公开(公告)号：US20080075883A1

公开(公告)日：2008-03-27

申请号：US11860817

申请日：2007-09-25

申请人： Yuuichi HAYATA ,  Kotaro WATANABE

发明人： Yuuichi HAYATA ,  Kotaro WATANABE

IPC分类号： B29C71/02

CPC分类号： B29C59/02 ,  B29C2035/0833 ,  B41M7/0045 ,  B41M7/0081 ,  C09D11/101 ,  C09D11/30

摘要： A process for producing a molded printed material is provided that includes (A) a step of forming an image by discharging an ink composition on a support by an inkjet method, the ink composition comprising at least one compound of monofunctional cationically polymerizable monomer selected from the group consisting of an oxetane compound, an oxirane compound, and a vinyl ether compound, and the proportion of the monofunctional cationically polymerizable monomer in the entire ink composition being at least 30 wt %, (B) a step of curing the ink composition by irradiating with actinic radiation the image obtained so as to obtain a printed material having the image cured on the support, and (C) a step of molding the printed material. There is also provided a molded printed material obtained by the process for producing a molded printed material.

摘要翻译： 提供了一种制造模制印刷材料的方法，其包括（A）通过喷墨方法将支持体上的油墨组合物排出而形成图像的步骤，该油墨组合物包含至少一种选自以下的单官能阳离子聚合单体的化合物： 由氧杂环丁烷化合物，环氧乙烷化合物和乙烯基醚化合物组成的组中的单官能阳离子聚合性单体的比例为30重量％以上，（B）通过照射使油墨组合物固化的工序 用光化辐射获得图像，以获得具有在载体上固化的图像的印刷材料，（C）模制印刷材料的步骤。 还提供了通过生产模制印刷材料的方法获得的模制印刷材料。

公开(公告)号：US20090087626A1

公开(公告)日：2009-04-02

申请号：US12237137

申请日：2008-09-24

申请人： Yuuichi HAYATA ,  Kazuhiro Yokoi

发明人： Yuuichi HAYATA ,  Kazuhiro Yokoi

IPC分类号： C09D11/10 ,  B05D3/06 ,  B29C51/06 ,  B32B3/10

CPC分类号： C09D11/101 ,  Y10T428/24802

摘要： An ink composition is provided that includes a perfluoroalkyl group-containing polymer, a polymerizable monomer, and a radical polymerization initiator, in which at least 80 wt % of the polymerizable monomer is a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes a step of discharging the ink composition onto a recording medium and a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material obtained by the inkjet recording method, and a process for producing a molded printed material that includes a step of forming an image by discharging the ink composition onto a support by an inkjet method, a step of irradiating the image thus obtained with actinic radiation so as to cure the ink composition and obtain a printed material having the image cured on the support, and a step of molding the printed material.

摘要翻译： 提供一种油墨组合物，其包括含全氟烷基的聚合物，可聚合单体和自由基聚合引发剂，其中至少80重量％的可聚合单体是选自单官能丙烯酸酯， 单官能甲基丙烯酸酯，单官能乙烯基氧基化合物，单官能N-乙烯基化合物，单官能丙烯酰胺和单官能甲基丙烯酰胺。 还提供了一种喷墨记录方法，其包括将油墨组合物排出到记录介质上的步骤和通过用光化辐射照射排出的油墨组合物来固化油墨组合物的步骤，通过喷墨记录方法获得的印刷材料，以及 一种模制印刷材料的制造方法，其包括通过喷墨方法将油墨组合物排出到支撑体上而形成图像的步骤，用光化辐射照射由此获得的图像以固化油墨组合物并获得 具有在载体上固化的图像的印刷材料和模制印刷材料的步骤。

