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1.发明授权公开(公告)号：US07880082B2
公开(公告)日：2011-02-01
申请号：US10511012
申请日：2003-04-10
申请人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
发明人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
IPC分类号： H01L31/00
CPC分类号： H01B1/122 , H01G9/2009 , H01G9/2031 , H01M14/005 , H01M2300/0082 , Y02E10/542 , Y02P70/521 , Y10S528/902
摘要： The present invention relates to a solid electrolyte having superior conductive properties and reliability, a photovoltaic device using this electrolyte, and manufacturing methods thereof. The solid electrolyte of the present invention is a solid electrolyte having an electrolyte composition and a matrix polymer. The matrix polymer is formed by polymerization of a first compound having at least two isocyanate groups and a second compound having at least two nucleophilic groups containing active hydrogen in accordance with a polyaddition reaction, and the polymerization is performed after a precursor for the matrix polymer is brought into contact with a surface on which the solid electrolyte is to be formed.
摘要翻译： 本发明涉及具有优良导电性和可靠性的固体电解质，使用该电解质的光电器件及其制造方法。 本发明的固体电解质是具有电解质组成物和基体聚合物的固体电解质。 基质聚合物通过根据加聚反应聚合具有至少两个异氰酸酯基的第一化合物和含有至少两个含有活性氢的亲核基团的第二化合物而形成，并且在基质聚合物的前体为 与要形成固体电解质的表面接触。
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2.发明授权公开(公告)号：US07422922B2
公开(公告)日：2008-09-09
申请号：US10541877
申请日：2003-12-25
申请人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
发明人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
IPC分类号： H01L21/00
CPC分类号： H01G9/2068 , H01G9/2031 , H01L31/022425 , H01M14/005 , Y02E10/542 , Y02P70/521
摘要： In a photoelectric conversion device using a semiconductor electrode composed of semiconductor nanoparticles, the semiconductor electrode is made by coating and drying a paste containing a binder and semiconductor nanoparticles dispersed therein on a transparent conductive substrate, and pressing the paste to bond the semiconductor nanoparticles onto the transparent conductive substrate while heating it to a temperature in the range from 30° C. to the softening temperature of the transparent conductive substrate, or, if the semiconductor nanoparticles retain a sensitizing dye, to a temperature in the range from 30° C. to lower one of the softening temperature of the transparent conductive substrate and the deactivation temperature of the sensitizing dye.
摘要翻译： 在使用由半导体纳米粒子构成的半导体电极的光电转换装置中，通过将含有粘合剂的糊料和分散在其中的半导体纳米粒子的糊剂涂布并干燥而形成在半导体纳米颗粒上的半导体电极，并且将该糊料粘合到半导体纳米粒子 透明导电基板，同时将其加热至30℃至该透明导电基板的软化温度的温度，或者如果半导体纳米颗粒保持敏化染料，则温度范围为30℃至 降低透明导电性基材的软化温度和敏化染料的失活温度。
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3.发明申请公开(公告)号：US20070125418A1
公开(公告)日：2007-06-07
申请号：US10523483
申请日：2004-05-26
申请人： Yusuke Suzuki , Masahiro Morooka , Kazuhiro Noda
发明人： Yusuke Suzuki , Masahiro Morooka , Kazuhiro Noda
IPC分类号： H01L31/00
CPC分类号： H01M14/005 , A61K47/6865 , A61K47/6889 , A61K47/6891 , A61K2039/505 , B82Y5/00 , B82Y30/00 , C07K16/18 , C07K16/30 , C07K2317/622 , C07K2317/82 , H01G9/2022 , H01G9/2031 , H01M4/926 , Y02E10/542 , Y02P70/521
摘要： An electrode is composed of a carbon carrying a metal and a binder polymer, and it is used as a counter electrode of a dye-sensitized solar cell. The metal carried by carbon is at least one kind of metal selected from the group consisting of Pt, Ru, Co, Ti, Ni, Al and Au. The carbon is needle-like carbon, fullerene, carbon nanotube, conductive carbon black, or the like, and its specific surface area is equal to or larger than 100 m2/g.
