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公开(公告)号：US06305622B1
公开(公告)日：2001-10-23
申请号：US09254781
申请日：1999-03-08
申请人： Tetsuya Iwao , Tadao Nishida , Kaoru Kawanishi , Seijiro Koga
发明人： Tetsuya Iwao , Tadao Nishida , Kaoru Kawanishi , Seijiro Koga
IPC分类号： B02C1912
CPC分类号： C07F5/062
摘要： A trihydrocarbyl aluminum is produced at a high yield by reacting an aluminum-magnesium alloy powder with a halogenated hydrocarbon. Prior to the reaction, the alloy powder is obtained by grinding treatment using a ball mill or a vibration ball mill. The reaction is conducted with agitation in the presence of abrasive particles or is conducted using a homogenizer without abrasive particles.
摘要翻译： 通过使铝镁合金粉末与卤代烃反应，以高产率生产三烃基铝。 在反应之前，通过使用球磨机或振动球磨机的研磨处理获得合金粉末。 反应在磨料颗粒存在下搅拌进行，或者使用没有磨料颗粒的均化器进行。
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2.发明授权
公开(公告)号：US5112991A
公开(公告)日：1992-05-12
申请号：US465160
申请日：1990-02-16
申请人： Tetsuya Iwao , Shuichi Osaka , Takao Sakaki , Tadao Nishida , Kiyoshi Yamamura , Seijiro Koga , Reiji Hirai , Haruo Nakagawa
发明人： Tetsuya Iwao , Shuichi Osaka , Takao Sakaki , Tadao Nishida , Kiyoshi Yamamura , Seijiro Koga , Reiji Hirai , Haruo Nakagawa
摘要： A process is provided herein for preparing an organo-substituted sodium aluminum hydride by reacting sodium, aluminum, an organic compound of specific structure containing a hydroxyl group and hydrogen.In such process, an aluminum alloy is used as the aluminum.
摘要翻译： PCT No.PCT / JP89 / 01116 Sec。 371日期1990年2月16日 102（e）日期1990年2月16日PCT提交1989年10月30日PCT公布。 出版物WO90 / 05128 日本1990年5月17日。本文提供了通过使钠，铝，含羟基和氢的特定结构的有机化合物反应制备有机取代的氢化铝钠的方法。 在这种方法中，使用铝合金作为铝。
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公开(公告)号：US08110694B2
公开(公告)日：2012-02-07
申请号：US12809363
申请日：2009-05-07
CPC分类号： C07F5/064
摘要： A method for manufacturing dialkylaluminum monohalide is provided by which dialkylaluminum monohalide substantially including no zinc component after recovering dialkylzinc from a reaction product obtained by a reaction of zinc halide and trialkylaluminum used as raw materials can be efficiently obtained on an industrial scale at a high yield. According to the method for manufacturing dialkylaluminum monohalide of the present invention, zinc halide is reacted with trialkylaluminum to produce dialkylzinc and dialkylaluminum monohalide, and after the dialkylzinc is separated from a reaction product by distillation, metal aluminum in which a molar ratio is 0.40 or more to zinc component, that is dissolved in the reaction product, and then the mixture is distilled to separate the dialkylaluminum monohalide which substantially includes no zinc component.
摘要翻译： 提供一卤化二烷基铝的制备方法，其中通过卤化锌和作为原料的三烷基铝的反应获得的反应产物中回收二烷基锌后，基本上不含锌成分的二卤化二烷基铝可以以高产率以工业规模得到。 根据本发明的二烷基铝一卤化物的制造方法，使卤化锌与三烷基铝反应生成二烷基锌和二卤化二烷基铝卤化物，二烷基锌通过蒸馏与反应产物分离后，摩尔比为0.40以上的金属铝 溶解在反应产物中的锌组分，然后将混合物蒸馏以分离基本上不含锌组分的二卤化二烷基铝。
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公开(公告)号：US20110021800A1
公开(公告)日：2011-01-27
申请号：US12809363
申请日：2009-05-07
IPC分类号： C07F5/06
CPC分类号： C07F5/064
摘要： A method for manufacturing dialkylaluminum monohalide is provided by which dialkylaluminum monohalide substantially including no zinc component after recovering dialkylzinc from a reaction product obtained by a reaction of zinc halide and trialkylaluminum used as raw materials can be efficiently obtained on an industrial scale at a high yield. According to the method for manufacturing dialkylaluminum monohalide of the present invention, zinc halide is reacted with trialkylaluminum to produce dialkylzinc and dialkylaluminum monohalide, and after the dialkylzinc is separated from a reaction product by distillation, metal aluminum in which a molar ratio is 0.40 or more to zinc component, that is dissolved in the reaction product, and then the mixture is distilled to separate the dialkylaluminum monohalide which substantially includes no zinc component.
