公开(公告)号：WO2017021783A2

公开(公告)日：2017-02-09

申请号：PCT/IB2016/001258

申请日：2016-08-04

Applicant: THIN FILM ELECTRONICS ASA ,  NILSSON, Jakob ,  BROX-NILSEN, Christian

Inventor： NILSSON, Jakob ,  BROX-NILSEN, Christian

IPC: C08F8/00 ,  C08F214/22 ,  C08F214/18 ,  H01L41/193 ,  H01L37/02

CPC classification number: H01L21/0212 ,  C08F8/00 ,  C08F8/04 ,  C08F8/12 ,  C08F8/20 ,  C08F8/26 ,  C08F214/182 ,  C08F214/22 ,  C08F2500/02 ,  C08F2810/40 ,  H01L27/11507 ,  H01L27/1159 ,  H01L28/00 ,  H01L37/025 ,  H01L41/193

Abstract: A method of exchanging or transforming end groups in and/or improving the ferroelectric properties of a PVDF-TrFE co-polymer is disclosed. A bulky or chemically dissimilar end group, such as an iodine, sulfate, aldehyde or carboxylic acid end group, may be transformed to a hydrogen, fluorine or chlorine atom. A method of making a PVDF-TrFE co- polymer is disclosed, including polymerizing a mixture of VDF and TrFE using an initiator, and transforming a bulky or chemically dissimilar end group to a hydrogen, fluorine or chlorine atom. A PVDF-TrFE co-polymer or other fluorinated alkene polymer is also disclosed. The co-polymer may be used as a ferroelectric, electromechanical, piezoelectric or dielectric material in an electronic device.

Abstract translation: 公开了在PVDF-TrFE共聚物中交换或转化端基和/或改进铁电性能的方法。 可以将大体积或化学上不同的末端基团，例如碘，硫酸盐，醛或羧酸端基转化成氢，氟或氯原子。 公开了制备PVDF-TrFE共聚物的方法，包括使用引发剂聚合VDF和TrFE的混合物，并将大体积或化学上不同的端基转化为氢，氟或氯原子。 还公开了PVDF-TrFE共聚物或其它氟化烯烃聚合物。 共聚物可以用作电子设备中的铁电，机电，压电或电介质材料。

公开(公告)号：WO2017021783A3

公开(公告)日：2017-05-26

申请号：PCT/IB2016001258

申请日：2016-08-04

Applicant: THIN FILM ELECTRONICS ASA ,  NILSSON JAKOB ,  BROX-NILSEN CHRISTIAN

Inventor： NILSSON JAKOB ,  BROX-NILSEN CHRISTIAN

IPC: C08F8/00 ,  C08F8/04 ,  C08F8/12 ,  C08F8/20 ,  C08F8/26 ,  C08F214/18 ,  C08F214/22 ,  H01L37/02 ,  H01L41/193

CPC classification number: H01L21/0212 ,  C08F8/00 ,  C08F8/04 ,  C08F8/12 ,  C08F8/20 ,  C08F8/26 ,  C08F214/182 ,  C08F214/22 ,  C08F2500/02 ,  C08F2810/40 ,  H01L27/11507 ,  H01L27/1159 ,  H01L28/00 ,  H01L37/025 ,  H01L41/193

Abstract: A method of exchanging or transforming end groups in a polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) co-polymer and thereby improving the ferroelectric properties of a PVDF-TrFE co-polymer is disclosed. A bulky or chemically dissimilar end group, such as an iodine or hydroxyl end group, may be transformed to a hydrogen, fluorine or chlorine atom. A PVDF-TrFE co-polymer comprising end groups or substituents selected from hydrogen, fluorine or chlorine is also disclosed. The co-polymer may be used as a ferroelectric, electromechanical, piezoelectric or dielectric material in an electronic device.

Abstract translation: 公开了交换或转化聚偏二氟乙烯 - 三氟乙烯（PVDF-TrFE）共聚物中的端基并由此改善PVDF-TrFE共聚物的铁电性质的方法。 体积大或化学上不相似的端基，例如碘或羟基端基，可以转化为氢，氟或氯原子。 还公开了包含选自氢，氟或氯的端基或取代基的PVDF-TrFE共聚物。 该共聚物可以用作电子器件中的铁电，机电，压电或介电材料。