公开(公告)号：WO2016094163A1

公开(公告)日：2016-06-16

申请号：PCT/US2015/063615

申请日：2015-12-03

Applicant: ARKEMA INC.

Inventor： PALYS, Leonard H. ,  DLUZNESKI, Peter R. ,  PAVLEK, William P. ,  DEFRANCISCI, Alfredo ,  CHANG, Feng-Jon ,  DESPOTOPOULOU, Marina ,  ABRAMS, Michael B. ,  BRENNAN, Joseph M. ,  TARTARIN, Isabelle

IPC: C08J3/24

CPC classification number: C08J3/242 ,  C08J2323/16 ,  C08K5/08 ,  C08K5/11 ,  C08K5/14 ,  C08K5/205 ,  C08K5/32 ,  C08K5/3435 ,  C08K5/3437 ,  C08K5/34924 ,  C08K5/36 ,  C08K5/40 ,  C08K5/47 ,  C08K5/524 ,  C08K2201/019 ,  C08L21/00

Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).

Abstract translation: 当在氧气存在下固化弹性体时，有机过氧化物配方的实施方案提供了表面粘性（通常包括无粘性表面）的显着改进。 过氧化物配方可以包括例如一种或多种选自含硫化合物，有机亚磷酸酯化合物，HALS（受阻胺光稳定剂）化合物，脂族烯丙基氨基甲酸酯化合物和包含氮氧化物（例如4-羟基-TEMPO） 和醌类（如单叔丁基氢醌）。

公开(公告)号：WO2014133853A1

公开(公告)日：2014-09-04

申请号：PCT/US2014/017276

申请日：2014-02-20

Applicant: ARKEMA INC.

Inventor： BRENNAN, Joseph M. ,  LYONS, Jason M. ,  PALYS, Leonard H.

IPC: E21B43/26

CPC classification number: C09K8/685 ,  C09K8/885 ,  C09K8/887 ,  C09K8/90 ,  C09K2208/26

Abstract: The addition of at least one promoter selected from the group consisting of thiosulfate salts, sulfite salts, bisulfite salts, erythorbate salts, isoascorbate salts, and combinations thereof to an aqueous treatment fluid containing a viscosifying polymer and a peroxide helps to promote the activity of the peroxide as a breaker, thus facilitating a reduction in viscosity of the aqueous treatment fluid at lower temperatures than are possible in the absence of the promoter. The promoted aqueous treatment fluid is useful as a fracture fluid to fracture subterranean formations in oil and gas recovery.

Abstract translation: 将选自硫代硫酸盐，亚硫酸盐，亚硫酸氢盐，异硫氰酸盐，异抗坏血酸盐及其组合的至少一种助催化剂加入到含有增粘聚合物和过氧化物的水性处理液中有助于促进 过氧化物作为破碎剂，从而有利于在不存在助催化剂的情况下在较低温度下降低水性处理流体的粘度。 促进的水处理流体可用作在油和气回收中破裂地下地层的断裂流体。

公开(公告)号：WO2016153792A1

公开(公告)日：2016-09-29

申请号：PCT/US2016/021656

申请日：2016-03-10

Applicant: ARKEMA INC.

Inventor： DESPOTOPOULOU, Marina ,  SWAN, Scot A. ,  PALYS, Leonard H. ,  BRENNAN, Joseph M. ,  ABRAMS, Michael B. ,  SCHWARTZ, Scott J.

IPC: C09K8/68 ,  C09K8/86 ,  C09K8/88

CPC classification number: C09K8/685 ,  C09K8/68 ,  C09K8/845 ,  C09K8/86 ,  C09K8/887 ,  C09K2208/26 ,  E21B43/26

Abstract: A breaker composition for use in a fracturing fluid comprises at least one organic peroxide (e.g., tert-butyl hydroperoxide), at least one dye (e.g., an FD&C dye), and at least one alcohol (e.g., propylene glycol). A promoter composition for use in a fracturing fluid comprises at least one promoter (e.g., sodium thiosulfate), at least one dye (e.g., an FD&C dye). According to certain embodiments, the dye increases the efficiency of the promoter and/or the organic peroxide, so that the break time and the peak viscosity of the aqueous treatment fluid are reduced.