摘要翻译： 提供一卤化二烷基铝的制备方法，其中通过卤化锌和作为原料的三烷基铝的反应获得的反应产物中回收二烷基锌后，基本上不含锌成分的二卤化二烷基铝可以以高产率以工业规模得到。 根据本发明的二烷基铝一卤化物的制造方法，使卤化锌与三烷基铝反应生成二烷基锌和二卤化二烷基铝卤化物，二烷基锌通过蒸馏与反应产物分离后，摩尔比为0.40以上的金属铝 溶解在反应产物中的锌组分，然后将混合物蒸馏以分离基本上不含锌组分的二卤化二烷基铝。
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公开(公告)号：US08236981B2
公开(公告)日：2012-08-07
申请号：US12990380
申请日：2009-04-30
摘要： A method for manufacturing dialkylzinc and dialkylaluminum monohalide that makes it possible to efficiently manufacture both dialkylzinc and dialkylaluminum monohalide of high purity and at a high yield on an industrial scale with a single reaction from zinc halide and trialkylaluminum as raw materials, while suppressing the production of precipitants in the reaction process and suppressing the adhesion of precipitates to the equipment and the admixture thereof into the product. The method for manufacturing dialkylzinc and dialkylaluminum monohalide by reacting zinc halide with trialkylaluminum, includes using trialkylaluminum with a hydride concentration of 0.01% by mass to 0.10% by mass, and separating dialkylzinc essentially not containing aluminum from reactants and then separating dialkylaluminum monohalide essentially not containing zinc.
摘要翻译： 二卤化锌和一卤化二烷基铝的制备方法，其可以以卤化锌和三烷基铝为原料的单一反应，以工业规模有效地制造高纯度的二烷基锌和一卤化二烷基铝，同时抑制 反应过程中的沉淀剂，并且抑制沉淀物对设备的粘附以及其与产物的混合物。 通过使卤化锌与三烷基铝反应制备二烷基锌和二烷基铝一卤化物的方法包括使用氢化物浓度为0.01质量％至0.10质量％的三烷基铝，并从反应物中分离出基本上不含有铝的二烷基锌，然后分离基本上不含 锌。
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公开(公告)号：US20110054206A1
公开(公告)日：2011-03-03
申请号：US12990380
申请日：2009-04-30
摘要： The present invention is to provide a method for manufacturing dialkylzinc and dialkylaluminum monohalide that makes it possible to efficiently manufacture both dialkylzinc and dialkylaluminum monohalide of high purity and at a high yield on an industrial scale with a single reaction from zinc halide and trialkylaluminum as raw materials, while suppressing the production of precipitants in the reaction process and suppressing the adhesion of precipitates to the equipment and the admixture thereof into the product.The method for manufacturing dialkylzinc and dialkylaluminum monohalide by reacting zinc halide with trialkylaluminum, comprising: using trialkylaluminum with a hydride concentration of 0.01% by mass to 0.10% by mass, and separating dialkylzinc essentially not containing aluminum from reactants and then separating dialkylaluminum monohalide essentially not containing zinc.
摘要翻译： 本发明提供一种制备二烷基锌和一卤化二烷基铝的方法，其使得可以从卤化锌和三烷基铝作为原料的单一反应以工业规模有效地制备高纯度的二烷基锌和二卤化二烷基铝一卤化物 同时抑制反应过程中沉淀剂的产生并抑制沉淀物对设备的粘附及其与产物的混合。 通过使卤化锌与三烷基铝反应制备二烷基锌和二烷基铝一卤化物的方法，包括：使用氢化物浓度为0.01质量％至0.10质量％的三烷基铝，并将基本上不含有铝的二烷基锌从反应物中分离出来， 含锌。
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