Abstract:
The present invention describes both a stretch-blow-molded opaque polyester container and a method of making it. The container, typically a beverage bottle has less than 15% transmission of visible light (500 nm) through a 0.4 millimeter wall thickness. It contains from about 0.1 to about 5wt. % of said opacifying material. The opacifying material may be any material compatible with polyester resin. The method of making the container includes introducing the opacifying material during polymerization, or prepared as a master batch for mixing with the polymer. Selection of certain opacifying materials can also result in favorable reheat properties, gas permeation-barrier improvements, and when the resin contains both opacifying material and oxygen scavenger there can be a synergistic effect with respect to CO 2 permeation.
Abstract:
Volatile organic compound or other materials are produced in the thermoplastic manufacture of thermoplastic polyester beverage containers. Such materials can be eluted into beverages such as carbonated beverages, sparkling or still water from the polyester. Such thermoplastic polyester resins can be manufactured with a material that can prevent the formation of, or react with, and absorb volatile by-products during the formation of thermoplastic preforms or containers from the thermoplastic pellet or chip. Further, as the preform is blown into a polyester container, the active materials of the invention prevent the generation of additional undesirable volatile materials. Lastly, the scavenger material can act as a barrier that prevents transport of materials from the exterior of the container into the container contents.
Abstract:
The present invention describes both a stretch-blow-molded opaque polyester container and a method of making it. The container, typically a beverage bottle has less than 15% transmission of visible light (500 nm) through a 0.4 millimeter wall thickness. It contains from about 0.1 to about 5wt. % of said opacifying material. The opacifying material may be any material compatible with polyester resin. The method of making the container includes introducing the opacifying material during polymerization, or prepared as a master batch for mixing with the polymer. Selection of certain opacifying materials can also result in favorable reheat properties, gas permeation-barrier improvements, and when the resin contains both opacifying material and oxygen scavenger there can be a synergistic effect with respect to CO 2 permeation.