公开(公告)号：US20100079845A1

公开(公告)日：2010-04-01

申请号：US12242917

申请日：2008-10-01

申请人： Zhongchun Wang ,  Paul P. Nguyen

发明人： Zhongchun Wang ,  Paul P. Nguyen

IPC分类号： G02F1/153

CPC分类号： G02F1/155 ,  G02F1/19

摘要： An all-solid-state electrochromic device comprises a transparent base material, and an electrochromic multilayer-stack structure formed on the transparent base material. The electrochromic multilayer-stack structure comprises a first transparent-conductive film formed on the transparent base material, an ion-storage layer formed on the first transparent-conductive film, a solid-electrolyte layer formed on the ion-storage layer, and an electrochromic layer formed on the solid-electrolyte layer. The electrochromic layer comprises a reflection-controllable electrochromic layer. In one exemplary embodiment, the electrochromic layer comprises a reflection-controllable layer that comprises at least one of antimony and an antimony-based alloy. A second transparent-conductive film can be formed on the reflection-controllable layer, or between the reflection-controllable layer and the solid-electrolyte layer. In one exemplary embodiment, the second transparent-conductive layer comprises a base metal and/or a base metal alloy.

摘要翻译： 全固体电致变色装置包括透明基材和形成在透明基材上的电致变色多层堆叠结构。 电致变色多层堆叠结构包括形成在透明基材上的第一透明导电膜，形成在第一透明导电膜上的离子存储层，形成在离子保存层上的固体电解质层和电致变色 层，形成在固体电解质层上。 电致变色层包括反射可控电致变色层。 在一个示例性实施例中，电致变色层包括反射可控层，其包含锑和锑基合金中的至少一种。 第二透明导电膜可以形成在反射可控层上，或反射可控层和固体电解质层之间。 在一个示例性实施例中，第二透明导电层包括贱金属和/或贱金属合金。

公开(公告)号：US07804635B1

公开(公告)日：2010-09-28

申请号：US12407950

申请日：2009-03-20

申请人： Zhongchun Wang ,  Paul P. Nguyen ,  Jeremy Alexander Dixon

发明人： Zhongchun Wang ,  Paul P. Nguyen ,  Jeremy Alexander Dixon

IPC分类号： G02F1/153 ,  G02F1/01 ,  G02F1/15 ,  C09K9/00

CPC分类号： C09K9/00

摘要： One exemplary embodiment of an electrochromic thin-film material comprises a metal-chalcogen compound; and/or a mixture or solid solution of one or more metal-rich metal-chalcogen compounds and/or lithium. One or more of the metals comprise Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Sb, or Bi, or combinations thereof; and one or more of the chalcogens comprise O, S, Se, or Te, or combinations thereof.

摘要翻译： 电致变色薄膜材料的一个示例性实施方案包括金属 - 硫属化合物; 和/或一种或多种富金属金属 - 硫属化合物和/或锂的混合物或固溶体。 一种或多种金属包括Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Sb或Bi，或其组合; 并且一个或多个硫属元素包括O，S，Se或Te，或其组合。

公开(公告)号：US20100238535A1

公开(公告)日：2010-09-23

申请号：US12407950

申请日：2009-03-20

申请人： Zhongchun Wang ,  Paul P. Nguyen ,  Jeremy A. Dixon

发明人： Zhongchun Wang ,  Paul P. Nguyen ,  Jeremy A. Dixon

IPC分类号： G02F1/153 ,  C09K9/00

CPC分类号： C09K9/00

摘要： One exemplary embodiment of an electrochromic thin-film material comprises a metal-chalcogen compound; and/or a mixture or solid solution of one or more metal-rich metal-chalcogen compounds and/or lithium. One or more of the metals comprise Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Sb, or Bi, or combinations thereof; and one or more of the chalcogens comprise O, S, Se, or Te, or combinations thereof.

摘要翻译： 电致变色薄膜材料的一个示例性实施方案包括金属 - 硫属化合物; 和/或一种或多种富金属金属 - 硫属化合物和/或锂的混合物或固溶体。 一种或多种金属包括Ti，Zr，Hf，V，Nb，Ta，Cr，Mo，W，Mn，Sb或Bi，或其组合; 并且一个或多个硫属元素包括O，S，Se或Te，或其组合。

公开(公告)号：US07646526B1

公开(公告)日：2010-01-12

申请号：US12242897

申请日：2008-09-30

申请人： Zhongchun Wang ,  Paul P. Nguyen

发明人： Zhongchun Wang ,  Paul P. Nguyen

IPC分类号： G02F1/153 ,  G02F1/03 ,  G09G3/34

CPC分类号： C03C17/06 ,  C03C2217/27 ,  C22C12/00 ,  C23C14/185 ,  G02F1/1508 ,  G02F1/1523 ,  G02F1/153 ,  G02F2001/1536 ,  G02F2201/34

摘要： One exemplary embodiment of an electrochromic thin-film material comprises an alloy of antimony and one or more base metals; and/or an alloy of antimony, one or more base metals, and lithium; and/or an alloy of antimony, one or more base metals, lithium, and one or more noble metals. Another exemplary embodiment of an electrochromic thin-film material comprises a multilayer stack, the multilayer stack comprising at least one layer comprising one of antimony, antimony-lithium alloy, antimony-one or more base metals alloy, antimony-one or more base metals-lithium alloy, antimony-one or more base metals-one or more noble metals alloy, and antimony-one or more base metals-one or more noble metals-lithium alloy; and at least one alternating layer comprising one of a base metal and a base-metal alloy. One or more of the base metals comprise Co, Mn, Ni, Fe, Zn, Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W, Cd, Mg, Al, Ga, In, Sn, Pb, and Bi, and alloys thereof.

