ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20250163317A1

    公开(公告)日:2025-05-22

    申请号:US18768289

    申请日:2024-07-10

    Abstract: A compound of Formula I, is provided. In Formula I, moiety A is a monocyclic ring or a polycyclic fused ring system; each of X1 to X2 and Z1 to Z3 is independently C or N; Y1 is C, N, O, S, Se, P, or As; K is a direct bond or a linker; each of A1 and A2 is C, Si, N, P, or As; each of L1, L2, and L3 is absent, a direct bond, or a linker; at least one of L1 to L4 is present; when L3 is present, X11 is C, whereas if L3 is absent, X11 is C or N; M is Pt or Pd; each R1, R2, RA, RB, RC, RD, Rα, and Rβ is hydrogen or a General Substituent defined herein and R* is a General Substituent defined herein. Formulations, OLEDs, and consumer products containing the compound are also provided.

    Organic Electroluminescent Materials and Devices

    公开(公告)号:US20210384449A1

    公开(公告)日:2021-12-09

    申请号:US17398619

    申请日:2021-08-10

    Abstract: A compound comprising a hexadentate ligand of Formula I coordinated to a metal selected from the group consisting of iridium, rhodium, and osmium; wherein rings A, B, C, D, E, and F are independently a 5-membered or 6-membered heteroaryl ring, or a 6-membered aryl ring; T1, T2, T3, T4, T5, and T6 are independently selected from C or N, wherein two to four of T1 to T6 are C, and two to four of T1 to T6 are N; Z1, Z2, Z3, and Z4 are independently selected from C or N, wherein if Z1 and Z2 are each N then T1 is a carbene carbon and two of T2 to T6 are N; Y1 and Y2 are independently selected from the group consisting of CR, SiR, B, or N; W1-W7 are independently selected from the group consisting of a direct bond, BR, BRR′, NR, PR, O, S, Se, C═X, S═O, SO2, CR, CRR′, SiRR′, GeRR′, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof; wherein X is selected from the group consisting of O, S, Se, NR′, and CR″R′″; RA to RF independently represent mono to the maximum allowable substitution, or no substitution; each R, R′, R″, R′″, and RA to RF is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, boryl, arylalkyl, alkoxy, aryloxy, amino, silyl, germyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, selenyl, and combinations thereof, and any two adjacent substituents R, R′, R″, R′″, and RA to RF are optionally joined to form a fused ring.

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