公开(公告)号：WO2015050560A1

公开(公告)日：2015-04-09

申请号：PCT/US2013/063449

申请日：2013-10-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JING, Naiyong ,  JIANG, Xuan ,  RIDDLE, Justin, A. ,  SUN, Fuxia ,  SCHMIDT, Daniel, J.

Inventor： JING, Naiyong ,  JIANG, Xuan ,  RIDDLE, Justin, A. ,  SUN, Fuxia ,  SCHMIDT, Daniel, J.

IPC: C09D1/00

CPC classification number: C09D1/00 ,  C03C17/23 ,  C03C2218/11 ,  C08J7/06 ,  C08J2367/03 ,  C08K3/36 ,  C09D7/61

Abstract: A method of making a coatable composition includes: providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the first composition has a pH greater than 6; acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; and dissolving at least one metal compound in the second composition to form the coatable composition. The silica nanoparticles have a polymodal particle size distribution, wherein the polymodal particle size distribution comprises a first mode having a first particle size in the range of from 8 to 35 nanometers, wherein the polymodal particle size distribution comprises a second mode having a second particle size in the range of from 2 to 20 nanometers, wherein the first particle size is greater than the second particle size. Coatable compositions, antistatic compositions, preparable by the method are also disclosed. Soil-resistant articles including the antistatic compositions are also disclosed.

Abstract translation: 制备可涂覆组合物的方法包括：提供包含分散在水性液体载体中的二氧化硅纳米颗粒的第一组合物，其中所述第一组合物的pH大于6; 使用无机酸将第一组合物酸化至pH小于或等于4，以提供第二组合物; 并将至少一种金属化合物溶解在第二组合物中以形成可涂覆组合物。 所述二氧化硅纳米颗粒具有多晶型粒度分布，其中所述多晶型粒度分布包括具有在8至35纳米范围内的第一粒度的第一模式，其中所述多模式粒度分布包括具有第二粒径的第二模式 在2至20纳米的范围内，其中第一粒度大于第二粒径。 还公开了可通过该方法制备的可涂敷组合物，抗静电组合物。 还公开了包括抗静电组合物的防锈制品。

公开(公告)号：WO2014075246A1

公开(公告)日：2014-05-22

申请号：PCT/CN2012/084609

申请日：2012-11-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  JING, Naiyong ,  MUGGLI, Mark W. ,  HEBERT, Larry S. ,  HAMER, Kevin M. ,  BLONG, Thomas J. ,  JUERGENS, Michael ,  TIERS, George Van Dyke ,  YU, Zhigang ,  WANG, Yaming ,  CHU, Yiwen

Inventor： JING, Naiyong ,  MUGGLI, Mark W. ,  HEBERT, Larry S. ,  HAMER, Kevin M. ,  BLONG, Thomas J. ,  JUERGENS, Michael ,  TIERS, George Van Dyke ,  YU, Zhigang ,  WANG, Yaming ,  CHU, Yiwen

IPC: C09D127/12 ,  C09D127/14 ,  C09D127/16 ,  C08K3/20

CPC classification number: C09D127/22 ,  C08J7/047 ,  C08J2367/02 ,  C08J2427/12 ,  C08K3/20 ,  C08K3/36 ,  C08K5/544 ,  C08K9/00 ,  C08K9/04 ,  C08K2201/011 ,  C08L2205/02 ,  C09D127/12 ,  C09D127/18 ,  H01L31/049 ,  Y02E10/50 ,  C08K9/06 ,  C09D127/16 ,  C08K13/02 ,  C08L27/18 ,  C08L27/12

Abstract: Presently described are methods of making coating comprising aqueous fluoropolymer latex dispersions, aqueous fluoropolymer coating compositions, coated substrates, and (e.g. backside) films of photovoltaic cells. In one embodiment, the film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; inorganic oxide nanoparticles; and a compound that reacts with the repeat units derived from VF and VDF to crosslink the fluoropolymer and/or couple the fluoropolymer to the inorganic oxide nanoparticles. In another embodiment, the backside film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; and an amino-substituted organosilane ester or ester equivalent crosslinking compound.

