公开(公告)号：US20050040368A1

公开(公告)日：2005-02-24

申请号：US10745970

申请日：2003-12-29

申请人： Yoshimi Iijima ,  Keisuke Asai

发明人： Yoshimi Iijima ,  Keisuke Asai

IPC分类号： G01K11/16 ,  C09D5/22 ,  C09D5/26 ,  C09D175/04 ,  C09K11/06 ,  G01K11/20 ,  G01N31/22

CPC分类号： G01K11/20

摘要： The present invention provides a temperature sensitive paint for low-temperature use which shows durability at low temperatures, has a high light emission intensity, and makes it possible to perform precise temperature measurements of surface temperature fields by applying the paint to the surface of an object and measuring the light emission even in cases where the measurement distance is long in, for example, a large cryogenic wind tunnel or the like. The temperature sensitive paint for low-temperature use contains a ruthenium complex having a high light emission intensity as a temperature sensitive luminophore, a urethane type polymer as a binder, and an alcohol organic solvent as a solvent. Use of an alcohol organic solvent makes it possible to dissolve a temperature sensitive luminophore at a high solubility and to increase the light emission intensity by raising the temperature sensitive luminophore concentration in the coating film, so that more precise temperature measurements can be performed. By using the urethane type polymer having the durability at low-temperature, it is possible to obtain durability where no cracks occur at low temperatures even when the film thickness is increased. Therefore, adjustment of the light emission intensity and surface treatment such as surface polishing and the like can be performed by using this temperature sensitive paint for low-temperature use.

摘要翻译： 本发明提供一种低温用温敏涂料，其在低温下显示耐久性，发光强度高，并且可以通过将涂料施涂到物体的表面上来进行表面温度场的精确温度测量 并且即使在例如大型低温风洞等中测量距离长的情况下也测量发光。 用于低温用途的感温涂料含有作为温度敏感的发光体具有高发光强度的钌配合物，作为粘合剂的聚氨酯类聚合物和作为溶剂的醇有机溶剂。 使用醇有机溶剂使得可以以高溶解度溶解温度敏感的发光体并通过提高涂膜中的温度敏感的发光体浓度来增加发光强度，从而可以进行更精确的温度测量。 通过使用在低温下具有耐久性的氨基甲酸酯型聚合物，即使膜厚增加，也可获得在低温下不发生裂纹的耐久性。 因此，通过使用这种温度敏感的低温用涂料，可以进行发光强度的调整和表面处理等的表面处理等。

公开(公告)号：US06787250B2

公开(公告)日：2004-09-07

申请号：US10182924

申请日：2002-07-29

申请人： Kengo Shibuya ,  Masanori Koshimizu ,  Yuko Takeoka ,  Keisuke Asai

发明人： Kengo Shibuya ,  Masanori Koshimizu ,  Yuko Takeoka ,  Keisuke Asai

IPC分类号： G01T120

CPC分类号： G01T1/2018

摘要： This invention relates to a radiation detection device for detecting ionizing beam discharges such as gamma rays, x-rays, electron beams, charged particle beams and neutral particle beams. Specifically, it relates to a radiation detection device which can measure radiations which exist for a very short time (of the order of subnanoseconds or less) from the appearance of photoemission to extinction. It is an object of this invention to provide a radiation detection device using a perovskite organic-inorganic hybrid compound as a scintillator, the formula of this compound being (R1—NR113)2MX4 or (R2═NR122)2MX4, or alternatively, (NR133—R3—NR133)MX4 or (NR142═R4═NR142)MX4 (in the formula, R1 is a monovalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, R2 is a divalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, and may be cyclic, R3 is a divalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, R4 is a tetravalent hydrocarbon group which may contain a heterocyclic ring and may be substituted by halogen atoms, R11-R14 may be identical or different, and may be hydrogen atoms or alkyl groups having two or more atoms, M is a Group IVa metal, Eu, Cd, Cu, Fe, Mn or Pd, and X is a halogen atom). This radiation detection device can quantify the radiation amount of the detected radiation.

