公开(公告)号：US4886895A

公开(公告)日：1989-12-12

申请号：US306113

申请日：1989-02-06

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/09 ,  C07F9/40 ,  C08K5/521 ,  C08K5/5333 ,  D06M13/292

CPC分类号： D06M13/292 ,  C07F9/091 ,  C07F9/093 ,  C07F9/4006 ,  C08K5/521 ,  C08K5/5333 ,  C23F11/1673

摘要： There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.

摘要翻译： 公开了包含含膦酸酯或磷酸酯的磷酸酯的含有多磷的化合物。 化合物可以通过以下方法制备：（a）通过与环氧化物反应，使含膦酸酯或含磷酸酯的醇与五氧化二磷反应，（b）使含膦酸酯或含磷酸盐的醇与磷酰卤反应，将任何 磷卤素键，然后使所得磷酸衍生物与环氧化物反应，（c）将含膦酸酯或含磷酸酯的醇与亚磷酸二烷基酯酯交换，氧化所得化合物以产生磷酸衍生物，并使磷酸衍生物与 环氧化物。 该化合物可用作聚氨酯和纺织品的阻燃添加剂。

公开(公告)号：US4292036A

公开(公告)日：1981-09-29

申请号：US146582

申请日：1980-05-05

申请人： Edward N. Walsh ,  Thomas A. Hardy

发明人： Edward N. Walsh ,  Thomas A. Hardy

IPC分类号： C07F9/09 ,  D06M13/292 ,  C07F9/11 ,  C07F9/40 ,  D06M1/00 ,  D06M13/34

CPC分类号： D06M13/292 ,  C07F9/091

摘要： Flame retardance is imparted to textile materials by impregnating them with a flame retardant composition comprising(a) at least one compound represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of aryl, arylalkyl, alkylaryl, alkenyl and alkyl having from 1 to about 6 carbon atoms and ##STR2## R.sup.3 represents an alkylene group having from 1 to about 5 carbon atoms, and R.sup.4 and R.sup.5 are each independently selected from the group consisting of hydrogen, ##STR3## wherein R.sup.6 represents an alkyl group having from 1 to about 4 carbon atoms; provided that not all of said R.sup.4 's and R.sup.5 's are --CH.sub.3 at the same time:(b) an aminoplast; and(c) an acid catalyst; and heating the impregnated textile material sufficiently to cure said flame retardant composition.

摘要翻译： 通过用阻燃组合物浸渍它们来赋予纺织材料阻燃性，所述阻燃组合物包含（a）至少一种由下式表示的化合物：其中R 1和R 2各自独立地选自芳基，芳基烷基，烷基芳基，烯基 和具有1至约6个碳原子的烷基，并且R 3代表具有1至约5个碳原子的亚烷基，且R 4和R 5各自独立地选自氢，其中R 6表示 具有1至约4个碳原子的烷基; 条件是并不是所有的R 4和R 5都是同时的-CH 3：（b）氨基塑料; 和（c）酸催化剂; 并充分加热浸渍的纺织材料以固化所述阻燃组合物。

公开(公告)号：US4883892A

公开(公告)日：1989-11-28

申请号：US260342

申请日：1988-10-20

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/40 ,  C08K5/5333

CPC分类号： C08K5/5333 ,  C07F9/4006 ,  C07F9/4075

摘要： There are disclosed novel phosphorous-containing compounds including and derived from hydrogen phosphonates. The compounds of the present invention can be prepared by reacting a hydrogen phosphonate with: (a) an ethylene derivative in a Michael reaction, (b) an amine or amide and formaldehyde in a Mannich reaction, (c) an aldehyde or ketone, (d) a halogen, (e) carbon tetrachloride and an alkylamine, and (f) carbon tetrachloride and a hydroxyphosphonate. Halophosphonates produced according to procedure (d) can also be used in reactions with (a) alkylamines and (b) hydroxyphosphonates or epoxides to produce the compounds of the present invention.