Abstract translation: 目前描述的是制备包含水性含氟聚合物胶乳分散体，含水氟聚合物涂料组合物，涂覆的基材和（例如背面）光伏电池的涂层的方法。 在一个实施方案中，该膜包含至少一种包含衍生自VF，VDF或其组合的重复单元的含氟聚合物; 无机氧化物纳米粒子; 以及与衍生自VF和VDF的重复单元反应以使含氟聚合物交联和/或将含氟聚合物偶联到无机氧化物纳米颗粒的化合物。 在另一个实施方案中，背面膜包含至少一种氟聚合物，其包含衍生自VF，VDF或其组合的重复单元; 和氨基取代的有机硅烷酯或酯等价交联化合物。

公开(公告)号：WO2014036448A1

公开(公告)日：2014-03-06

申请号：PCT/US2013/057591

申请日：2013-08-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  RIDDLE, Justin, A. ,  HOBBS, Terry, R. ,  LU, David, D. ,  D'SOUZA, Andrew, S. ,  JING, Naiyong ,  GARDNER, James, P., Jr. ,  ZHANG, Yifan ,  MALMBERG, Zachary, J.

Inventor： RIDDLE, Justin, A. ,  HOBBS, Terry, R. ,  LU, David, D. ,  D'SOUZA, Andrew, S. ,  JING, Naiyong ,  GARDNER, James, P., Jr. ,  ZHANG, Yifan ,  MALMBERG, Zachary, J.

IPC: C11D3/16 ,  B08B3/08

CPC classification number: B08B3/10 ,  C11D3/08 ,  C11D3/1246 ,  C11D3/162 ,  C11D11/0035

Abstract: A method of removing an unwanted constituent from a siliceous surface in which the method includes contacting the siliceous surface and the unwanted constituent with a multi-functional composition (e.g., a cleaning and protecting composition) that includes water, a hydrophilic silane, and a surfactant, and drying the surface, and compositions that include a hydrophilic silane, and a surfactant

Abstract translation: 一种从硅质表面除去不需要的成分的方法，其中所述方法包括用包含水，亲水硅烷和表面活性剂的多功能组合物（例如清洁和保护组合物）接触硅质表面和不需要的成分 ，并干燥表面，以及包括亲水硅烷和表面活性剂的组合物

公开(公告)号：WO2014008383A1

公开(公告)日：2014-01-09

申请号：PCT/US2013/049300

申请日：2013-07-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  BROWN, Katherine A. ,  NARUM, Timothy N. ,  JING, Naiyong ,  HEBRINK, Timothy J.

Inventor： BROWN, Katherine A. ,  NARUM, Timothy N. ,  JING, Naiyong ,  HEBRINK, Timothy J.

IPC: C03C17/00 ,  C03C17/22 ,  C09D5/16

CPC classification number: C03C17/02 ,  C03C17/007 ,  C03C2217/213 ,  C03C2217/42 ,  C03C2217/478 ,  C03C2217/78 ,  C03C2218/111 ,  C03C2218/114 ,  C03C2218/118 ,  C03C2218/32 ,  C08K3/36 ,  C09D5/00 ,  C09D5/1681 ,  C09D7/67

Abstract: The present disclosure relates generally to anti-soiling compositions, methods of applying anti-soiling compositions, and equipment for applying anti-soiling compositions. In some embodiments, the present disclosure relates to a method of forming a durable coating on a glass substrate, comprising: (1) applying a coating composition to a glass substrate, the applied coating composition having a thickness of greater than 4 microns; the coating composition consisting essentially of about 0.25% to about 10% by weight of non-oxidizing nanoparticles, an acid, and water; (2) allowing the coating composition to remain on the glass substrate for at least an amount of time sufficient to permit at least some of the nanoparticles to bond to the glass substrate; (3) reducing the thickness of the coating composition to about 0.25 to 4 microns, and (4) evaporating at least some of the water to form the durable coating.