摘要翻译： 本发明涉及一种用于检测诸如γ射线，X射线，电子束，带电粒子束和中性粒子束的电离束放电的放射线检测装置。 具体地说，本发明涉及一种放射线检测装置，该放射线检测装置可以测量从光照发射到消光的非常短的时间（亚纳秒级以下）存在的辐射。本发明的目的是提供一种辐射检测装置 使用钙钛矿有机 - 无机杂化化合物作为闪烁体，该化合物的化学式为（R 1 -NR 11）2 M 2或（R 2 = NR 12）2 X 2，或者， NR 13 R 3或-NR 14 R 3 =（NR 14）= NR 4 = NR 14）MX 4（式中，R 1为单价 可以含有杂环并且可以被卤素原子取代的烃基，R 2是可以含有杂环并且可以被卤素原子取代的二价烃基，并且可以是环状，R 3是 可以含有杂环并且可以被卤素原子取代的二价烃基，R 4是可以含有杂环的四价烃基，并且可被ha取代 碱原子，R 11 -R 14可以相同或不同，可以是氢原子或具有两个或多个原子的烷基，M是Ⅳa族金属，Eu，Cd，Cu，Fe，Mn或Pd ，X为卤素原子）。 该放射线检测装置能够量化检测出的放射线的辐射量。

公开(公告)号：USD548139S1

公开(公告)日：2007-08-07

申请号：US29256254

申请日：2006-03-20

申请人： Han Seung Lee ,  Keisuke Asai

设计人： Han Seung Lee ,  Keisuke Asai

公开(公告)号：US07069169B2

公开(公告)日：2006-06-27

申请号：US10743786

申请日：2003-12-24

申请人： Kazuyuki Nakakita ,  Keisuke Asai

发明人： Kazuyuki Nakakita ,  Keisuke Asai

IPC分类号： G01K11/12

CPC分类号： G01K17/20 ,  G01K11/12

摘要： An object of the present invention is to provide a method that allows the heat flux distribution on an object surface to be measured even when the heat flux is an unsteady or short-duration phenomenon, and that does not depend on the material of the object; and to provide a system for measuring the heat flux distribution on an object surface with the aid of this method. In the method for measuring the heat flux on an object surface in accordance with the present invention, the emission intensity of a temperature-sensitive paint that varies with the temperature of the object surface is chronologically captured and sensed as video information at a high frame rate, an image of the temperature distribution on the object surface is obtained based on characteristics between the emission intensity and temperature calibration, and the heat flux in each domain is calculated by the Cook and Feldermann method.

摘要翻译： 本发明的目的是提供即使当热通量是不稳定或短时间现象而且不依赖于物体的材料时，也能够测量物体表面上的热通量分布的方法。 并提供一种借助于该方法测量物体表面上的热通量分布的系统。 在根据本发明的用于测量物体表面上的热通量的方法中，随着物体表面的温度而变化的温度敏感性涂料的发射强度按时间顺序捕获并被感测为高帧率的视频信息 根据发光强度和温度校准之间的特性，获得物体表面温度分布的图像，并通过Cook和Feldermann方法计算每个域中的热通量。

公开(公告)号：US20080099684A1

公开(公告)日：2008-05-01

申请号：US10584985

申请日：2005-01-12

申请人： Hidetoshi Murakami ,  Kengo Shibuya ,  Haruo Saito ,  Keisuke Asai ,  Tsuneo Honda

发明人： Hidetoshi Murakami ,  Kengo Shibuya ,  Haruo Saito ,  Keisuke Asai ,  Tsuneo Honda

IPC分类号： G01T1/202

CPC分类号： G01T1/20 ,  G01T1/2023

摘要： To present a scintillation crystal containing a fluorescent component with excellent luminous efficiency and short decay time while the wavelength of the emitted light being in the visible light region or very near the visible light region and a radiation detection device using the scintillation crystal having an excellent timing resolution capability.Barium chloride (BaCl2) is used as the scintillation crystal. A radiation detection device comprising a barium chloride (BaCl2) crystal as a scintillator and a photomultiplier tube to receive the light from the scintillator wherein the wavelength of the light emitted from the scintillator is between 250 nm and 350 nm and the scintillator is located in a low humidity atmosphere.