摘要翻译： 电极由携带金属和粘合剂聚合物的碳组成，并且用作染料敏化太阳能电池的对电极。 由碳承载的金属是选自Pt，Ru，Co，Ti，Ni，Al和Au中的至少一种金属。 碳为针状碳，富勒烯，碳纳米管，导电性炭黑等，其比表面积为100m 2 / g以下。
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4.发明申请公开(公告)号：US20060185717A1
公开(公告)日：2006-08-24
申请号：US10543050
申请日：2003-12-26
IPC分类号： H01L31/00
CPC分类号： H01G9/2031 , C09C1/3607 , Y02E10/542 , Y02P70/521
摘要： A paste in which semiconductor fine grain such as titanium oxide fine grain or the like and a binder made of a polymer compound are mixed is coated onto a transparent conductive substrate and sintered, thereby forming a semiconductor layer made of the semiconductor fine grain, after that, ultraviolet rays are irradiated to the semiconductor layer and, by using a photocatalyst effect of the semiconductor fine grain, an organic substance remaining in the semiconductor layer is removed.
摘要翻译： 将其中混合了诸如氧化钛微粒等的半导体细晶粒和由高分子化合物制成的粘合剂的糊料涂覆在透明导电基材上并烧结，从而形成由半导体细晶粒制成的半导体层，之后 紫外线照射到半导体层，通过使用半导体细粒的光催化剂效果，去除留在半导体层中的有机物质。
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5.发明申请公开(公告)号：US20060107994A1
公开(公告)日：2006-05-25
申请号：US10541877
申请日：2003-12-25
申请人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
发明人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
CPC分类号： H01G9/2068 , H01G9/2031 , H01L31/022425 , H01M14/005 , Y02E10/542 , Y02P70/521
摘要： In a photoelectric conversion device using a semiconductor electrode composed of semiconductor nanoparticles, the semiconductor electrode is made by coating and drying a paste containing a binder and semiconductor nanoparticles dispersed therein on a transparent conductive substrate, and pressing the paste to bond the semiconductor nanoparticles onto the transparent conductive substrate while heating it to a temperature in the range from 30° C. to the softening temperature of the transparent conductive substrate, or, if the semiconductor nanoparticles retain a sensitizing dye, to a temperature in the range from 30° C. to lower one of the softening temperature of the transparent conductive substrate and the deactivation temperature of the sensitizing dye.
摘要翻译： 在使用由半导体纳米粒子构成的半导体电极的光电转换装置中，通过将含有粘合剂的糊料和分散在其中的半导体纳米粒子的糊剂涂布并干燥而形成在半导体纳米颗粒上的半导体电极，并且将该糊料粘合到半导体纳米粒子 透明导电基板，同时将其加热至30℃至该透明导电基板的软化温度的温度，或者如果半导体纳米颗粒保持敏化染料，则温度范围为30℃至 降低透明导电性基材的软化温度和敏化染料的失活温度。
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公开(公告)号：US20060011232A1
公开(公告)日：2006-01-19
申请号：US10527351
申请日：2003-08-22
申请人： Yusuke Suzuki , Masahiro Morooka , Kazuhiro Noda
发明人： Yusuke Suzuki , Masahiro Morooka , Kazuhiro Noda
IPC分类号： H01L31/00
CPC分类号： H01L31/022425 , H01L31/022475 , Y02E10/542
摘要： The present invention relates to a photovoltaic element conveniently used for a solar cell. An ITO substrate coated with a metallic oxide or a derivative thereof is used as a transparent electrode (3). Thus, the fall of a resistance value is suppressed even when the photovoltaic element is exposed to high temperature or acid.
摘要翻译： 本发明涉及一种方便用于太阳能电池的光电元件。 使用涂覆有金属氧化物或其衍生物的ITO基板作为透明电极（3）。 因此，即使当光电元件暴露于高温或酸时，电阻值的下降也被抑制。
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7.发明申请公开(公告)号：US20050263182A1
公开(公告)日：2005-12-01
申请号：US10511012
申请日：2003-04-10
申请人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
发明人： Masahiro Morooka , Yusuke Suzuki , Kazuhiro Noda
CPC分类号： H01B1/122 , H01G9/2009 , H01G9/2031 , H01M14/005 , H01M2300/0082 , Y02E10/542 , Y02P70/521 , Y10S528/902
摘要： The present invention relates to a solid electrolyte having superior conductive properties and reliability, a photovoltaic device using this electrolyte, and manufacturing methods thereof. The solid electrolyte of the present invention is a solid electrolyte having an electrolyte composition and a matrix polymer. The matrix polymer is formed by polymerization of a first compound having at least two isocyanate groups and a second compound having at least two nucleophilic groups containing active hydrogen in accordance with a polyaddition reaction, and the polymerization is performed after a precursor for the matrix polymer is brought into contact with a surface on which the solid electrolyte is to be formed.
