-
公开(公告)号：US4623525A
公开(公告)日：1986-11-18
申请号：US689110
申请日：1985-01-07
IPC分类号： C01B21/098 , C01B25/10
CPC分类号： C01B21/0986
摘要： The present invention relates to the stabilization against water of solutions of poly(dichlorophosphazene) through the utilization of water reacting complexes of substituted silicon, tin, germanium or titanium chlorides which are complexed with a tertiary amine base.
摘要翻译： 本发明涉及通过利用与叔胺碱络合的取代硅，锡，锗或氯化钛的水反应配合物来稳定聚（二氯膦腈）溶液的水分。
-
2.发明授权Polyphosphazene polymers containing substituted alkyl/cycloalkyl substituents 失效含有取代烷基/环烷基取代基的聚磷腈聚合物
公开(公告)号：US4258171A
公开(公告)日：1981-03-24
申请号：US71899
申请日：1979-09-04
CPC分类号： C08G73/00
摘要： Polyphosphazene polymers are prepared which contain repeating units represented by the formulas: ##STR1## wherein X and X' are the same or different and are represented by: ##STR2## wherein R.sub.1-4 are independently selected from the group consisting of hydrogen, halogen, nitro, cyano, alkylmercapto, arylmercapto, dialkylamine, alkyl, aryl, alkoxy, aryloxy and heterocyclic radicals or R.sub.1 and R.sub.3 when taken together can form a cycloalkyl or heterocyclic ring; X' can also be selected from a group consisting of chloro radicals, substituted or unsubstituted alkoxy, aryloxy, amino and mercapto radicals or mixtures thereof; and 20.ltoreq.(w+y+z).ltoreq.50,000 per polymer.The polymers of the invention can be utilized to form protective films and can also be utilized in applications such as for molding, coatings, foams and the like.
摘要翻译： 制备聚磷腈聚合物，其含有由下式表示的重复单元：其中X和X'相同或不同，并由下式表示：其中R1-4独立地选自氢，卤素， 硝基，氰基，烷基巯基，芳基巯基，二烷基胺，烷基，芳基，烷氧基，芳氧基和杂环基团或R 1和R 3一起可以形成环烷基或杂环; X'还可以选自氯基，取代或未取代的烷氧基，芳氧基，氨基和巯基或其混合物; 和20（=（w + y + z））/ 50,000。 本发明的聚合物可用于形成保护膜，也可用于成型，涂料，泡沫等应用。
-
公开(公告)号：US4247679A
公开(公告)日：1981-01-27
申请号：US941103
申请日：1978-09-08
CPC分类号： C08G79/025
摘要： Polyphosphazene copolymers are prepared which contain units represented by the formulas: ##STR1## wherein X is --OR'RC--C.uparw.CH in which R and R' are hydrogen or alkyl groups containing from 1 to 6 carbon atoms; wherein X' is selected from the group consisting of substituted and unsubstituted alkoxy, aryloxy, amino and mercapto groups and wherein 20.ltoreq.(a+b+c).ltoreq.50,000 per polymer.The copolymers of the invention can be utilized to form protective films and may also be utilized in applications such as moldings, coatings and the like.
摘要翻译： 制备聚磷腈共聚物，其含有由下式表示的单元：其中X是-OR'RC-C＆uarr＆CH，其中R和R'是氢或含有1至6个碳原子的烷基; 其中X'选自取代和未取代的烷氧基，芳氧基，氨基和巯基，并且其中每个聚合物20（a + b + c）= 50,000。 本发明的共聚物可用于形成保护膜，也可用于诸如模制品，涂料等的应用中。
-
4.发明授权Polyphosphazene copolymers containing substituents derived from substituted 2-nitroethanols 失效含有取代的2-硝基乙醇的取代基的聚磷腈共聚物
公开(公告)号：US4221900A
公开(公告)日：1980-09-09
申请号：US12620
申请日：1979-02-16
CPC分类号： C08G79/025
摘要： Polyphosphazene polymers are prepared which contain units represented by the formulas: ##STR1## wherein X is ##STR2## in which R and R.sub.1 are selected from the group consisting of alkyl groups containing from 1 to 12 carbon atoms, cycloalkyl groups containing from 3 to 12 carbon atoms and aryl groups wherein X' is selected from the group consisting of substituted or unsubstituted alkoxy, aryloxy, amino and mercapto groups and wherein .ltoreq.20(a+b+c).ltoreq.50,000 per polymer.The copolymers of the invention can be utilized to form films and may also be utilized in applications such as moldings, coatings, foams and the like.