摘要翻译： 公开了包括并衍生自氢膦酸盐的新颖的含磷化合物。 本发明的化合物可以通过使膦酸氢钾与（a）迈克尔反应中的乙烯衍生物，（b）曼尼希反应中的胺或酰胺和甲醛反应制得，（c）醛或酮（ d）卤素，（e）四氯化碳和烷基胺，和（f）四氯化碳和羟基膦酸盐。 根据方法（d）制备的卤代膦酸盐也可用于与（a）烷基胺和（b）羟基膦酸酯或环氧化物的反应中，以产生本发明的化合物。

公开(公告)号：US4883891A

公开(公告)日：1989-11-28

申请号：US258536

申请日：1988-10-17

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/40 ,  C08K5/5333

CPC分类号： C08K5/5333 ,  C07F9/4006 ,  C07F9/4075

摘要： There are disclosed novel phosphorous-containing compounds including and derived from hydrogen phosphonates. The compounds of the present invention can be prepared by reacting a hydrogen phosphonate with: (a) an ethylene derivative in a Michael reaction, (b) an amine or amide and formaldehyde in a Mannich reaction, (c) an aldehyde or ketone, (d) a halogen, (e) carbon tetrachloride and an alkylamine, and (f) carbon tetrachloride and a hydroxyphosphate. Halophosphonates produced according to procedure (d) can also be used in reactions with (a) alkylamines and (b) hydroxyphosphonates or epoxides to produce the compounds of the present invention.

摘要翻译： 公开了包括并衍生自氢膦酸盐的新颖的含磷化合物。 本发明的化合物可以通过使膦酸氢钾与（a）迈克尔反应中的乙烯衍生物，（b）曼尼希反应中的胺或酰胺和甲醛反应制得，（c）醛或酮（ d）卤素，（e）四氯化碳和烷基胺，和（f）四氯化碳和羟基磷酸酯。 根据方法（d）制备的卤代膦酸盐也可用于与（a）烷基胺和（b）羟基膦酸酯或环氧化物的反应中，以产生本发明的化合物。

公开(公告)号：US4808744A

公开(公告)日：1989-02-28

申请号：US20829

申请日：1987-03-02

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/40 ,  C08K5/5333

CPC分类号： C08K5/5333 ,  C07F9/4006 ,  C07F9/4075

摘要： There are disclosed novel phosphorus-containing compounds including and derived from hydrogen phosphonates. The compounds of the present invention can be prepared by reacting a hydrogen phosphonate with: (a) an ethylene derivative in a Michael reaction, (b) an amine or amide and formaldehyde in a Mannich reaction, (c) an aldehyde or ketone, (d) a halogen, (e) carbon tetrachloride and an alkylamine, and (f) carbon tetrachloride and a hydroxyphosphonate. Halophosphonates produced according to procedure (d) can also be used in reactions with (a) alkylamines and (b) hydroxyphosphonates or epoxides to produce the compounds of the present invention.

摘要翻译： 公开了包含并衍生自氢化膦酸盐的新型含磷化合物。 本发明的化合物可以通过使膦酸氢钾与（a）迈克尔反应中的乙烯衍生物，（b）曼尼希反应中的胺或酰胺和甲醛反应制得，（c）醛或酮（ d）卤素，（e）四氯化碳和烷基胺，和（f）四氯化碳和羟基膦酸盐。 根据方法（d）制备的卤代膦酸盐也可用于与（a）烷基胺和（b）羟基膦酸酯或环氧化物的反应中，以产生本发明的化合物。

公开(公告)号：US4697030A

公开(公告)日：1987-09-29

申请号：US737374

申请日：1985-05-23

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/09 ,  C07F9/40 ,  C08K5/521 ,  C08K5/5333 ,  D06M13/292 ,  C07F9/11

CPC分类号： D06M13/292 ,  C07F9/091 ,  C07F9/093 ,  C07F9/4006 ,  C08K5/521 ,  C08K5/5333

摘要： There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.

