公开(公告)号：US08097368B2

公开(公告)日：2012-01-17

申请号：US12507228

申请日：2009-07-22

申请人： Takanobu Chiga ,  Hiroyuki Matsumoto ,  Ryo Mogi ,  Osamu Omae ,  Masafumi Kobayashi

发明人： Takanobu Chiga ,  Hiroyuki Matsumoto ,  Ryo Mogi ,  Osamu Omae ,  Masafumi Kobayashi

IPC分类号： H01M10/056

CPC分类号： H01M10/4235 ,  H01M10/052 ,  H01M10/0567

摘要： The present invention provides a non-aqueous electrolyte secondary battery comprising a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte, wherein the non-aqueous electrolyte comprises a non-aqueous solvent and lithium salt as an electrolyte, and wherein the non-aqueous solvent contains chain fluorinated carboxylic acid ester represented by the formula CH3COOCH2CH3-xFx (wherein x is 2 or 3) and a film forming chemical decomposed in the range of +1.0 to 3.0 V based on an equilibrium potential between metal lithium and lithium ion.

摘要翻译： 本发明提供一种非水电解质二次电池，其包含正极，负极，隔膜和非水电解质，其中所述非水电解质包含非水溶剂和作为电解质的锂盐，以及 其中所述非水溶剂含有由式CH3COOCH2CH3-xFx（其中x为2或3）表示的链状氟化羧酸酯，并且成膜化学物质基于金属锂之间的平衡电位在1.0V至3.0V的范围内分解 和锂离子。

公开(公告)号：US20100035162A1

公开(公告)日：2010-02-11

申请号：US12507228

申请日：2009-07-22

申请人： Takanobu Chiga ,  Hiroyuki Matsumoto ,  Ryo Mogi ,  Osamu Omae ,  Masafumi Kobayashi

发明人： Takanobu Chiga ,  Hiroyuki Matsumoto ,  Ryo Mogi ,  Osamu Omae ,  Masafumi Kobayashi

IPC分类号： H01M6/14

CPC分类号： H01M10/4235 ,  H01M10/052 ,  H01M10/0567

摘要： The present invention provides a non-aqueous electrolyte secondary battery comprising a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte, wherein the non-aqueous electrolyte comprises a non-aqueous solvent and lithium salt as an electrolyte, and wherein the non-aqueous solvent contains chain fluorinated carboxylic acid ester represented by the formula CH3COOCH2CH3-xFx (wherein x is 2 or 3) and a film forming chemical decomposed in the range of +1.0 to 3.0 V based on an equilibrium potential between metal lithium and lithium ion.

摘要翻译： 本发明提供一种非水电解质二次电池，其包含正极，负极，隔膜和非水电解质，其中所述非水电解质包含非水溶剂和作为电解质的锂盐，以及 其中所述非水溶剂含有由式CH3COOCH2CH3-xFx（其中x为2或3）表示的链状氟化羧酸酯，并且成膜化学物质基于金属锂之间的平衡电位在1.0V至3.0V的范围内分解 和锂离子。

公开(公告)号：US08945781B2

公开(公告)日：2015-02-03

申请号：US12522231

申请日：2008-02-05

申请人： Takanobu Chiga ,  Keiji Saisho ,  Ryo Mogi ,  Osamu Omae

发明人： Takanobu Chiga ,  Keiji Saisho ,  Ryo Mogi ,  Osamu Omae

IPC分类号： H01M6/16 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M4/131 ,  H01M4/133

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0028 ,  H01M2300/0034 ,  H01M2300/0037 ,  H01M2300/004 ,  Y02E60/122

摘要： The present invention provides a non-aqueous electrolyte secondary battery wherein a reaction between a non-aqueous electrolyte and an electrode is suppressed and decrease in battery capacity under high temperature is restricted, so that long time excellent battery characteristics can be obtained. A non-aqueous solvent of the non-aqueous electrolyte contains: chain fluorinated carboxylic acid ester represented by the formula R1-CH2—COO—R2 where R1 represents hydrogen or alkyl group and R2 represents alkyl group and the sum of the carbon numbers of R1 and R2 is 3 or less, and in the case that R1 is hydrogen, at least one part of hydrogen in R2 is replaced with fluorine, and, in the case that R1 is alkyl group, at least one part of hydrogen in R1 and/or R2 is replaced with fluorine; and a film forming chemical compound decomposed in the range of +1.0 to 3.0 V based on an equilibrium potential between metal lithium and lithium ion.

摘要翻译： 本发明提供了一种非水电解质二次电池，其中非水电解质和电极之间的反应被抑制，并且在高温下的电池容量的降低受到限制，从而可以获得长时间的优异的电池特性。 非水电解质的非水溶剂包含：由式R1-CH2-COO-R2表示的链状氟化羧酸酯，其中R1表示氢或烷基，R2表示烷基，R1的碳数之和 R2为3以下，在R1为氢的情况下，R2中的至少一部分氢被氟代替，在R1为烷基的情况下，R1和/ 或R 2被氟取代; 并且基于金属锂和锂离子之间的平衡电位，在+1.0至3.0V的范围内分解成膜化合物。

公开(公告)号：US20100081062A1

公开(公告)日：2010-04-01

申请号：US12522231

申请日：2008-02-05

申请人： Takanobu Chiga ,  Keiji Saisho ,  Ryo Mogi ,  Osamu Omae

发明人： Takanobu Chiga ,  Keiji Saisho ,  Ryo Mogi ,  Osamu Omae

IPC分类号： H01M2/14 ,  H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0028 ,  H01M2300/0034 ,  H01M2300/0037 ,  H01M2300/004 ,  Y02E60/122

摘要： The present invention provides a non-aqueous electrolyte secondary battery wherein a reaction between a non-aqueous electrolyte and an electrode is suppressed and decrease in battery capacity under high temperature is restricted, so that long time excellent battery characteristics can be obtained. A non-aqueous solvent of the non-aqueous electrolyte contains: chain fluorinated carboxylic acid ester represented by the formula R1-CH2—COO—R2 where R1 represents hydrogen or alkyl group and R2 represents alkyl group and the sum of the carbon numbers of R1 and R2 is 3 or less, and in the case that R1 is hydrogen, at least one part of hydrogen in R2 is replaced with fluorine, and, in the case that R1 is alkyl group, at least one part of hydrogen in R1 and/or R2 is replaced with fluorine; and a film forming chemical compound decomposed in the range of +1.0 to 3.0 V based on an equilibrium potential between metal lithium and lithium ion.

摘要翻译： 本发明提供了一种非水电解质二次电池，其中非水电解质和电极之间的反应被抑制，并且在高温下的电池容量的降低受到限制，从而可以获得长时间的优异的电池特性。 非水电解质的非水溶剂包含：由式R1-CH2-COO-R2表示的链状氟化羧酸酯，其中R1表示氢或烷基，R2表示烷基，R1的碳数之和 R2为3以下，在R1为氢的情况下，R2中的至少一部分氢被氟取代，在R1为烷基的情况下，R1和/ 或R 2被氟取代; 并且基于金属锂和锂离子之间的平衡电位，在+1.0至3.0V的范围内分解成膜化合物。