摘要翻译： 为了呈现包含具有优异的发光效率和短的衰减时间的荧光成分的闪烁晶体，而发射的光的波长在可见光区域或非常接近可见光区域，并且使用闪烁晶体的放射线检测装置具有优异的定时 分辨能力。 氯化钡（BaCl 2 H 2）用作闪烁晶体。 一种辐射检测装置，包括作为闪烁体的氯化钡（BaCl 2 N 2）晶体和用于接收来自闪烁体的光的光电倍增管，其中从闪烁体发射的光的波长为250nm至350nm nm，闪烁体位于低湿度的气氛中。

公开(公告)号：USD550383S1

公开(公告)日：2007-09-04

申请号：US29256257

申请日：2006-03-20

申请人： Keisuke Asai

设计人： Keisuke Asai

公开(公告)号：US20090121188A1

公开(公告)日：2009-05-14

申请号：US11883563

申请日：2006-01-27

申请人： Masanori Koshimizu ,  Kengo Shibuya ,  Haruo Saito ,  Keisuke Asai ,  Tsuneo Honda

发明人： Masanori Koshimizu ,  Kengo Shibuya ,  Haruo Saito ,  Keisuke Asai ,  Tsuneo Honda

IPC分类号： G01T1/20

CPC分类号： G01T1/2023 ,  C09K11/7733 ,  C30B11/00 ,  C30B29/12 ,  G21K4/00

摘要： [PROBLEMS] To provide a scintillator responding to high counting rate sustaining high-speed and high detection efficiency of BaF2 and to provide a radiation detection device with high time resolution by using the scintillator.[MEANS FOR SOLVING PROBLEMS] A specified amount of rare earth element (Eu) is doped into BaF2 to reduce long decay lifetime component (600 to 620 nm), leaving fast decaying component (0.6 to 0.8 ns) of BaF2 luminescence unchanged. The present invention is a high counting rate scintillator for detecting radiation comprising BaF2 doped with rare earth elements (Eu), wherein the doping amount is in the range of 0.02 to 1.0 mol %.

摘要翻译： [问题]提供响应于高计数率的闪烁体，其保持BaF2的高速和高检测效率，并通过使用闪烁体提供具有高时间分辨率的放射线检测装置。 [解决问题的手段]将BaF2中规定量的稀土元素（Eu）掺杂到BaF2中以减少长衰减寿命成分（600〜620nm），使BaF2发光的快速衰减成分（0.6〜0.8ns）不变。 本发明是用于检测包含掺杂有稀土元素（Eu）的BaF 2的辐射的高计数速率闪烁体，其中掺杂量在0.02至1.0mol％的范围内。

公开(公告)号：US06797390B2

公开(公告)日：2004-09-28

申请号：US10386671

申请日：2003-03-13

申请人： Keisuke Asai ,  Hiroyuki Nishide

发明人： Keisuke Asai ,  Hiroyuki Nishide

IPC分类号： B32B904

CPC分类号： C08G61/04 ,  Y10T428/2852 ,  Y10T428/31663 ,  Y10T436/209163

摘要： An oxygen-quenching luminophore constituting part of a pressure-sensitive luminophore is directly bonded by a covalent bond to an organic polymer compound having trimethylsilyl groups, so the luminophore molecules are retained in the polymer and free aggregation is inhibited when the organic solvent is evaporated. It is therefore possible to prevent light response from being reduced by the aggregation of the luminophore molecules during evaporation of the organic solvent, which is a drawback of forming films from conventional mixed-type pressure-sensitive paints. A thin-film sensor with uniform characteristics can be formed by spraying or application from a pressure-sensitive paint obtained by mixing a functional polymer with a solvent. In addition, a coating solution that has high reproducibility and is suitable for spraying or application can be obtained merely by dissolving the functional polymer as a single component in a suitable solvent. It is possible to obtain a functional polymer, a pressure-sensitive paint, and a pressure-sensitive element in which a reduction in light response due to luminophore aggregation can be prevented, and a thin sensor film having uniform characteristics can be formed, even when the organic solvent has evaporated.

