oligomer is polymerized, at least one kind of a photopolymerization initiator (C) selected from the group consisting of an acylphosphine oxide initiator (C-1), and a mixed initiator (C-2) of an α-aminoalkylphenone initiator and a thioxanthone initiator, and a surface tension conditioner (D).