Abstract translation: 用于压裂流体的破碎组合物包含至少一种有机过氧化物（例如叔丁基过氧化氢），至少一种染料（例如FD＆C染料）和至少一种醇（例如丙二醇）。 用于压裂流体的促进剂组合物包含至少一种促进剂（例如硫代硫酸钠），至少一种染料（例如FD＆C染料）。 根据某些实施方案，染料增加了促进剂和/或有机过氧化物的效率，使得水性处理流体的断裂时间和峰值粘度降低。

公开(公告)号：WO2016153791A1

公开(公告)日：2016-09-29

申请号：PCT/US2016/021654

申请日：2016-03-10

Applicant: ARKEMA INC.

Inventor： DESPOTOPOULOU, Marina ,  SWAN, Scot A. ,  PALYS, Leonard H. ,  BRENNAN, Joseph M. ,  ABRAMS, Michael B. ,  SCHWARTZ, Scott J.

IPC: C07C57/13 ,  C08F4/32 ,  C08K5/14 ,  C09B11/00

CPC classification number: C09B67/0083 ,  C08F4/32 ,  C08K5/0041 ,  C08K5/05 ,  C08K5/14

Abstract: Stable organic peroxide compositions include at least one organic peroxide (e.g., tert-butyl hydroperoxide), at least one dye (e.g., an FD&C dye), and at least one alcohol (e.g., propylene glycol, tert-butanol, and/or glycerin).

Abstract translation: 稳定的有机过氧化物组合物包括至少一种有机过氧化物（例如叔丁基过氧化氢），至少一种染料（例如FD＆C染料）和至少一种醇（例如丙二醇，叔丁醇和/或甘油 ）。

公开(公告)号：WO2016094164A1

公开(公告)日：2016-06-16

申请号：PCT/US2015/063617

申请日：2015-12-03

Applicant: ARKEMA INC.

Inventor： CHANG, Feng-Jon ,  PAVLEK, William P. ,  PALYS, Leonard H. ,  DLUZNESKI, Peter R. ,  DESPOTOPOULOU, Marina ,  DEFRANCISCI, Alfredo ,  BRENNAN, Joseph M. ,  ABRAMS, Michael B. ,  TARTARIN, Isabelle

IPC: C08L1/08

CPC classification number: C08L23/16 ,  C08J3/24 ,  C08J2323/16 ,  C08J2401/14 ,  C08L1/08 ,  C08L23/0869 ,  C08L2310/00 ,  C08L2312/00 ,  C08L1/14 ,  C08K5/14 ,  C08L1/10

Abstract: An organic peroxide formulation includes at least one organic peroxide and at least one cellulose compound. Embodiments of the organic peroxide formulations significant improvements in surface tackiness (often including but not limited to tack-free surfaces) when curing elastomers in the presence of oxygen. Embodiments of the present invention relate to organic peroxide formulations that can cure solid elastomers in the full or partial presence of oxygen using, for example, a hot air oven or tunnel, molten salt bath, or steam autoclave. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.

Abstract translation: 有机过氧化物制剂包括至少一种有机过氧化物和至少一种纤维素化合物。 当在氧气存在下固化弹性体时，有机过氧化物配方的实施方案显着改善了表面粘性（通常包括但不限于无粘性表面）。 本发明的实施方案涉及可以使用例如热空气烘箱或隧道，熔融盐浴或蒸汽高压釜在氧气全部或部分存在下固化固体弹性体的有机过氧化物配方。 本发明的实施方案还涉及可交联弹性体组合物，用于固化弹性体的方法，以及通过这些方法制备的产品。