摘要翻译： 构成压敏发光体的一部分的氧猝发发光体通过共价键直接键合到具有三甲基甲硅烷基的有机高分子化合物上，因此，当有机溶剂蒸发时，发光体分子保留在聚合物中，并且抑制游离聚集。 因此，通过在有机溶剂的蒸发过程中发光体分子的聚集来防止光的反应降低，这是由传统的混合型压敏涂料形成薄膜的缺点。 具有均匀特性的薄膜传感器可以通过将功能性聚合物与溶剂混合得到的压敏涂料进行喷涂或涂布而形成。 此外，仅通过将功能性聚合物作为单一成分溶解在合适的溶剂中，可以获得具有高再现性并且适于喷涂或施用的涂布溶液。 可以获得功能性聚合物，压敏涂料和能够防止由于发光聚集引起的光响应减少的压敏元件，并且即使形成具有均匀特性的薄传感器膜，即使 有机溶剂蒸发。

公开(公告)号：US20060197028A1

公开(公告)日：2006-09-07

申请号：US10552522

申请日：2004-03-31

申请人： Kengo Shibuya ,  Hidetoshi Murakami ,  Haruo Saito ,  Keisuke Asai

发明人： Kengo Shibuya ,  Hidetoshi Murakami ,  Haruo Saito ,  Keisuke Asai

IPC分类号： G01T3/06

CPC分类号： G01T1/1645 ,  G01T1/20

摘要： A gamma ray detector having a very high time resolution. By using CsBr (cesium bromide) as a scintillator crystal and a MCP built-in photoelectron multiplier tube as a photoelectron multiplier, much larger time resolution are obtained in detecting gamma rays than conventional detectors.

摘要翻译： 具有非常高的时间分辨率的伽马射线检测器。 通过使用CsBr（溴化铯）作为闪烁体晶体和MCP内置的光电子倍增管作为光电子倍增器，在检测伽马射线时比常规检测器获得更大的时间分辨率。

公开(公告)号：US07087904B2

公开(公告)日：2006-08-08

申请号：US10451755

申请日：2002-07-29

申请人： Kengo Shibuya ,  Masanori Koshimizu ,  Keisuke Asai

发明人： Kengo Shibuya ,  Masanori Koshimizu ,  Keisuke Asai

IPC分类号： G01T1/161 ,  C09K11/06

CPC分类号： C09K11/664

摘要： This invention is a positron emission tomography (PET) device comprising as a scintillator a perovskite organic/inorganic hybrid compound selected from the group represented by the general formulae: (R1—NR113)2MX4 or (R2—NR12)2MX4, (NR133—R3—NR133)MX4, or (NR142═R4═NR142)MX4, or AMX3. When used as a scintillator, the perovskite organic/inorganic hybrid compound emits visible light with a very fast (subnanosecond order) response, allowing for improved resolution and time-of-flight PET methods.

摘要翻译： 本发明是一种正电子发射断层摄影（PET）装置，其包括选自以下通式表示的钙钛矿有机/无机杂化化合物作为闪烁体：<？in-line-formula description =“In-line Formulas”end =“ （“1”）11“3”3“（”1“）。 或（R 12）-NR 12，（NR 12）12，或（R 12） 3个或3个或更多个（NR（R 3）3） 2 4 或AMX 3 <？in-line-formula description =“In-line Formulas”end =“tail”？>当用作闪烁体时，钙钛矿有机/无机杂化物 复合物以非常快的（亚纳秒级）响应发出可见光，允许改进分辨率和飞行时间PET方法。