摘要翻译： 电致变色薄膜材料的一个示例性实施方案包括锑和一种或多种贱金属的合金; 和/或锑，一种或多种贱金属和锂的合金; 和/或锑，一种或多种贱金属，锂和一种或多种贵金属的合金。 电致变色薄膜材料的另一示例性实施方案包括多层叠层，所述多层叠层包括至少一层，包括锑，锑 - 锂合金，锑 - 一种或多种贱金属合金，锑 - 一种或多种贱金属 - 锂合金，锑 - 一种或多种贱金属 - 一种或多种贵金属合金和锑 - 一种或多种贱金属 - 一种或多种贵金属 - 锂合金; 以及包含贱金属和贱金属合金之一的至少一个交替层。 一种或多种贱金属包括Co，Mn，Ni，Fe，Zn，Ti，V，Cr，Zr，Nb，Mo，Hf，Ta，W，Cd，Mg，Al，Ga，In，Sn，Pb， 和Bi及其合金。

公开(公告)号：US08031389B2

公开(公告)日：2011-10-04

申请号：US12242917

申请日：2008-10-01

申请人： Zhongchun Wang ,  Paul P. Nguyen

发明人： Zhongchun Wang ,  Paul P. Nguyen

IPC分类号： G02F1/153

CPC分类号： G02F1/155 ,  G02F1/19

摘要： An all-solid-state electrochromic device comprises a transparent base material, and an electrochromic multilayer-stack structure formed on the transparent base material. The electrochromic multilayer-stack structure comprises a first transparent-conductive film formed on the transparent base material, an ion-storage layer formed on the first transparent-conductive film, a solid-electrolyte layer formed on the ion-storage layer, and an electrochromic layer formed on the solid-electrolyte layer. The electrochromic layer comprises a reflection-controllable electrochromic layer. In one exemplary embodiment, the electrochromic layer comprises a reflection-controllable layer that comprises at least one of antimony and an antimony-based alloy. A second transparent-conductive film can be formed on the reflection-controllable layer, or between the reflection-controllable layer and the solid-electrolyte layer. In one exemplary embodiment, the second transparent-conductive layer comprises a base metal and/or a base metal alloy.

摘要翻译： 全固体电致变色装置包括透明基材和形成在透明基材上的电致变色多层堆叠结构。 电致变色多层堆叠结构包括形成在透明基材上的第一透明导电膜，形成在第一透明导电膜上的离子存储层，形成在离子保存层上的固体电解质层和电致变色 层，形成在固体电解质层上。 电致变色层包括反射可控电致变色层。 在一个示例性实施例中，电致变色层包括反射可控层，其包含锑和锑基合金中的至少一种。 第二透明导电膜可以形成在反射可控层上，或反射可控层和固体电解质层之间。 在一个示例性实施例中，第二透明导电层包括贱金属和/或贱金属合金。

公开(公告)号：US07715082B2

公开(公告)日：2010-05-11

申请号：US12165292

申请日：2008-06-30

申请人： Zhongchun Wang ,  Paul P. Nguyen

发明人： Zhongchun Wang ,  Paul P. Nguyen

IPC分类号： G02F1/153 ,  G02F1/01 ,  G09G3/19 ,  G09G3/38

CPC分类号： G02F1/1523 ,  G02F1/153

摘要： An electrochromic switching device comprises a counter electrode, an active electrode and an electrolyte layer disposed between the counter electrode and the active electrode. The active electrode comprises at least one of an oxide, a nitride, an oxynitrides, a partial oxide, a partial nitride and a partial oxynitride of at least one of Sb, Bi, Si, Ge, Sn, Te, N, P, As, Ga, In, Al, C, Pb and I. Upon application of a current to the electrochromic switching device, a compound comprising at least one of the alkali and the alkaline earth metal ion and an element of the active electrode is formed as part of the active electrode.

