公开(公告)号：US07291318B2

公开(公告)日：2007-11-06

申请号：US10687805

申请日：2003-10-20

申请人： Yasunori Sakurabayashi ,  Takuya Kondo ,  Yasushi Yamazawa ,  Yoshinao Suzuki ,  Marc Monthioux ,  Mikako LE. Lay

发明人： Yasunori Sakurabayashi ,  Takuya Kondo ,  Yasushi Yamazawa ,  Yoshinao Suzuki ,  Marc Monthioux ,  Mikako LE. Lay

IPC分类号： D01F9/12 ,  B82B3/00

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/152 ,  C01B32/16 ,  C01B2202/02 ,  C01B2202/06 ,  C01B2202/34 ,  C01B2202/36 ,  Y10S977/844

摘要： A method is presented for effectively manufacturing multi-wall (double-wall, etc.) carbon nanotubes (CNTs) having a structure whereby interior tubes are formed within the CNTs. In this manufacturing method, fullerene/CNT hybrid structures are prepared, wherein assembled fullerenes, these being fullerenes that are linked, have been housed within single-wall CNTs. The interior tubes are formed from the assembled fullerenes by subjecting the hybrid structures to electron beam irradiation while in a heated state. It is preferred that irradiation with the electron beams occurs at a temperature of 100˜500° C. and with the electron beams having an accelerating voltage of 80˜250 kV. According to the manufacturing method of the present invention, multi-wall CNTs with few defects can be manufactured at lower temperatures and in a shorter period than in the case where the fullerene/CNT hybrid structures are only maintained under high temperature conditions (and electron beam irradiation is not performed).

摘要翻译： 提出了一种用于有效地制造具有结构的多壁（双壁等）碳纳米管（CNT）的方法，其中内部管在CNT内形成。 在该制造方法中，制备富勒烯/ CNT混合结构，其中组装的富勒烯（这些是连接的富勒烯）已经容纳在单壁CNT内。 内部管由组装的富勒烯形成，通过在加热状态下对混合结构进行电子束照射。 优选的是，电子束的照射在100〜500℃的温度下发生，电子束的加速电压为80〜250kV。 根据本发明的制造方法，可以在较低的温度下和较短的时间内制造具有少量缺陷的多壁CNT，而不是富勒烯/ CNT复合结构仅保持在高温条件下（和电子束 不进行照射）。