摘要翻译： 本发明涉及具有优良导电性和可靠性的固体电解质，使用该电解质的光电器件及其制造方法。 本发明的固体电解质是具有电解质组成物和基体聚合物的固体电解质。 基质聚合物通过根据加聚反应聚合具有至少两个异氰酸酯基的第一化合物和含有至少两个含有活性氢的亲核基团的第二化合物而形成，并且在基质聚合物的前体为 与要形成固体电解质的表面接触。
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8.发明授权公开(公告)号：US07820471B2
公开(公告)日：2010-10-26
申请号：US10543050
申请日：2003-12-26
IPC分类号： H01L21/00
CPC分类号： H01G9/2031 , C09C1/3607 , Y02E10/542 , Y02P70/521
摘要： A paste in which semiconductor fine grain such as titanium oxide fine grain or the like and a binder made of a polymer compound are mixed is coated onto a transparent conductive substrate and sintered, thereby forming a semiconductor layer made of the semiconductor fine grain, after that, ultraviolet rays are irradiated to the semiconductor layer and, by using a photocatalyst effect of the semiconductor fine grain, an organic substance remaining in the semiconductor layer is removed.
摘要翻译： 将其中混合了诸如氧化钛微粒等的半导体细晶粒和由高分子化合物制成的粘合剂的糊料涂覆在透明导电基材上并烧结，从而形成由半导体细晶粒制成的半导体层，之后 紫外线照射到半导体层，通过使用半导体细粒的光催化剂效果，去除留在半导体层中的有机物质。
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9.发明申请PHOTOELECTRIC CONVERSION DEVICE, ITS MANUFACTURING METHOD, ELECTRONIC APPARATUS, ITS MANUFACTURING METHOD, SEMICONDUCTOR LAYER, AND ITS MANUFACTURING METHOD 审中-公开光电转换装置及其制造方法，电子装置及其制造方法，半导体层及其制造方法公开(公告)号：US20100255632A1
公开(公告)日：2010-10-07
申请号：US12816525
申请日：2010-06-16
IPC分类号： H01L31/18
CPC分类号： H01G9/2031 , C09C1/3607 , Y02E10/542 , Y02P70/521
摘要： A paste in which semiconductor fine grain such as titanium oxide fine grain or the like and a binder made of a polymer compound are mixed is coated onto a transparent conductive substrate and sintered, thereby forming a semiconductor layer made of the semiconductor fine grain, after that, ultraviolet rays are irradiated to the semiconductor layer and, by using a photocatalyst effect of the semiconductor fine grain, an organic substance remaining in the semiconductor layer is removed.
摘要翻译： 将其中混合了诸如氧化钛微粒等的半导体细晶粒和由高分子化合物制成的粘合剂的糊料涂覆在透明导电基材上并烧结，从而形成由半导体细晶粒制成的半导体层，之后 紫外线照射到半导体层，通过使用半导体细粒的光催化剂效果，去除留在半导体层中的有机物质。
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10.发明申请Dye sensitization photoelectric converter and process for fabricating the same 审中-公开染料敏化光电转换器及其制造方法公开(公告)号：US20060084257A1
公开(公告)日：2006-04-20
申请号：US10540629
申请日：2003-12-12
IPC分类号： H01L21/44
CPC分类号： H01M14/005 , B82Y10/00 , H01G9/2031 , H01G9/2063 , Y02E10/542 , Y02P70/521
摘要： In a dye-sensitized photoelectric transfer device having a semiconductor layer and an electrolyte layer between a transparent conductive substrate and a counter conductive substrate, the semiconductor layer is composed of titania nanotubes, and a sensitizing dye is retained by the titania nanotubes. The titania nanotubes preferably have an anatase-type crystalline form. The dye-sensitized photoelectric transfer device is used as a dye-sensitized solar cell.
摘要翻译： 在具有半导体层和透明导电性基板与对向导电性基板之间的电解质层的染料敏化型光电转移元件中，半导体层由二氧化钛纳米管构成，增感色素被二氧化钛纳米管保持。 二氧化钛纳米管优选具有锐钛矿型结晶形式。 染料敏化光电转移装置用作染料敏化太阳能电池。
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