公开(公告)号：US20110169902A1

公开(公告)日：2011-07-14

申请号：US13006106

申请日：2011-01-13

申请人： Yuuichi HAYATA ,  Yasuhito Oshima

发明人： Yuuichi HAYATA ,  Yasuhito Oshima

IPC分类号： B41J2/01 ,  C09D11/10

CPC分类号： C09D11/101 ,  C09D11/30

摘要： An inkjet ink composition is provided that includes (Component A) an N-vinyllactam, (Component B) a di(meth)acrylate ester of at least one type of diol selected from the group consisting of a straight-chain hydrocarbon diol having 9 to 18 carbon atoms, a branched hydrocarbon diol having 6 to 18 carbon atoms, and a monoalicyclic hydrocarbon diol having 6 to 18 carbon atoms, and (Component C) at least one type of polymerization initiator selected from the group consisting of an α-amino ketone compound, a thioxanthone compound, a thiochromanone compound, and a bisacylphosphine oxide compound. There is also provided an inkjet recording method that includes (a) an image formation step of forming an image above a support by discharging the inkjet ink composition by an inkjet method and (b) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the support.

摘要翻译： 提供了一种喷墨油墨组合物，其包含（组分A）N-乙烯基内酰胺，（组分B）至少一种选自以下的直链烃二醇中的至少一种二醇的二（甲基）丙烯酸酯：具有9至 18个碳原子，具有6-18个碳原子的支链烃二醇和具有6-18个碳原子的单脂烃二醇和（组分C）至少一种聚合引发剂，其选自α-氨基酮 噻吨酮化合物，噻吩酮化合物和双酰基氧化膦化合物。 还提供了一种喷墨记录方法，其包括（a）通过喷墨方法排出喷墨油墨组合物而形成载体上方的图像的图像形成步骤和（b）通过照射所获得的油墨组合物来固化油墨组合物的固化步骤 形成具有光化辐射的图像，从而获得在载体上方具有固化图像的印刷材料。

公开(公告)号：US20080206527A1

公开(公告)日：2008-08-28

申请号：US12036944

申请日：2008-02-25

申请人： Yuuichi HAYATA

发明人： Yuuichi HAYATA

IPC分类号： B32B3/00 ,  C08G67/02 ,  C08J7/04

CPC分类号： C09D11/40 ,  C09D11/101 ,  C09D11/322 ,  Y10T428/24802

摘要： An ink composition is provided that includes (A) a pigment, (B) a polymerizable monomer, (C) a polymerization initiator, and (D) a dispersant, the content of the pigment being no greater than 1 wt % of the entire ink composition, and the ratio (D/A) of the weight A of the pigment to the weight D of the dispersant in the ink composition satisfying the relationship 0.5

摘要翻译： 提供一种油墨组合物，其包含（A）颜料，（B）可聚合单体，（C）聚合引发剂和（D）分散剂，颜料的含量不大于整个油墨的1重量％ 组合物，以及油墨组合物中颜料的重量A与分散剂的重量D的比（D / A）满足关系式0.5

公开(公告)号：US20080131618A1

公开(公告)日：2008-06-05

申请号：US11947257

申请日：2007-11-29

申请人： Ippei NAKAMURA ,  Kaoru TOJO ,  Yuuichi HAYATA

发明人： Ippei NAKAMURA ,  Kaoru TOJO ,  Yuuichi HAYATA

IPC分类号： C09D11/10 ,  C08G61/00

CPC分类号： C09D11/101 ,  B41M7/0072 ,  B41M7/0081

摘要： An ink composition for inkjet-recording, which shows a high sensitivity to irradiation with actinic radiation and is able to form an image with superior curability, permitting the image formed after curing to have sufficient adhesiveness to a recording medium, as well as to have excellent flexibility in the formed image portion, and an inkjet-recording method using the same is provided: wherein the ink composition for inkjet-recording comprises (A) a compound having a polymerizable unsaturated bond and a cyclic amine structure in the molecule, (B) a compound having a polymerizable unsaturated bond and an alicyclic structure in the molecule, and (C) a radical polymerization initiator.

