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公开(公告)号：US4485187A
公开(公告)日：1984-11-27
申请号：US418499
申请日：1982-09-15
申请人： Takeshi Nomura , Kouji Maruyama , Hiroshi Ueno , Naomi Inaba , Makota Yoda
发明人： Takeshi Nomura , Kouji Maruyama , Hiroshi Ueno , Naomi Inaba , Makota Yoda
CPC分类号： C08F10/00
摘要： A catalyst for polymerizing ethylene and .alpha.-olefins and process for producing ethylene polymers which comprises homopolymerizing ethylene or copolymerizing ethylene and other olefins in the presence of a catalyst comprising a catalyst component and an organoaluminum compound, said catalyst component being obtained by mechanically copulverizing (A) a magnesium halide and (B) magnesium hydrocarbyloxide at a molar ratio of B/A=0.5 to 1.5 and subsequently bringing the resulting pulverized product into contact with a tetravalent titanium halide in the presence of a hydrocarbon and/or halogenated hydrocarbon.
摘要翻译： 一种用于聚合乙烯和α-烯烃的催化剂以及用于生产乙烯聚合物的方法，该方法包括在包含催化剂组分和有机铝化合物的催化剂的存在下均聚乙烯或共聚乙烯和其它烯烃，所述催化剂组分通过机械共混（A ）卤化镁和（B）摩尔比为B / A = 0.5至1.5的镁氢氧化镁，随后在烃和/或卤代烃存在下将所得粉碎产物与四价卤化钛接触。
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公开(公告)号：US4485186A
公开(公告)日：1984-11-27
申请号：US418500
申请日：1982-09-15
申请人： Hiroshi Ueno , Tadanao Kohara , Takeshi Nomura , Kouji Maruyama , Naomi Inaba , Makota Yoda
发明人： Hiroshi Ueno , Tadanao Kohara , Takeshi Nomura , Kouji Maruyama , Naomi Inaba , Makota Yoda
CPC分类号： C08F10/00
摘要： A catalyst component for polymerization of olefins which is prepared by bringing a magnesium alkoxide, a halogenated hydrocarbon, and a titanium compound into contact with one another. The catalyst component together with a organoaluminum cocatalyst is used for the polymerization of olefins and especially for the homopolymerization of ethylene and copolymerization of ethylene with an .alpha.-olefin having from 3 to 10 carbon atoms.
摘要翻译： 通过使烷氧基镁，卤代烃和钛化合物彼此接触而制备的烯烃聚合催化剂组分。 催化剂组分与有机铝助催化剂一起用于烯烃的聚合，特别是用于乙烯的均聚和乙烯与具有3至10个碳原子的α-烯烃的共聚。
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公开(公告)号：US4686265A
公开(公告)日：1987-08-11
申请号：US868000
申请日：1986-05-29
申请人： Kouji Maruyama , Takeshi Nomura , Hiroshi Ueno , Naomi Inaba
发明人： Kouji Maruyama , Takeshi Nomura , Hiroshi Ueno , Naomi Inaba
CPC分类号： C08F10/00 , Y10S526/904
摘要： A process for polymerizing one or more alpha-olefins in the presence of a catalyst system comprising (A) a solid titanium containing catalyst component said component prepared by contacting a magnesium alkoxide, a halogenated hydrocarbon, an electron donor and a titanium compound with one another, and (B) an organoaluminum cocatalyst. In preferred embodiments, the magnesium alkoxide is first contacted with a magnesium halide. The solid titanium containing compound can be treated with an organoaluminum compound.
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公开(公告)号：US4613581A
公开(公告)日：1986-09-23
申请号：US768974
申请日：1985-08-23
申请人： Kouji Maruyama , Takeshi Nomura , Hiroshi Ueno , Naomi Inaba
发明人： Kouji Maruyama , Takeshi Nomura , Hiroshi Ueno , Naomi Inaba
CPC分类号： C08F10/00 , Y10S526/904
摘要： A solid titanium containing catalyst component for use in olefin polymerization said component prepared by contacting a magnesium alkoxide, a halogenated hydrocarbon, an electron donor and a titanium compound with one another. In preferred embodiments, the magnesium alkoxide is first contacted with a magnesium halide. The solid titanium containing compound can be treated with an organoaluminum compound.
摘要翻译： 一种用于烯烃聚合的固体含钛催化剂组分，所述组分通过使烷氧基镁，卤代烃，电子给体和钛化合物彼此接触而制备。 在优选的实施方案中，首先将镁醇盐与卤化镁接触。 含钛固体化合物可以用有机铝化合物处理。
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公开(公告)号：US4595735A
公开(公告)日：1986-06-17
申请号：US779179
申请日：1985-09-23
申请人： Takeshi Nomura , Kouji Maruyama , Hiroshi Ueno , Naomi Inaba
发明人： Takeshi Nomura , Kouji Maruyama , Hiroshi Ueno , Naomi Inaba
CPC分类号： C08F10/00
摘要： A catalyst component for the polymerization of olefins and particularly ethylene which is prepared by contacting a contact product of a magnesium alkoxide, a halogenated hydrocarbon, a halogenated silane with a titanium compound. The catalyst component in combination with a organoaluminium cocatalyst is useful for the polymerization of ethylene having a high melt index.