摘要翻译： 制备含有由下式表示的单元的聚磷腈聚合物：其中X为
，其中R和R 1选自含有1至12个碳原子的烷基，含有3至12个碳原子的环烷基 碳原子和芳基，其中X'选自取代或未取代的烷氧基，芳氧基，氨基和巯基，并且其中每个聚合物 -
5.发明授权Polyphosphazene polymers containing N-substituted amido and imido substituents 失效含有N-取代酰胺基和亚氨基取代基的聚磷腈聚合物
公开(公告)号：US4218557A
公开(公告)日：1980-08-19
申请号：US953718
申请日：1978-10-20
CPC分类号： C08G79/025
摘要： Polyphosphazene polymers are prepared which contain repeating units represented by the formulas: ##STR1## wherein X is represented by: ##STR2## wherein Y is selected from the group consisting of ##STR3## and --SO.sub.2 -- and p=0 or 1; when p=0, R.sub.1 and R.sub.2 are independently selected from a group consisting of substituted or unsubstituted aliphatic, aryl, araryl, and alkylaryl radicals or R.sub.1 and R.sub.2 can form a cyclic amide containing radical wherein R.sub.1 and R.sub.2 taken together are selected from a group consisting of --CH.sub.2).sub.n where n=2 to 12, wherein R.sub.3 is a lower alkyl radical or hydrogen; and when p=1, R.sub.1 and R.sub.2 taken together form a linkage in a cyclic imide containing radical selected from a group consisting of --CH.sub.2).sub.n, where n'=2 or 3 and ##STR4## where R.sub.3 is as defined above, R.sub.4 is selected from the group consisting of hydrogen, halogen and alkyl radical containing 1 to 6 carbon atoms; and p' is 0 to 4, X' is a substituted or unsubstituted alkoxy, aryloxy, amino or mercapto substituent group or mixtures thereof which are compatible with an N-substituted amido substituent and are known in the state of the art of polyphosphazene technology; and 20.ltoreq.(w+y+z).ltoreq. 50,000 per polymer and (y+z)>0.The polymers of the invention can be utilized to form protective films and can also be utilized in applications such as for molding, coatings, foams and the like.
摘要翻译： 制备聚磷腈聚合物，其含有由下式表示的重复单元：其中X由下式表示：其中Y选自由下列组成的组：＆lt; IMAGE＆gt;和-SO 2 - 和p = 0或1; 当p = 0时，R 1和R 2独立地选自由取代或未取代的脂族，芳基，芳芳基和烷基芳基组成的组，或者R 1和R 2可以形成含有环酰胺的基团，其中R 1和R 2一起选自基团 由-CH 2）n组成，其中n = 2至12，其中R 3为低级烷基或氢; 并且当p = 1时，R 1和R 2一起形成含有选自-CH 2）n的环状酰亚胺基团中的键，其中n'= 2或3，其中R 3如上所定义，R 4 选自氢，卤素和含有1至6个碳原子的烷基; 并且p'为0至4，X'为与N-取代的酰氨基取代基相容的取代或未取代的烷氧基，芳氧基，氨基或巯基取代基或其混合物，并且在聚磷腈技术领域已知; 和每个聚合物的20（w + y + z） 0。 本发明的聚合物可用于形成保护膜，也可用于成型，涂料，泡沫等应用。
-
公开(公告)号：US4182835A
公开(公告)日：1980-01-08
申请号：US941109
申请日：1978-09-08
IPC分类号： C08F299/00 , C01B21/098 , C08F290/00 , C08G79/00 , C08G79/02 , C08G79/04 , C08G85/00
CPC分类号： C08G79/025
摘要： Polyphosphazene copolymers are prepared which contain randomly distributed units represented by the formulas: ##STR1## wherein X is --CNO.sub.2 R.sub.1 R.sub.2 in which R.sub.1 and R.sub.2 are H, a branched, straight chain or cyclic alkyl group containing from 1 to 12 carbon atoms or mixtures thereof, and wherein X' is selected from the group consisting of substituted and unsubstituted alkoxy, alkenyloxy, aryloxy, alkenylaryloxy, amino and mercapto groups or mixtures thereof.In the copolymer units represented by the above formulas, all X substituent groups may be the same or they may be mixed and all X' substituent groups may be the same or mixed. In the mixtures, the X substituent groups may be mixtures of different --CNO.sub.2 R.sub.1 R.sub.2 groups and the X' substituent groups may be mixtures of alkoxy, alkenyloxy, aryloxy, alkenylaryloxy, amino and mercapto groups.The copolymers of the invention can be utilized to form protective films and may also be utilized in applications such as for moldings, coatings, and the like.