摘要翻译： 一种用于喷墨记录的油墨组合物，其对光化辐射的照射具有高度敏感性，并且能够形成具有优异固化性的图像，使得固化后形成的图像对记录介质具有足够的粘附性，并且具有优异的 提供形成图像部分的柔性和使用其的喷墨记录方法：其中喷墨记录用油墨组合物包含（A）分子中具有聚合性不饱和键和环状胺结构的化合物，（B） 分子中具有聚合性不饱和键和脂环结构的化合物，（C）自由基聚合引发剂。

公开(公告)号：US20090202795A1

公开(公告)日：2009-08-13

申请号：US12355003

申请日：2009-01-16

申请人： Yuuichi HAYATA ,  Kazuhiro Yokoi

发明人： Yuuichi HAYATA ,  Kazuhiro Yokoi

IPC分类号： C08K5/5419 ,  B05D3/06 ,  B32B3/00

CPC分类号： C08F283/124 ,  C09D11/101 ,  Y10T428/24802

摘要： An ink composition is provided that includes (A) a compound having an ethylenically unsaturated double bond and a silicone chain, (B) a polymerizable monomer, and (C) a radical polymerization initiator, at least 75 wt % of the polymerizable monomer being a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional ethylenically unsaturated carboxylic acid compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes (i-1) a step of discharging the ink composition onto a recording medium and (i-2) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material formed by employing the inkjet recording method, and a molded printed material formed by subjecting the printed material to molding.

摘要翻译： 提供了一种油墨组合物，其包括（A）具有烯属不饱和双键和硅氧烷链的化合物，（B）可聚合单体和（C）自由基聚合引发剂，至少75重量％的可聚合单体为 选自单官能丙烯酸酯，单官能甲基丙烯酸酯，单官能乙烯基氧基化合物，单官能N-乙烯基化合物，单官能烯键式不饱和羧酸化合物，单官能丙烯酰胺和单官能甲基丙烯酰胺的单官能可聚合单体。 还提供了一种喷墨记录方法，其包括（i-1）将油墨组合物排出到记录介质上的步骤，（i-2）通过用光化辐射照射排出的油墨组合物来固化油墨组合物的步骤， 通过使用喷墨记录方法形成的印刷材料和通过对印刷材料进行成型而形成的模制印刷材料。

公开(公告)号：US20080075884A1

公开(公告)日：2008-03-27

申请号：US11861100

申请日：2007-09-25

申请人： Yuuichi HAYATA

发明人： Yuuichi HAYATA

IPC分类号： B29C71/02

CPC分类号： B29C59/02 ,  B29C2035/0833 ,  B41M5/52 ,  B41M7/0045 ,  B41M7/0081 ,  C09D11/101 ,  C09D11/30

摘要： A process for producing a molded printed material is provided that includes (A) a step of forming an image on a support by an inkjet method using an ink composition comprising a polymerizable monomer, a colorant, and a polymerization initiator, (B) a step of forming a surface coating layer on the image by an inkjet method using a liquid composition comprising a polymerizable monomer and a polymerization initiator and comprising substantially no colorant, (C) a step of curing the image by irradiation with actinic radiation, (D) a step of curing the surface coating layer by irradiation with actinic radiation so as to obtain a printed material having the image and the surface coating layer cured on the support, and (E) a step of molding the printed material. There is also provided a molded printed material obtained by the process for producing a molded printed material.

摘要翻译： 提供一种制造模制印刷材料的方法，其包括（A）使用包含可聚合单体，着色剂和聚合引发剂的油墨组合物的喷墨方法在载体上形成图像的步骤，（B）步骤 通过使用包含可聚合单体和聚合引发剂的液体组合物的喷墨方法在图像上形成表面涂层，并且基本上不包含着色剂，（C）通过光化辐射照射来固化图像的步骤，（D） 通过用光化辐射照射来固化表面被覆层的步骤，以获得具有在载体上固化的图像和表面涂层的印刷材料，（E）成型印刷材料的步骤。 还提供了通过生产模制印刷材料的方法获得的模制印刷材料。

