WHEREIN R IS SELECTED FROM HYDROGEN AND ALKYL GROUPS OF 1 TO 6 CARBON ATOMS, Z IS SELECTED FROM CHLORINE, BROMINE, IODINE AND -NO2, P IS 2 TO 6 AND THE RATIO M:N IS FROM 1:1 TO 50:1. THE LIQUID PREPOLYMERS MAY BE PREPARED BY COPOLYMERIZING PERFLUORONITROSOMETHANE, TETRAFLUOROETHYLENE AND A NITROSOPERFLUORO ACID OR ESTER IN THE PRESENCE OF A TERMINATOR WHICH MAY BE CHLORINE, BROMINE, IODINE OR NITORGEN DIOXIDE. THE POLYMERS CAN BE CURED WITH SUCH CURING AGENTS AS EPOXIDES, METAL OXIDES AND CHROMIUM PERFLUOROACETATE TO PRODUCE RUBBERS HAVING GOOD PHYSICAL PROPERTIES AND CHEMICAL RESISTANCE.
摘要:
CURED NITROSO RUBBERS ARE PROVIDED BY CURING TERPLOYMERS OF MIXTURES OF THREE FLUORINATED MONOMERS INCLUDING A 4-BROMO-2,3,5,6-TETRAFLUORONITROSOBENZENE OR 4-CARBOXY-2,3,5,6-TETRAFLUORONITROSOBENZENE.
摘要:
Fluorinated oligomers, polymers, and copolymers including poly[[1,1 ′-biphenyl]-4,4′-diyl[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]] and other compounds useful for high performance polymer, electronic, aerospace, coatings, and high temperature gas separation applications. Also provided are methods for synthesizing fluorinated polymer derivatives.