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公开(公告)号:US20220112361A1
公开(公告)日:2022-04-14
申请号:US17500302
申请日:2021-10-13
申请人: Sennics Co., Ltd.
发明人: Yang GAO , Jin ZHANG , Zhimin TANG
摘要: A formulation for rubber composition with reduced odor and good thermal oxidative aging-resistance and tension fatigue resistance comprising 100 parts by weight of a diene elastomer, 30 to 70 parts by weight of a reinforcing filler, 0.1 to 8 parts by weight of an antidegradant composition, and 0.5 to 3 parts by weight of a crosslinker, wherein the antidegradant composition includes a 6PPD antidegradant with a purity of equal to or greater than about 98% and an S-TMQ. The rubber composition has no added odor inhibitor/adsorbent or deodorizing additive, while by using combination of 6PPD with purity of equal to or greater than about 98% and an S-TMQ instead of traditional combination of 6PPD and a TMQ, the VOC emission of the rubber composition is effectively reduced, the odor grade is reduced, and the thermal oxidative aging-resistance and tension fatigue resistance is improved.
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公开(公告)号:US20210230099A1
公开(公告)日:2021-07-29
申请号:US17226951
申请日:2021-04-09
申请人: Sennics Co, Ltd.
IPC分类号: C07C211/55 , B60C1/00 , C08L21/00
摘要: Antidegradant composition comprising a first compound of Formula I: and a second antidegradant that is not the compound of Formula I; and rubber composition comprising the antidegradant composition. The rubber composition has good resistance to appearance discoloration while maintaining the mechanical and anti-aging properties, thus, are suitable for making the entire tire or as part of the rubber matrix.
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公开(公告)号:US10793510B2
公开(公告)日:2020-10-06
申请号:US15956618
申请日:2018-04-18
申请人: Sennics Co., Ltd.
发明人: Xiangyun Guo , Jinguo Xing , Xiaomin Ruan , Xinmin Chen
IPC分类号: C07C209/60 , C07C209/68 , C07C211/55
摘要: A method for preparing an aryl substituted p-phenylenediamine substance is provided. A structural formula of the aryl substituted p-phenylenediamine substance is shown as Formula (I′), where each of R′ and R″ is phenyl or o-methylphenyl, and R′ is same as or different from R″; and the method comprises that: a raw material A and a raw material B are reacted in the presence of a hydrogen acceptor and a catalyst to form the aryl substituted p-phenylenediamine substance, the raw material A having a structure shown as Formula (I), the raw material B being cyclohexanone and/or o-methylcyclohexanone and the hydrogen acceptor being a hydrogen acceptor capable of accepting hydrogen for conversion into the raw material B. Raw materials are low in cost and readily available; use of a large amount of water for post-treatment is avoided. The reaction condition is relatively mild, and corrosion to equipment is avoided.
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公开(公告)号:US20220153964A1
公开(公告)日:2022-05-19
申请号:US17526965
申请日:2021-11-15
申请人: Sennics Co., Ltd.
IPC分类号: C08K5/3492 , C08K5/18 , C08J3/22 , B60C1/00 , C08K5/09
摘要: An antidegradant composition, an antidegradant master batch comprising the antidegradant composition and a rubber composition comprising the antidegradant composition or the antidegradant master batch. The antidegradant composition comprises antidegradant TMPPD and one or two selected from antidegradant N3100-B and an antidegradant N3100-C. The antidegradant composition and antidegradant master batch render a rubber compound and a rubber article excellent discoloration resistance, fatigue resistance, ozone resistance, and mechanical properties before and after thermal oxidative aging and enables the rubber compound to be used in the manufacture of all or part of the rubber matrix, especially as a tire sidewall rubber composition and a tire tread rubber composition.
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公开(公告)号:US10829615B2
公开(公告)日:2020-11-10
申请号:US16217006
申请日:2018-12-11
申请人: Sennics Co., Ltd.
