公开(公告)号：US20160271582A1

公开(公告)日：2016-09-22

申请号：US15079903

申请日：2016-03-24

Applicant: YEDA RESEARCH AND DEVELOPMENT CO. LTD.

Inventor： Milko E. VAN DER BOOM ,  Michal LAHAV ,  Shira HAMAMI ,  Maria-Chiara DI-GREGORIO ,  Qiang WEN ,  Sreejith SHANKAR POOPPANAL

IPC: B01J20/22 ,  C07D213/06 ,  C07D213/42

CPC classification number: B01J20/226 ,  C07B2200/13 ,  C07C2603/74 ,  C07D213/06 ,  C07D213/42

Abstract: The present invention provides metal-organic materials, more specifically organometallic polymers, comprising polypyridyl organic ligands such as tetrakis(4-(pyridin-4-ylethynyl)phenyl)methane, tetrakis(4-(2-(pyridin-4-yl)vinyl)phenyl)methane, 1,3,5,7-tetrakis(4-(pyridin-4-ylethynyl)phenyl)adamantane or 1,3,5,7-tetrakis(4-(2-(pyridine-4-yl)vinyl)phenyl) adamantine, and metal ions structurally coordinated with said ligands, and having three-dimensional crystalline micro or sub-micro structure; as well as a method for the preparation thereof. These metal-organic materials are useful as adsorbents in processes for gas adsorption or separation.

Abstract translation: 本发明提供金属 - 有机材料，更具体地说是有机金属聚合物，其包含聚吡啶基有机配体如四（4-（吡啶-4-基乙炔基）苯基）甲烷，四（4-（2-（吡啶-4-基） ）苯基）甲烷，1,3,5,7-四（4-（吡啶-4-基乙炔基）苯基）金刚烷或1,3,5,7-四（4-（2-（吡啶-4-基） 乙烯基）苯基）金刚烷和与所述配体结构配位的金属离子，并具有三维结晶微亚结构或亚微结构; 以及其制备方法。 这些金属有机材料可用作气体吸附或分离方法中的吸附剂。