摘要翻译： 制备聚磷腈共聚物，其含有由下式表示的随机分布的单元：其中X为-CNO 2 R 1 R 2，其中R 1和R 2为H，含有1至12个碳原子的支链，直链或环状烷基或其混合物， 并且其中X'选自取代和未取代的烷氧基，烯氧基，芳氧基，烯基芳氧基，氨基和巯基或其混合物。 在由上式表示的共聚物单元中，所有X取代基可以相同或可以混合，并且所有X'取代基可以相同或混合。 在混合物中，X取代基可以是不同的-CNO 2 R 1 R 2基团的混合物，X'取代基可以是烷氧基，烯氧基，芳氧基，烯基芳氧基，氨基和巯基的混合物。 本发明的共聚物可用于形成保护膜，也可用于诸如模制品，涂料等的应用中。
-
7.发明授权Polyphosphazene polymers containing alkoxy substitutents containing a fully substituted carbon in the beta position 失效含有在β位置含有完全取代的碳的烷氧基取代基的聚磷腈聚合物
公开(公告)号：US4264759A
公开(公告)日：1981-04-28
申请号：US941105
申请日：1978-09-08
CPC分类号： C08G79/025 , C08L85/02
摘要： Polyphosphazene polymers are prepared which contain repeating units represented by the formulas: ##STR1## wherein X is represented by: ##STR2## wherein R.sub.1, and R.sub.2 and R.sub.3 are independently selected from the group consisting of substituted or unsubstituted alkyl and alkoxy radicals containing from 1 to 12 carbon atoms and aryl radicals; X' is chlorine or a substituted or unsubstituted alkoxy, aryloxy, amino or mercapto radical or mixture thereof, which are compatible with the alkoxy substituent containing a fully substituted carbon in the beta position; and 20.ltoreq.(w+y+x).ltoreq. 50,000 per polymer.The polymers of the invention can be utilized to form protective films, and can also be utilized in applications such as for molding, coatings, foams and the like.
摘要翻译： 制备含有由下式表示的重复单元的聚磷腈聚合物：其中X表示为：其中R 1，R 2和R 3独立地选自取代或未取代的烷基和烷氧基，所述烷基和烷氧基含有1 至12个碳原子和芳基; X'是氯或取代或未取代的烷氧基，芳氧基，氨基或巯基或其混合物，其与在β位含有完全取代的碳的烷氧基取代基相容; 和20（=（w + y + x））/ 50,000。 本发明的聚合物可用于形成保护膜，也可用于成型，涂料，泡沫等应用。
-
公开(公告)号：US4258170A
公开(公告)日：1981-03-24
申请号：US67985
申请日：1979-08-20
CPC分类号： C08G79/025
摘要： Polyphosphazene polymers are prepared which contain repeating units represented by the formulas: ##STR1## wherein X is represented by one or more of the following structural formulas: ##STR2## wherein R.sub.1-11 are independently selected from the group consisting of hydrogen, halogen, cyano, nitro, and substituted and unsubstituted alkyl, aryl, alkoxy, aryloxy, alkylmercapto, and dialkylamino radicals, and R.sub.1 or 3 and R.sub.2, or R.sub.5 and R.sub.6 taken together can form a substituted or unsubstituted benzene ring structure; X' can represent one or more substituents from the group consisting of a halogen radical, substituted and unsubstituted alkoxy, aryloxy, amino and mercapto radicals which are known in the state of the art in poly(phosphazene) technology and which are compatible with the copolymer substituents. The polymer can contain from 20 to 50,000 of such units such that 20.ltoreq.(w+y+z).ltoreq.50,000.The polymers of the invention can be utilized to form protective films and can also be utilized in applications such as for molding, coatings, foams, and the like.