摘要: Novel and long-acting rubber anti-degradant and rubber composition comprising the same for tires. The anti-degradant comprises at least two compounds, each of which is selected from a compound of Formula I, II, III-a, or III-b: and each of the compounds have different formulae from others, and can't be compounds of formula III-a and III-b at the same time when the anti-degradant consists of only 2 compounds. The anti-degradant is used to provide a rubber composition with improved long-term resistance to thermo-oxidative aging and ozone aging.
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6.
公开(公告)号:US20190375913A1
公开(公告)日:2019-12-12
申请号:US16217006
申请日:2018-12-11
申请人: Sennics Co., Ltd.
摘要: Novel and long-acting rubber anti-degradant and rubber composition comprising the same for tires. The anti-degradant comprises at least two compounds, each of which is selected from a compound of Formula I, II, III-a, or III-b: and each of the compounds have different formulae from others, and can't be compounds of formula III-a and III-b at the same time when the anti-degradant consists of only 2 compounds. The anti-degradant is used to provide a rubber composition with improved long-term resistance to thermo-oxidative aging and ozone aging.
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公开(公告)号:US20180237376A1
公开(公告)日:2018-08-23
申请号:US15956618
申请日:2018-04-18
申请人: Sennics Co., Ltd.
发明人: Xiangyun GUO , Jinguo Xing , Xiaomin Ruan , Xinmin Chen
IPC分类号: C07C209/60 , C07C211/55
摘要: A method for preparing an aryl substituted p-phenylenediamine substance is provided. A structural formula of the aryl substituted p-phenylenediamine substance is shown as Formula (I′), where each of R′ and R″ is phenyl or o-methylphenyl, and R′ is same as or different from R″; and the method comprises that: a raw material A and a raw material B are reacted in the presence of a hydrogen acceptor and a catalyst to form the aryl substituted p-phenylenediamine substance, the raw material A having a structure shown as Formula (I), the raw material B being cyclohexanone and/or o-methylcyclohexanone and the hydrogen acceptor being a hydrogen acceptor capable of accepting hydrogen for conversion into the raw material B. Raw materials are low in cost and readily available; use of a large amount of water for post-treatment is avoided. The reaction condition is relatively mild, and corrosion to equipment is avoided.
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公开(公告)号:US20230042687A1
公开(公告)日:2023-02-09
申请号:US17547214
申请日:2021-12-09
申请人: Sennics Co., Ltd.
发明人: Hao WANG , Yang GAO , Yousheng HE
摘要: A rubber protective wax, comprising hydrocarbon compounds, a polyethylene wax and an antidegradant. The rubber protective wax of the present invention can render rubber good thermal oxidative aging resistance, static ozone aging resistance, dynamic ozone aging resistance, flex cracking resistance and tensile fatigue resistance, and has good protection effects in both static environment and dynamic load environment.
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9.
公开(公告)号:US20220306590A1
公开(公告)日:2022-09-29
申请号:US17736074
申请日:2022-05-03
申请人: Sennics Co., Ltd.
发明人: Xiangyun GUO , Jinguo XING , Yanxiang LIU , Hui LI , Yang GAO , Zhimin TANG , Haibo ZHU , Qi QI
IPC分类号: C07D251/70 , C08K5/3492 , B60C1/00
摘要: A compound having anti-aging and discoloration resistance effects and a preparation method therefor are provided. The structure of the compound is represented by formula (I). The compound provides longer-lasting anti-aging performance, and has discoloration resistance. The compound may be used as an anti-aging agent in rubber products, especially rubber tires, and can prevent the aging and deterioration of rubber products or rubber tires due to light, heat, oxygen, and fatigue, during use.
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公开(公告)号:US11008281B2
公开(公告)日:2021-05-18
申请号:US16721894
申请日:2019-12-19
申请人: Sennics Co., Ltd.
IPC分类号: C07C211/55 , B60C1/00 , C08L21/00
摘要: Antidegradant compound of Formula I: and antidegradant composition comprising the same and rubber composition comprising the antidegradant compound or composition. The rubber composition has good resistance to appearance discoloration while maintaining the mechanical and anti-aging properties, thus, are suitable for making the entire tire or as part of the rubber matrix.
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