COBALT CATALYSTS AND PRECURSORS THEREFOR
    43.
    发明申请

    公开(公告)号:WO2020183148A1

    公开(公告)日:2020-09-17

    申请号:PCT/GB2020/050568

    申请日:2020-03-10

    摘要: A cobalt catalyst precursor is described comprising cobalt oxide crystallites disposed within pores of a titania support, wherein the cobalt oxide crystallites have an average size as determined by XRD in the range 6 to 18nm, and the titania support is a spherical titania support with a particle size in the range 100 to 1000 μm, wherein the catalyst precursor has a pore volume of 0.2 to 0.6 cm 3 /g and an average pore diameter in the range 30 to 60 nm, and wherein the catalyst precursor has a ratio of the average cobalt oxide crystallite size to the average pore diameter in the range 0.1:1 to 0.6:1. The catalyst precursor may be reduced to provide catalysts suitable for use in Fisher-Tropsch reactions.

    一种自拟合纳米催化污水处理剂的生产方法

    公开(公告)号:WO2020150909A1

    公开(公告)日:2020-07-30

    申请号:PCT/CN2019/072734

    申请日:2019-01-22

    发明人: 龚家竹

    摘要: 一种自拟合纳米催化污水处理剂的生产方法,该方法是将硫酸法钛白粉工业生产的稀硫酸和钛原料,经过化学反应,控制酸钛比和铁钛比,生产纳米催化污水处理剂;用于印染污水及其它碱性污水处理时,借助于污水中的碱性和稀释环境,自拟合水解产生新生态纳米二氧化钛超细颗粒,作为污水中有机物分解的催化剂,将有机物分解为二氧化碳和水;分解氧化的水合铁化合物作为絮凝吸附纳米颗粒,达到污水去除有机物的目的。

    IMPROVED MIXED METAL OXIDE CATALYST USEFUL FOR PARAFFIN DEHYDROGENATION

    公开(公告)号:WO2020069480A1

    公开(公告)日:2020-04-02

    申请号:PCT/US2019/053710

    申请日:2019-09-28

    申请人: EXELUS, INC.

    摘要: The invention relates to a catalyst composition suitable for the dehydrogenation of paraffins having 2-8 carbon atoms comprising zinc oxide and titanium dioxide, optionally further comprising oxides of cerium (Ce), dysprosium (Dy), erbium (Er), europium (Eu), gadolinium (Gd), lanthanum (La), neodymium (Nd), praseodymium (Pr), samarium (Sm), terbium (Tb), ytterbium (Yb), yttrium (Y), tungsten (W) and Zirconium (Zr) or mixtures thereof, wherein said catalyst composition is substantially free of chromium and platinum. The catalysts possess unique combinations of activity, selectivity, and stability. Methods for preparing improved dehydrogenation catalysts and a process for dehydrogenating paraffins having 2-8 carbon atoms, comprising contacting the mixed metal oxide catalyst with paraffins are also described. The catalyst may also be disposed on a porous support in an attrition-resistant form and used in a fluidized bed reactor.