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    METHOD FOR PREPARING COPOLYESTERCARBONATES
    12.
    发明申请
    METHOD FOR PREPARING COPOLYESTERCARBONATES 审中-公开
    制备共聚碳酸酯的方法

    公开(公告)号：WO2005019300A3

    公开(公告)日：2005-12-29

    申请号：PCT/US2004020892

    申请日：2004-06-30

    Applicant: GEN ELECTRIC ,  O'NEIL GREGORY ALLEN ,  ACAR ALI ERSIN ,  SYBERT PAUL DEAN ,  RANGARAJAN PRATIMA NMN ,  ZHOU HONGYI NMN ,  SURIANO JOSEPH ANTHONY

    Inventor： O'NEIL GREGORY ALLEN ,  ACAR ALI ERSIN ,  SYBERT PAUL DEAN ,  RANGARAJAN PRATIMA NMN ,  ZHOU HONGYI NMN ,  SURIANO JOSEPH ANTHONY

    IPC: C08F20/00 ,  C08G63/19 ,  C08G63/193 ,  C08G63/40 ,  C08G63/64

    CPC classification number: C08G63/64

    Abstract: A method of preparing block copolyestercarbonates wherein at least one dihydroxy­substituted aromatic hydrocarbon moiety and at least one aromatic diacid chloride are reacted under interfacial conditions to give a hydroxy-terminated polyester intermediate. The dihydroxy-substituted aromatic compound is used in about 10 mole to about 125 mole percent excess relative to the diacid chloride. Enhanced control of hydroxy-terminated polyester intermediate molecular weight is achieved by limiting the amount of water present to provide a final salt level of greater than 30 percent. The final salt level is a theoretical value but is readily calculable. The hydroxy­terminated polyester intermediate is then converted to a block copolyestercarbonate by reaction with a carbonate precursor such as phosgene.

    Abstract translation: 制备嵌段共聚酯碳酸酯的方法，其中至少一种二羟基取代的芳族烃部分和至少一种芳族二酰氯在界面条件下反应得到羟基封端的聚酯中间体。 二羟基取代的芳族化合物以相对于二酰氯为约10摩尔至约125摩尔％的过量使用。 羟基封端的聚酯中间体分子量的增强控制通过限制存在的水的量来提供大于30％的最终盐水平来实现。 最终的盐水平是理论值，但是很容易计算。 然后通过与诸如光气的碳酸酯前体反应将羟基封端的聚酯中间体转化成嵌段共聚酯碳酸酯。

    FUNCTIONAL POLYARYLETERS
    16.
    发明申请
    FUNCTIONAL POLYARYLETERS 审中-公开
    功能聚合物

    公开(公告)号：WO2008073537A1

    公开(公告)日：2008-06-19

    申请号：PCT/US2007/076221

    申请日：2007-08-17

    Applicant: GENERAL ELECTRIC COMPANY ,  ZHANG, Yanshi ,  STEIGER, Daniel ,  SURIANO, Joseph, Anthony ,  YEAGER, Gary, William

    Inventor： ZHANG, Yanshi ,  STEIGER, Daniel ,  SURIANO, Joseph, Anthony ,  YEAGER, Gary, William

    IPC: C08G75/23 ,  C08G65/38

    CPC classification number: C08G65/40 ,  C08G65/48 ,  C08G75/23

    Abstract: Membranes comprising functional polyarylether having structural units of formula (I) are useful for hemodialysis and hemofiltration, wherein X is selected from Br, NR 4 R 5 , OOCR 6 , OR 7 , NR 4 CONR 5 R 6 , NR 4 COOR 5 R 6 and combinations thereof; R 1 , R 2 and R 3 are independently at each occurrence CH 2 X, H, halo, cyano, nitro, a C 1 -C 12 aliphatic radical, a C 3 -C 12 cycloaliphatic radical, a C 3 -C 12 aromatic radical or a combination thereof; R 4 and R 5 are independently H, a C 1-10 aliphatic radical, a C 3 -C 12 cycloaliphatic radical, a C 3 -C 12 aromatic radical, or a combination thereof; R 6 is H, a C 2-10 aliphatic radical, a C 3 -C 12 cycloaliphatic radical, a C 3 -C 12 aromatic radical or a combination thereof; R 7 is OCH 2 CH 2 (OCH 2 CH 2 ) n OH or OOCCH 2 (OCH 2 CH 2 ) n CH 3 ; Z is a direct bond, O, S, SO, SO 2 , CO, phenylphospinyl oxide, alkenyl, alkynyl, a C 1 -C 12 aliphatic radical, a C 3 -C 12 cycloaliphatic radical, a C 3 -C 12 aromatic radical or a combination thereof; a, b, and c are independently 1 or 2; and m, n and p are independently 0 or 1.

    Abstract translation: 包含具有式（I）结构单元的官能聚芳醚的膜可用于血液透析和血液滤过，其中X选自Br，NR4R5，O0CR6 或，或者，NR 4，SEQ ID NO：5，NR 4， SUPER COOR＆lt; 5＆gt; 6＆lt; 6＆gt;及其组合; R 1，R 2和R 3在每次出现时独立地为CH 2 X，H，卤素，氰基 ，硝基，C 1 -C 12脂族基团，C 3 -C 12脂环族基团，C 1 -C 12 - C 3 -C 12芳族基团或其组合; R 4和R 5独立地是H，C 1-10烷基脂族基，C 3 -C 12脂环族基团，C 3 -C 12 - 芳族基团或其组合; R 6是H，C 2-10脂族基团，C 3 -C 12 - 脂环族基团， C 3 -C 12芳族基团或其组合; R 2是OCH 2 CH 2（OCH 2 CH 2 CH 2） ; Z是直接键，O，S，SO，SO 2，CO，苯基氧化烯，烯基，炔基，C 1 -C 12 >脂族基团，C 3 -C 12脂环族基团，C 3 -C 12芳族基团或C 3 -C 12 - 其组合; a，b和c独立地为1或2; m，n和p独立地为0或1。

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