摘要翻译： 制备含有由下式表示的重复单元的聚磷腈聚合物：其中X由以下结构式中的一个或多个表示：其中R 11-11独立地选自氢，卤素，氰基 硝基，取代和未取代的烷基，芳基，烷氧基，芳氧基，烷基巯基和二烷基氨基，R1或3和R2或R5和R6一起可以形成取代或未取代的苯环结构; X'可以表示在聚（磷腈）技术中在现有技术中已知的并且与共聚物相容的卤素基团，取代和未取代的烷氧基，芳氧基，氨基和巯基的一个或多个取代基 取代基。 聚合物可以含有20-50,000个这样的单元，使得20（w + y + z）= 50,000。 本发明的聚合物可以用于形成保护膜，并且还可以用于诸如模塑，涂料，泡沫等的应用中。
-
公开(公告)号：US4242494A
公开(公告)日：1980-12-30
申请号：US68036
申请日：1979-08-20
CPC分类号： C08G79/025
摘要： Polyphosphazene polymers are prepared which contain repeating units represented by the formulas: ##STR1## wherein X and X' are the same or different and are represented by: ##STR2## wherein R is selected from the group consisting of hydrogen and unsubstituted and substituted alkyl, aryl, and heterocyclic groups; X' may additionally be selected from the group consisting of chloro- and substituted or unsubstituted alkoxy, aryloxy, amino and mercapto radicals or a mixture thereof; and 20.ltoreq.(w+y+z).ltoreq.50,000.The polymers of the invention can be utilized in applications such as molding, coatings, foams and the like.
摘要翻译： 制备聚磷腈聚合物，其含有由下式表示的重复单元：其中X和X'相同或不同，并由下式表示：其中R选自氢 和未取代和取代的烷基，芳基和杂环基团; X'可以另外选自氯代和取代或未取代的烷氧基，芳氧基，氨基和巯基或其混合物; 和20
-
10.发明授权Polyphosphazene polymers containing substituted or unsubstituted nitrophenoxy substituents 失效含有取代或未取代的硝基苯氧基取代基的聚磷腈聚合物
公开(公告)号：US4242492A
公开(公告)日：1980-12-30
申请号：US941119
申请日：1978-09-08
CPC分类号： C08G79/025
摘要： Polyphosphazene polymers are prepared which contain randomly distributed units represented by the formulas: ##STR1## wherein X is selected from the group consisting of substituted and unsubstituted mono, di, and tri nitro substituted phenoxy groups and mixtures thereof and wherein X' is the same as X or is selected from the group consisting of substituted and unsubstituted alkoxy, alkenyloxy, aryloxy, alkenylaryloxy, amino and mercapto groups.The polymers of the invention can be utilized to form protective films and may also be utilized in application such as for moldings, coatings, and the like where heat stability and solvent resistance are important.
摘要翻译： 制备聚磷腈聚合物，其含有由下式表示的随机分布的单元：其中X选自取代和未取代的单，二和三硝基取代的苯氧基及其混合物，其中X'与 X或选自取代和未取代的烷氧基，烯氧基，芳氧基，烯基芳氧基，氨基和巯基。 本发明的聚合物可用于形成保护膜，并且也可用于应用中，例如其中热稳定性和耐溶剂性重要的模制品，涂料等。
-
-
-
-
-
-
-
-
-
搜索结果
107 条记录 (耗时 0.026 秒)
