公开(公告)号：WO2015171291A3

公开(公告)日：2016-12-15

申请号：PCT/US2015026587

申请日：2015-04-20

Applicant: UOP LLC

Inventor： MARTINS SUSIE C ,  BRODERICK ERIN M ,  NAFIS DOUGLAS A ,  DESALVO KAITLIN M ,  SMITH STUART ,  BHATTACHARYYA ALAKANANDA

IPC: C07C2/08 ,  B01J38/50 ,  C07C9/16 ,  C07F5/02 ,  C07F7/08

CPC classification number: C07C2/62 ,  B01J27/053 ,  B01J27/08 ,  B01J27/16 ,  B01J27/28 ,  B01J27/285 ,  B01J27/30 ,  B01J27/32 ,  B01J38/60 ,  C07C2/60 ,  C07C2527/125 ,  C07C2531/02 ,  C07C2531/22 ,  C10G50/00 ,  C10G2300/1092 ,  C10G2400/02 ,  Y02P20/584 ,  C07C9/21

Abstract: A hydrocarbon conversion process is described. The process includes contacting a hydrocarbon feed with an acidic catalyst under hydrocarbon conversion conditions in a hydrocarbon conversion zone. The hydrocarbon feed reacts to form a mixture comprising reaction products, the acidic catalyst, and deactivated acidic catalyst containing conjunct polymer. The mixture is separated into at least two streams, a first stream comprising the reaction products and a second stream comprising the deactivated acidic catalyst. The reaction products are recovered. The deactivated acidic catalyst is contacted with at least one silane or borane compound in a regeneration zone under regeneration conditions, the conjunct polymer reacting with the at least one silane or borane compound resulting in a catalyst phase and an organic phase containing the conjunct polymer and at least one silyl or boryl compound.

Abstract translation: 描述烃转化方法。 该方法包括在烃转化区的烃转化条件下使烃进料与酸性催化剂接触。 烃进料反应形成包含反应产物，酸性催化剂和含有结合聚合物的失活酸性催化剂的混合物。 将混合物分离成至少两股物流，包含反应产物的第一物流和包含失活的酸性催化剂的第二料流。 回收反应产物。 失活的酸性催化剂在再生条件下在再生区中与至少一种硅烷或硼烷化合物接触，该结合聚合物与至少一种硅烷或甲硼烷化合物反应，产生催化剂相和含有该结合聚合物的有机相， 至少一种甲硅烷基或硼基化合物。

公开(公告)号：WO2015171322A3

公开(公告)日：2016-12-22

申请号：PCT/US2015027200

申请日：2015-04-23

Applicant: UOP LLC

Inventor： MARTINS SUSIE C ,  NAFIS DOUGLAS A ,  BRODERICK ERIN M

IPC: C07F7/08 ,  C07C2/08 ,  C07F5/02

CPC classification number: C07F7/0801 ,  C07F5/027 ,  C07F7/083

Abstract: A method of regenerating a silyl or boryl compound is described. The silyl or boryl compound is contained in an organic phase with conjunct polymer. The silyl or boryl compound is chemically reduced with a hydrogen containing compound in a silane or borane regeneration zone under regeneration conditions to form at least one regenerated silane or borane compound and a metal salt compound. The regenerated silane or borane compound is recovered.

Abstract translation: 描述了再生甲硅烷基或硼基化合物的方法。 甲硅烷基或硼基化合物包含在具有结合聚合物的有机相中。 甲硅烷基或硼基化合物在再生条件下在硅烷或硼烷再生区中用含氢化合物化学还原，以形成至少一种再生的硅烷或硼烷化合物和金属盐化合物。 回收再生的硅烷或硼烷化合物。

公开(公告)号：WO2015171301A3

公开(公告)日：2017-02-16

申请号：PCT/US2015026769

申请日：2015-04-21

Applicant: UOP LLC

Inventor： BRODERICK ERIN M ,  BHATTACHARYYA ALAKANANDA ,  MARTINS SUSIE C ,  DESALVO KAITLIN M ,  NAFIS DOUGLAS A

IPC: B01J38/50 ,  C07C2/08 ,  C07F7/08

CPC classification number: B01J31/4053 ,  B01J31/0288 ,  B01J31/0298 ,  B01J31/4092 ,  B01J38/50 ,  B01J38/56 ,  B01J38/60 ,  B01J2231/64 ,  B01J2531/31

Abstract: A method of regenerating an acidic catalyst is described. A silane compound is contacted with an acidic catalyst that contains conjunct polymer, which releases the conjunct polymer from the acidic catalyst. The acidic catalyst can then be re-activated with acid. The conjunct polymer can be separated from the silane compound, and the silane compound can be recycled.

Abstract translation: 描述了酸性催化剂的再生方法。 硅烷化合物与含有结合聚合物的酸性催化剂接触，该酸性催化剂从酸性催化剂中释放出结合的聚合物。 酸性催化剂然后可以用酸重新活化。 可以将结合的聚合物与硅烷化合物分离，并且可以回收硅烷化合物。

公开(公告)号：WO2016094250A2

公开(公告)日：2016-06-16

申请号：PCT/US2015064030

申请日：2015-12-04

Applicant: UOP LLC

Inventor： DETRICK KURT ,  WEGERER DAVID A ,  SCHMIDT ROBERT J ,  PHAM TRUNG ,  BUCHBINDER AVRAM M ,  EDIRISINGHE PRANEETH D ,  MARTINS SUSIE C

IPC: C10G53/08

CPC classification number: C07C7/12 ,  B01J31/0277 ,  B01J31/4069 ,  B01J38/48 ,  B01J2231/44 ,  B01J2531/002 ,  B01J2531/008 ,  C07C2/74 ,  C07C7/13

Abstract: One or more processes for recovering entrained ionic liquid from a hydrocarbon phase containing droplets of ionic liquid are described. The processes includes contacting the hydrocarbon phase containing the droplets of ionic liquid with a retaining material in a separation zone. The droplets of ionic liquid are retained by the retaining material. The ionic liquid may be recovered from the retaining material with a solvent or desorbent. The retaining material may be regenerated and the ionic liquid may be reactivated. The retaining material may be used in a wash vessel to retain or remove contaminant solids within the reactor or other vessels.

Abstract translation: 描述了一种或多种从含有离子液体液滴的烃相中回收夹带的离子液体的方法。 该方法包括使含有离子液体液滴的烃相与保留材料在分离区中接触。 离子液体的液滴被保持材料保留。 离子液体可以用溶剂或解吸剂从保留材料中回收。 保持材料可以被再生并且离子液体可以被再活化。 保持材料可以用在洗涤容器中以保留或去除反应器或其他容器内的污染物固体。