摘要:
Method for collecting and concentrating charged species, specifically, contaminant species in a medium, preferably soil. The method utilizes electrokinesis to drive contaminant species into and through a bed adjacent to a drive electrode. The bed comprises a moderately electrically conductive adsorbent material which is porous and is infused with water or other solvent capable of conducting electrical current. The bed material, preferably activated carbon, is easily removed and disposed of. Preferably, where activated carbon is used, after contaminant species are collected and concentrated, the mixture of activated carbon and contaminant species is removed and burned to form a stable and easily disposable waste product.
摘要:
A bipolar cell for the electrowinning of aluminium has bipolar electrodes each comprising a carbon cathode body having on one side an active surface on which aluminium is produced and connected on the other side through an oxygen impermeable barrier layer to an electrochemically active anode layer having an oxygen evolving iron oxide-based outer surface. The anode layer may comprise a metal-based anode substrate and a transition metal oxide-based outside layer, in particular an iron oxide-based outside layer, which either is an applied layer or is obtainable by oxidising the surface of the anode substrate which contains iron. During operation, the anode layer can be kept dimensionally stable by maintaining in the electrolyte a concentration of transition metal species which are present as one or more corresponding transition metal oxides in the electrochemically-active layer. The cell operating temperature is sufficiently low so that the required concentration The cell operating temperature is sufficiently low so that the required concentration of transition metal species in the electrolyte is limited by the reduced solubility thereof in the electrolyte at the operating temperature. This limits the contamination of the product aluminium by the transition metal species to an acceptable level.
摘要:
A non-carbon, metal-based, high temperature resistant, electrically conductive and electrochemically active anode of a cell for the production of aluminum has a metal-based oxidation-resistant substrate to which an adherent multi-layer coating is applied prior to its immersion into the electrolyte and start up of the electrolysis by connection to the positive current supply. The multi-layer coating is obtainable from one or more applied layers selected from: a liquid solution, a dispersion in a liquid or a paste, a suspension in a liquid or a paste, and a pasty or non-pasty slurry, and combinations thereof, with or without heat treatment between two consecutively applied layers. At least one layer of the multi-layer coating contains a polymeric and/or a colloidal carrier. The coating is after final heat treatment electrically conductive and has during operation in the cell an electrochemically active surface for the oxidation of oxygen ions present at the surface of the anode.
摘要:
An amperometric in situ apparatus and technique for measuring the concentrations and transport properties of easily dissociable oxides in slags is described. The technique consists of a combination of different measurements utilizing an electrolyte to separate a reference-gas compartment from the slag of interest. A method and apparatus for metals extraction is also described which includes a vessel for holding a molten electrolyte, the electrolyte comprising a mobile metallic species and an anionic species having a diffusivity greater than about 10−5 cm2/sec; a cathode and an anode, the cathode in electrical contact with the molten metal electrolyte, the cathode and molten electrolyte separated from the anode by an ionic membrane capable of transporting the anionic species of the electrolyte into the membrane; and a power source for generating a potential between the cathode and the anode.
摘要:
A solid material (12′) circumscribing an anode system (10) in an electrolysis apparatus is made from a mixture of cryolite and/or alumina (Al2O3), where the solid material (12′) contacts and surrounds the anodes (14, 14′).
摘要翻译:在电解装置中限定阳极系统(10)的固体材料(12')由冰晶石和/或氧化铝(Al 2 O 3)的混合物制成,其中固体材料(12')接触并围绕阳极(14,14) ')。
摘要:
A cell for the electrowinning of aluminium comprises at least one non-carbon metal-based anode (10) having an electrically conductive metallic structure (12, 13, 15) which is suspended substantially parallel to a facing cathode (20, 21, 22). Such metallic structure (12, 13, 15) comprises a series of parallel horizontal anode members (15), each having an electrochemically active surface (16) on which during electrolysis oxygen is anodically evolved. The electrochemically active surfaces (16) are in a generally coplanar arrangement to form the active anode surface. The anode members are spaced apart from one another by inter-member gaps forming flow-through openings (17) for the circulation of electrolyte (30) driven by the escape of anodically-evolved oxygen. The electrolyte (30) may circulate upwardly and/or downwardly in the flow-through openings (17) and possibly around the anode structure (12, 13, 15).
摘要:
St. John's Wort products which have enhanced bioactivity in a serotonin re-uptake assay and enhanced stability are identified and manufactured from Hypericum perforatum biomass with supercritical and near critical fluids with and without polar cosolvents. These fluids are used to fractionate the biomass materials in several sequential steps. In each step, the biomass is subjected to a multiplicity of supercritical or near critical fluid extraction steps, with different solvation conditions used for each fraction. Thus, fractionation of the biomass is effected and the St. John's Wort products are manufactured. In addition to excellent overall yield, the bioactivity and stability of the St. John's Wort products manufactured from Hypericum perforatum biomass with supercritical and near critical fluids with and without polar cosolvents are significantly higher than that obtained by conventional organic phase extraction.