摘要翻译： 公开了包含含膦酸酯或磷酸酯的磷酸酯的含有多磷的化合物。 化合物可以通过以下方法制备：（a）通过与环氧化物反应，使含膦酸酯或含磷酸酯的醇与五氧化二磷反应，（b）使含膦酸酯或含磷酸盐的醇与磷酰卤反应，将任何 磷卤素键，然后使所得磷酸衍生物与环氧化物反应，（c）将含膦酸酯或含磷酸酯的醇与亚磷酸二烷基酯酯交换，氧化所得化合物以产生磷酸衍生物，并使磷酸衍生物与 环氧化物。 该化合物可用作聚氨酯和纺织品的阻燃添加剂。

公开(公告)号：US5117033A

公开(公告)日：1992-05-26

申请号：US606668

申请日：1990-10-31

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/09 ,  C07F9/40 ,  C08K5/521 ,  C08K5/5333 ,  D06M13/292

CPC分类号： D06M13/292 ,  C07F9/091 ,  C07F9/093 ,  C07F9/4006 ,  C08K5/521 ,  C08K5/5333

摘要： There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting with the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.

摘要翻译： 公开了包含含膦酸酯或磷酸酯的磷酸酯的含有多磷的化合物。 化合物可以通过以下方法制备：（a）通过与环氧化物反应，使含膦酸酯或含磷酸酯的醇与五氧化二磷反应，（b）使含膦酸酯或含磷酸盐的醇与磷酰卤反应，将任何 磷卤素键，然后与得到的磷酸衍生物与环氧化物反应，（c）使含膦酸酯或含磷酸酯的醇与亚磷酸二烷基酯酯交换，氧化所得化合物以产生磷酸衍生物，并使磷酸衍生物 与环氧化物。 该化合物可用作聚氨酯和纺织品的阻燃添加剂。

公开(公告)号：US5097057A

公开(公告)日：1992-03-17

申请号：US414781

申请日：1989-09-29

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/40 ,  C08K5/5333

CPC分类号： C08K5/5333 ,  C07F9/4006 ,  C07F9/4075

摘要： There are disclosed novel phosphorus-containing compounds including and derived from hydrogen phosphonates. The compounds of the present invention can be prepared by reacting a hydrogen phosphonate with: (a) an ethylene derivative in a Michael reaction, (b) an amine or amide and formaldehyde in a Mannich reaction, (c) an aldehyde or ketone, (d) a halogen, (e) carbon tetrachloride and an alkylamine, and (f) carbon tetrachloride and a hydroxyphosphonate. Halophosphonates produced according to procedure (d) can also be used in reactions with (a) alkylamines and (b) hydroxyphosphonates or epoxides to produce the compounds of the present invention.

摘要翻译： 公开了包含并衍生自氢化膦酸盐的新型含磷化合物。 本发明的化合物可以通过使膦酸氢钾与（a）迈克尔反应中的乙烯衍生物，（b）曼尼希反应中的胺或酰胺和甲醛反应制得，（c）醛或酮（ d）卤素，（e）四氯化碳和烷基胺，和（f）四氯化碳和羟基膦酸盐。 根据方法（d）制备的卤代膦酸盐也可用于与（a）烷基胺和（b）羟基膦酸酯或环氧化物的反应中，以产生本发明的化合物。

公开(公告)号：US4820854A

公开(公告)日：1989-04-11

申请号：US66664

申请日：1987-06-26

申请人： Thomas A. Hardy ,  Edward N. Walsh

发明人： Thomas A. Hardy ,  Edward N. Walsh

IPC分类号： C07F9/09 ,  C07F9/40 ,  C08K5/521 ,  C08K5/5333 ,  D06M13/292

CPC分类号： D06M13/292 ,  C07F9/091 ,  C07F9/093 ,  C07F9/4006 ,  C08K5/521 ,  C08K5/5333 ,  C23F11/1673

摘要： There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.

公开(公告)号：US4093651A

公开(公告)日：1978-06-06

申请号：US753119

申请日：1976-12-22

申请人： Milton L. Honig ,  Carl C. Greco ,  Edward N. Walsh

发明人： Milton L. Honig ,  Carl C. Greco ,  Edward N. Walsh

IPC分类号： C07C313/08 ,  C07C145/00

CPC分类号： C07C313/08

摘要： A method for improving the yield of perchloromethyl mercaptan by including in the reaction mixture phosphonates or phosphonites, in amounts effective to suppress the formation of undesirable byproducts, such as carbon tetrachloride and sulfur monochloride.

摘要翻译： 通过在反应混合物中包含膦酸盐或亚膦酸盐来提高全氯甲基硫醇的产率的方法，其用量有效地抑制不希望的副产物如四氯化碳和一氯化硫的形成。