公开(公告)号：US11884616B2

公开(公告)日：2024-01-30

申请号：US17936988

申请日：2022-09-30

Applicant: UOP LLC

Inventor： Bryan J. Egolf ,  Christopher D. DiGiulio ,  William Yanez ,  Ka L. Lok ,  Elie J. Fayad ,  Haibo Yu ,  Kristen E. Allaire ,  Falaah Falih ,  Jeffrey R. Grott ,  Sujay R. Krishnamurthy ,  Hari S. Bajpai ,  Phillip F. Daly ,  Matthew R. Zuraski ,  Hosoo Lim ,  Joseph Peterson ,  Michael R. Van de Cotte ,  Steven A. Bradley

IPC: C07C5/333 ,  B01J19/18

CPC classification number: C07C5/333 ,  B01J19/1862 ,  B01J2219/0004 ,  B01J2219/00058 ,  B01J2219/00065 ,  C07C2527/02

Abstract: Processes and apparatus for reforming hydrocarbons to reduce the impact of contaminants created by non-catalyst coking. The reaction zone receives sulfur to inhibit the impact, and a control index is used to control the determine conditions with generally lower pressures. Additionally, a compression zone, pressure control zone and combustion zone operation are provided for the operation of the reaction zone at the generally lower pressures.

公开(公告)号：US20240109856A1

公开(公告)日：2024-04-04

申请号：US18469102

申请日：2023-09-18

Applicant: UOP LLC

Inventor： Kristen E. Allaire ,  Veronica G. Deak ,  Yili Shi ,  Joel T. Walenga

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: An integrated process for making furan-2,5-dicarboxylic acid (FDCA) and FDCA derivatives combines a furfural oxidation reaction, an intermediate water removal step, and a furoate salt carboxylation reaction. A furfural feed stream is oxidized with an alkaline solution in the presence of a catalyst and excess base with air as the oxidant. The resulting furoate solution from the first process step is dried to remove water. The anhydrous solid products are sent to a carboxylation process to produce FDCA salt, which can optionally be further reacted to form FDCA or FDCA ester.

公开(公告)号：US20240217940A1

公开(公告)日：2024-07-04

申请号：US18506347

申请日：2023-11-10

Applicant: UOP LLC

Inventor： Yili Shi ,  Veronica G. Deak ,  Kristen E. Allaire ,  Joel T. Walenga

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: Processes for producing biomonomers and precursors for same with a slurry-phase reaction. A furoate carboxylation reaction is conducted within a hydrocarbon slurry which includes carbon dioxide. The reaction produces dicarboxylates which can be separated from the slurry and used to produce biomonomers like furan dicarboxylate methyl ester and furan dicarboxylic acid.

公开(公告)号：US20240217910A1

公开(公告)日：2024-07-04

申请号：US18506340

申请日：2023-11-10

Applicant: UOP LLC

Inventor： Yili Shi ,  Veronica G. Deak ,  Kristen E. Allaire ,  Joel T. Walenga

IPC: C07C51/15 ,  C07C51/42

CPC classification number: C07C51/15 ,  C07C51/42

Abstract: Processes for producing biomonomers and precursors for producing same. A carboxylation reaction is conducted between an aromatic hydrocarbon, such as a furoate, and a dicarboxylated alkali salt. The reaction produces a carboxylated aromatic hydrocarbon and a decarboxylated alkali salt. The carboxylated aromatic hydrocarbon can be separated and used to produce biomonomers like furan dicarboxylate methyl ester and furan dicarboxylic acid. The decarboxylated alkali salt may be regenerated.

公开(公告)号：US20240217939A1

公开(公告)日：2024-07-04

申请号：US18506342

申请日：2023-11-10

Applicant: UOP LLC

Inventor： Yili Shi ,  Veronica G. Deak ,  Kristen E. Allaire ,  Joel T. Walenga

IPC: C07D307/68

CPC classification number: C07D307/68 ,  B01J2/06

Abstract: Processes for producing biomonomers and precursors for same. A furoate carboxylation reaction is conducted with particles formed from furoates and an alkali base and optionally a reaction promoter. The particles may be in a slurry. The parties are exposed to gaseous carbon dioxide and heated. The reaction produces dicarboxylates which can be separated and used to produce biomonomers like furan dicarboxylate methyl ester and furan dicarboxylic acid.

公开(公告)号：US20230212095A1

公开(公告)日：2023-07-06

申请号：US17936988

申请日：2022-09-30

Applicant: UOP LLC

Inventor： Bryan J. Egolf ,  Christopher D. DiGiulio ,  William Yanez ,  Ka L. Lok ,  Elie J. Fayad ,  Haibo Yu ,  Kristen E. Allaire ,  Falaah Falih ,  Jeffrey R. Grott ,  Sujay R. Krishnamurthy ,  Hari S. Bajpai ,  Phillip F. Daly ,  Matthew R. Zuraski ,  Hosoo Lim ,  Joseph Peterson ,  Michael R. Van de Cotte ,  Steven A. Bradley

IPC: C07C5/333 ,  B01J19/18

CPC classification number: C07C5/333 ,  B01J19/1862 ,  C07C2527/02 ,  B01J2219/0004 ,  B01J2219/00065 ,  B01J2219/00058

Abstract: Processes and apparatus for reforming hydrocarbons to reduce the impact of contaminants created by non-catalyst coking. The reaction zone receives sulfur to inhibit the impact, and a control index is used to control the determine conditions with generally lower pressures. Additionally, a compression zone, pressure control zone and combustion zone operation are provided for the operation of the reaction zone at the generally lower pressures.