摘要翻译： 电致变色开关装置包括对电极，有源电极和设置在对电极和有源电极之间的电解质层。 有源电极包括Sb，Bi，Si，Ge，Sn，Te，N，P，As中的至少一种的氧化物，氮化物，氮氧化物，部分氧化物，部分氮化物和部分氧氮化物中的至少一种 Ga，In，Al，C，Pb和I.当向电致变色开关装置施加电流时，将包含碱金属和碱土金属离子中的至少一种的化合物和有源电极的元素形成为部分 的活性电极。

公开(公告)号：US20090323158A1

公开(公告)日：2009-12-31

申请号：US12165292

申请日：2008-06-30

申请人： Zhongchun Wang ,  Paul P. Nguyen

发明人： Zhongchun Wang ,  Paul P. Nguyen

IPC分类号： G02F1/153

CPC分类号： G02F1/1523 ,  G02F1/153

摘要： An electrochromic switching device comprises a counter electrode, an active electrode and an electrolyte layer disposed between the counter electrode and the active electrode. The active electrode comprises at least one of an oxide, a nitride, an oxynitrides, a partial oxide, a partial nitride and a partial oxynitride of at least one of Sb, Bi, Si, Ge, Sn, Te, N, P, As, Ga, In, Al, C, Pb and I. Upon application of a current to the electrochromic switching device, a compound comprising at least one of the alkali and the alkaline earth metal ion and an element of the active electrode is formed as part of the active electrode.

摘要翻译： 电致变色开关装置包括对电极，有源电极和设置在对电极和有源电极之间的电解质层。 有源电极包括Sb，Bi，Si，Ge，Sn，Te，N，P，As中的至少一种的氧化物，氮化物，氮氧化物，部分氧化物，部分氮化物和部分氧氮化物中的至少一种 Ga，In，Al，C，Pb和I.当向电致变色开关装置施加电流时，将包含碱金属和碱土金属离子中的至少一种的化合物和有源电极的元素形成为部分 的活性电极。

公开(公告)号：US11916192B2

公开(公告)日：2024-02-27

申请号：US17185159

申请日：2021-02-25

申请人： Zhongchun Wang ,  Arvind Kamath

发明人： Zhongchun Wang ,  Arvind Kamath

IPC分类号： H01M10/0562 ,  H01M10/0525 ,  H01M10/0585 ,  H01M4/62 ,  H01M4/36 ,  H01M4/02

CPC分类号： H01M10/0562 ,  H01M4/366 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/0585 ,  H01M2004/027 ,  H01M2300/0071 ,  H01M2300/0094

摘要： A multilayer solid-state electrolyte, solid-state battery cells including the same, and methods of making the electrolyte and the battery cells are disclosed. The multi-layer solid-state electrolyte includes a solid bulk electrolyte layer comprising carbon-doped lithium phosphorus oxynitride (LiPON) or WO3+x (where 0≤x≤1), and a solid anode interface layer comprising LiPON or a metal oxide that forms a stable complex oxide with lithium oxide and conducts lithium ions when lithiated. The anode interface layer has a thickness less than that of the bulk electrolyte layer. The method of making the multi-layer solid-state electrolyte includes depositing one of the solid bulk electrolyte layer and the solid anode interface layer on an active layer of a battery cell, then depositing the other layer on the one layer. As for the solid-state electrolyte, the anode interface layer has a thickness less than that of the bulk electrolyte layer.

公开(公告)号：US08749868B2

公开(公告)日：2014-06-10

申请号：US13610684

申请日：2012-09-11

申请人： Zhongchun Wang ,  Anshu Pradhan ,  Robert Rozbicki

发明人： Zhongchun Wang ,  Anshu Pradhan ,  Robert Rozbicki

IPC分类号： G02F1/15

CPC分类号： G02F1/155 ,  C23C14/083 ,  C23C14/34 ,  C23C14/5806 ,  G02F1/1508 ,  G02F1/1523 ,  G02F1/153 ,  G02F2001/1555 ,  H01J37/3426

摘要： Conventional electrochromic devices frequently suffer from poor reliability and poor performance. Improvements are made using entirely solid and inorganic materials. Electrochromic devices are fabricated by forming an ion conducting electronically insulating interfacial region that serves as an IC layer. In some methods, the interfacial region is formed after formation of an electrochromic and a counter electrode layer. The interfacial region contains an ion conducting electronically insulating material along with components of the electrochromic and/or the counter electrode layer. Materials and microstructure of the electrochromic devices provide improvements in performance and reliability over conventional devices.

公开(公告)号：US08389715B1

公开(公告)日：2013-03-05

申请号：US12756744

申请日：2010-04-08

申请人： John A. Shelnutt ,  Kathleen E. Martin ,  Zhongchun Wang ,  Craig J. Medforth

发明人： John A. Shelnutt ,  Kathleen E. Martin ,  Zhongchun Wang ,  Craig J. Medforth

IPC分类号： C07D487/00 ,  C07B47/00

CPC分类号： C07D487/22

摘要： A nanostructured molecular unit and method for forming is described where a cationic porphyrin having an ethanolic substituent species and a metal in the porphyrin cavity is combined with an anionic porphyrin having a sulfonate substituent species and a metal in the porphyrin cavity to form by self-assembly a nanostructured molecular unit with a morphology comprising four dendritic elements connected at a central node.

摘要翻译： 描述了纳米结构分子单元和形成方法，其中在卟啉空腔中具有乙醇取代基物质和金属的阳离子卟啉与卟啉空穴中具有磺酸盐取代基物质和金属的阴离子卟啉与自组装形成 具有形式的纳米结构分子单元，其包含在中心节点处连接的四个树突状元件。