公开(公告)号：US4843142A

公开(公告)日：1989-06-27

申请号：US947412

申请日：1986-12-24

申请人： Yasuo Sano ,  Kouichi Shirahama ,  Takahiko Hirono

发明人： Yasuo Sano ,  Kouichi Shirahama ,  Takahiko Hirono

IPC分类号： C08G69/44

CPC分类号： C08G69/44

摘要： A process for producing a cross-linked resin which comprises: reacting at least one phenolic reactant selected from the group consisting of(a) a compound having phenolic hydroxyls and having the general formula:HO--Ar--OHwherein Ar represents a divalent aromatic group composed of single or condensed aromatic rings, or a divalent aromatic group composed of two or more aromatic rings connected by C--C covalent bond, or a divalent aromatic group composed of two or more aromatic rings connected by a divalent hydrocarbon group or a divalent group selected from the group consisting of carbonyl, thioether, ether and amide group, and wherein the aromatic ring may bear additional hydroxyls or substituents which are inactive to the bis(2-oxazoline) compound, and(b) a polymer having not less than two phenolic hydroxyls in the molecule.with a bis(2-oxazoline) compound in a molar ratio of the bis(2-oxazoline) compound to the phenolic reactant not less than about 1, in the presence of a catalyst selected from the group consisting of phosphorous acid, organic phosphites and oxazoline ring-opening polymerization catalysts at elevated temperatures.

摘要翻译： 一种制备交联树脂的方法，其包括：使至少一种选自（a）具有酚羟基的化合物和具有通式HO-Ar-OH的酚反应物反应，其中Ar表示二价芳族基团 或由两个或更多个通过CC共价键连接的芳环组成的二价芳香族基团或由两个以上由二价烃基或二价基团连接的芳香环构成的二价芳香族基团构成的二价芳香族基团， 由羰基，硫醚，醚和酰胺基组成的组，其中芳环可以带有对双（2-恶唑啉）化合物无活性的另外的羟基或取代基，和（b）具有不少于2个酚羟基的聚合物 在分子中。 在选自亚磷酸，有机亚磷酸酯和有机亚磷酸酯的催化剂的存在下，使双（2-恶唑啉）化合物与双（2-恶唑啉）化合物与酚反应物的摩尔比不小于约1， 恶唑啉开环聚合催化剂。