公开(公告)号：US08889879B2

公开(公告)日：2014-11-18

申请号：US13872544

申请日：2013-04-29

Applicant: University of Florida Research Foundation, Inc.

Inventor： Adam Steven Veige ,  Trevor Del Castillo ,  Leslie Justin Murray ,  Xi Yang ,  Andrew R. Powers

IPC: C07F1/12 ,  C07F9/50

CPC classification number: C07F1/12 ,  C07F9/5045

Abstract: Embodiments of the invention are directed to bimetallic substituted triazole compounds and methods to prepare the compounds. The compounds include at least one 1,2,3-triazole that is substituted by two metal ions at the 1 and 4 or 5 positions of the triazole ring. An iClick reaction between a metal acetylide and a metal azide results in the bimetallic substituted triazole ring. Depending on the metal acetylide and the metal azide used, monomeric bimetallic substituted triazole compounds, oligomeric bimetallic triazole compounds, or polymeric bimetallic triazole compounds are formed. Polymeric bimetallic triazole compounds can be linear, branched, ladder, two-dimensional network, or three-dimensional networks.

Abstract translation: 本发明的实施方案涉及双金属取代的三唑化合物和制备化合物的方法。 所述化合物包括在三唑环的1和4或5位被两个金属离子取代的至少一个1,2,3-三唑。 金属乙炔化物和金属叠氮化物之间的iClick反应导致双金属取代的三唑环。 根据金属乙炔化物和所用的金属叠氮化物，形成单体双金属取代的三唑化合物，低聚双金属三唑化合物或聚合双金属三唑化合物。 聚合双金属三唑化合物可以是直链，支链，梯子，二维网络或三维网络。