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公开(公告)号：US4544648A
公开(公告)日：1985-10-01
申请号：US615015
申请日：1984-05-29
申请人： Takeshi Nomura , Kouji Maruyama , Hiroshi Ueno , Naomi Inaba
发明人： Takeshi Nomura , Kouji Maruyama , Hiroshi Ueno , Naomi Inaba
CPC分类号： C08F10/00
摘要： A catalyst component for the polymerization of olefins and particularly ethylene which is prepared by contacting a contact product of a magnesium alkoxide, a halogenated hydrocarbon, a halogenated silane with a titanium compound. The catalyst component in combination with a organoaluminum cocatalyst is useful for the polymerization of ethylene having a high melt index.
摘要翻译： 通过使烷氧基镁，卤代烃，卤代硅烷与钛化合物的接触产物接触而制备的用于烯烃，特别是乙烯聚合的催化剂组分。 与有机铝助催化剂组合的催化剂组分可用于具有高熔体指数的乙烯的聚合。
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公开(公告)号：US4711939A
公开(公告)日：1987-12-08
申请号：US924961
申请日：1986-10-30
CPC分类号： C08F10/00
摘要： A catalyst component for polymerization of olefins which is prepared by reacting a magnesium alkoxide with a silicon compound having at least one hydrogen-silicon bond, contacting the reaction product with a carboxylic acid halide and/or carboxylic acid anhydride, and contacting the resulting contact product with a titanium compound.
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公开(公告)号：US4654318A
公开(公告)日：1987-03-31
申请号：US705770
申请日：1985-02-26
CPC分类号： C08F10/00
摘要： A process for preparing a catalyst component for the polymerization of olefins which comprises the steps of contacting (a) a magnesium dialkoxide soluble in an inert solvent, (b) a silicon compound having the hydrogen-silicon bond, and (c) an electron donor compound with one another in the presence of an inert solvent, and contacting the resulting reaction product with (d) a titanium compound.
摘要翻译： 一种制备用于烯烃聚合的催化剂组分的方法，其包括以下步骤：（a）可溶于惰性溶剂的二烷氧基镁，（b）具有氢 - 硅键的硅化合物和（c）电子给体 在惰性溶剂的存在下彼此混合，并使所得反应产物与（d）钛化合物接触。
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公开(公告)号：US4565798A
公开(公告)日：1986-01-21
申请号：US672780
申请日：1984-11-19
CPC分类号： C08F10/00
摘要： A process for polymerizing olefins in the presence of a catalyst composed of:(A) a catalyst component obtained by contacting with one another,(a) a magnesium alkoxide,(b) a silicon compound having a hydrogen-silicon bond,(c) an electron donor compound, and(d) a titanium compound(B) an organic compound of a metal of Groups I and III of the Periodic Table, and(C) an organo silicon compound represented by the formula R.sub.q.sup.9 SiX.sub.g.sup.2 (OR.sup.10).sub.k wherein R.sup.9 and R.sup.10 are the same or different hydrocarbon groups, X.sub.2 is a halogen atom, 0.ltoreq.q
摘要翻译： 一种在催化剂存在下聚合烯烃的方法，该催化剂由以下组成：（A）通过彼此接触获得的催化剂组分，（a）烷醇镁，（b）具有氢 - 硅键的硅化合物，（c） 电子给体化合物和（d）钛化合物（B）元素周期表第I族和第III族金属的有机化合物和（C）由式Rq9SiXg2（OR10）k表示的有机硅化合物，其中R9 R 10为相同或不同的烃基，X2为卤素原子，0
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公开(公告)号：US4321346A
公开(公告)日：1982-03-23
申请号：US111171
申请日：1979-07-20
申请人： Hiroshi Ueno , Naomi Inaba , Tukuo Makishima , Koh Watanabe , Shozo Wada
发明人： Hiroshi Ueno , Naomi Inaba , Tukuo Makishima , Koh Watanabe , Shozo Wada
CPC分类号： C08F10/00
摘要： A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an organo-metal compound and then treating the resulting reduced solids product with a chlorinated saturated hydrocarbon having two carbon atoms in the presence of a complexing agent. The resulting titanium trichloride complex composition, when employed as a co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.
摘要翻译： 通过用有机金属化合物还原四氯化钛然后在络合剂存在下用具有两个碳原子的氯化饱和烃处理所得的还原固体产物来制备三氯化钛催化络合物。 所得到的三氯化钛复合物组合物当用作α-烯烃聚合中的齐格勒型催化剂的有机金属化合物的助催化剂时，导致均匀的聚合物颗粒具有意想不到的高聚合活性和高立体规则聚合物产率。
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