公开(公告)号：US20080075882A1

公开(公告)日：2008-03-27

申请号：US11860077

申请日：2007-09-24

申请人： Yuuichi HAYATA

发明人： Yuuichi HAYATA

IPC分类号： B29C71/02

CPC分类号： B29C71/02 ,  B29C59/02 ,  B29C2035/0833 ,  B41M5/0023 ,  B41M7/0081 ,  C09D11/101 ,  C09D11/30

摘要： A process for producing a molded printed material is provided that includes (A) a step of forming an image by discharging an ink composition on a support by an inkjet method, the ink composition comprising at least 60 wt % relative to the entire ink composition of at least one monofunctional radically polymerizable monomer having only one unsaturated double bond group selected from the group consisting of an acrylate group, a methacrylate group, an acrylamide group, a methacrylamide group, and an N-vinyl group and having at least one cyclic structure-containing group, (B) a step of curing the ink composition by irradiating with actinic radiation the image obtained so as to obtain a printed material having the image cured on the support, and (C) a step of molding the printed material. There is also provided a molded printed material obtained by the process for producing a molded printed material.

摘要翻译： 提供了一种生产模制印刷材料的方法，其包括（A）通过喷墨方法将油墨组合物排放在载体上形成图像的步骤，该油墨组合物相对于整个油墨组合物包含至少60重量％ 至少一种仅具有选自丙烯酸酯基，甲基丙烯酸酯基，丙烯酰胺基，甲基丙烯酰胺基和N-乙烯基中的一个不饱和双键基团的至少一个单官能自由基聚合单体，并且具有至少一个环状结构 - （B）通过用光化辐射照射获得的图像以获得具有在载体上固化的图像的印刷材料来固化油墨组合物的步骤，（C）成型印刷材料的步骤。 还提供了通过生产模制印刷材料的方法获得的模制印刷材料。

公开(公告)号：US20130016166A1

公开(公告)日：2013-01-17

申请号：US13547488

申请日：2012-07-12

申请人： Yuuichi HAYATA

发明人： Yuuichi HAYATA

IPC分类号： B41J2/01 ,  C09D11/10

CPC分类号： C09D11/101 ,  B41J2/2107 ,  C09D11/322

摘要： An ink composition is provided that comprises at least (Component A-1) diethylene glycol monobutyl ether acrylate, (Component A-2) at least one compound selected from the group consisting of a compound represented by Formula (1), phenoxyethyl acrylate, isobornyl acrylate, 3,3,5-trimethylcyclohexyl acrylate, and 4-t-butylcyclohexyl acrylate, (Component A-3) an N-vinyllactam and/or tetrahydrofurfuryl acrylate, and (Component B) a polymerization initiator, Component A-1 having a content of 1 to 35 wt % of the entire ink composition, and Components A-1 to A-3 having a total content of 60 to 90 wt % of the entire ink composition wherein R1 denotes a hydrogen atom or a methyl group and X denotes a single bond or a divalent linking group.

摘要翻译： 提供一种油墨组合物，其至少包含（组分A-1）二甘醇单丁醚丙烯酸酯，（组分A-2）至少一种选自由式（1）表示的化合物，丙烯酸苯氧基乙酯，异冰片基 丙烯酸酯，丙烯酸3,3,5-三甲基环己酯和丙烯酸4-叔丁基环己酯（组分A-3），N-乙烯基内酰胺和/或四氢糠基丙烯酸酯，和（组分B）聚合引发剂，组分A-1 含量为整个油墨组合物的1至35重量％，以及其中R 1表示氢原子或甲基且X表示全部油墨组合物的总含量为60至90重量％的组分A-1至A-3 单键或二价连接基团。

公开(公告)号：US20120069082A1

公开(公告)日：2012-03-22

申请号：US13238971

申请日：2011-09-21

申请人： Yuuichi HAYATA

发明人： Yuuichi HAYATA

IPC分类号： B41J2/015

CPC分类号： B41M5/0023 ,  B41J2/01 ,  B41J2/2107 ,  B41M5/0011 ,  B41M7/0081 ,  C09D11/101 ,  C09D11/322 ,  C09D11/40

摘要： An inkjet recording method is provided in which image formation is carried out by employing an ink set, the inks of each color including a polymerizable compound and a polymerization initiator, and discharge of the inks being repeated 2 to 16 times for the same area.

摘要翻译： 提供一种喷墨记录方法，其中通过使用油墨组，每种颜色的油墨包括可聚合化合物和聚合引发剂进行图像形成，并且对于相同的区域，油墨的排出重复2至16次。