Abstract translation: 本公开一般涉及防污染组合物，施用抗污染组合物的方法，以及用于施用抗污染组合物的设备。 在一些实施方案中，本公开内容涉及在玻璃基底上形成耐久涂层的方法，其包括：（1）将涂料组合物施加到玻璃基底上，所涂覆的涂料组合物具有大于4微米的厚度; 涂层组合物基本上由约0.25％至约10％重量的非氧化性纳米颗粒，酸和水组成; （2）允许涂料组合物保留在玻璃基材上至少一定量的时间，足以允许至少一些纳米颗粒结合到玻璃基底; （3）将涂料组合物的厚度减小至约0.25至4微米，和（4）蒸发至少一些水以形成耐久涂层。

公开(公告)号：WO2013165965A1

公开(公告)日：2013-11-07

申请号：PCT/US2013/038788

申请日：2013-04-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  O'NEILL, Mark B. ,  HENDERSON, Andrew J. ,  HEBRINK, Timothy J. ,  KATARE, Rajesh K. ,  JING, Naiyong ,  NORTH, Diane ,  PETERSON, Eric M. ,  ROCHE, John L. ,  MOLNAR, Attila ,  EATON, Joseph H.

Inventor： O'NEILL, Mark B. ,  HENDERSON, Andrew J. ,  HEBRINK, Timothy J. ,  KATARE, Rajesh K. ,  JING, Naiyong ,  NORTH, Diane ,  PETERSON, Eric M. ,  ROCHE, John L. ,  MOLNAR, Attila ,  EATON, Joseph H.

IPC: H02N6/00

CPC classification number: G02B5/0866 ,  F24S23/82 ,  F24S2023/86 ,  Y02E10/40

Abstract: The present disclosure generally relates to durable solar mirror films, methods of making durable solar mirror films, and constructions including durable solar mirror films. In one embodiment, the present disclosure relates to a solar mirror film comprising: a weatherable layer having a weatherable layer coefficient of hygroscopic expansion; a reflective layer having a reflective layer coefficient of hygroscopic expansion; and a compliant layer between the weatherable layer and the reflective layer, the compliant layer having a compliant layer coefficient of hygroscopic expansion that is between the weatherable layer coefficient of hygroscopic expansion and the reflective layer coefficient of hygroscopic expansion.

Abstract translation: 本公开总体上涉及耐久的太阳镜镜片，制造耐用的太阳镜膜的方法以及包括耐用的太阳镜膜的结构。 在一个实施例中，本公开涉及一种太阳镜，其包括：具有耐候性层吸湿膨胀系数的耐候层; 具有反射层吸湿膨胀系数的反射层; 以及耐候层和反射层之间的柔顺层，柔顺层具有吸湿膨胀系数的柔顺层，其吸湿膨胀系数与吸湿膨胀的反射层系数之间。

公开(公告)号：WO2013165726A1

公开(公告)日：2013-11-07

申请号：PCT/US2013/037584

申请日：2013-04-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  O'NEILL, Mark, B. ,  HENDERSON, Andrew, J. ,  HEBRINK, Timothy J. ,  KATARE, Rajesh, K. ,  JING, Naiyong ,  NORTH, Diane ,  PETERSON, Eric, M.

Inventor： O'NEILL, Mark, B. ,  HENDERSON, Andrew, J. ,  HEBRINK, Timothy J. ,  KATARE, Rajesh, K. ,  JING, Naiyong ,  NORTH, Diane ,  PETERSON, Eric, M.

IPC: B32B5/00 ,  B32B33/00 ,  G02B5/08

CPC classification number: H02S40/22 ,  B32B33/00 ,  B32B37/153 ,  B32B2037/246 ,  B32B2038/0028 ,  B32B2038/0092 ,  B32B2307/40 ,  F24S23/70 ,  G02B1/10 ,  G02B1/105 ,  G02B1/14 ,  G02B5/0808 ,  G02B5/0875 ,  Y02E10/40 ,  Y02E10/52

Abstract: The present disclosure generally relates to durable solar mirror films, methods of making durable solar mirror films, and constructions including durable solar mirror films. In one embodiment, the present disclosure relates to a solar mirror film comprising: a multilayer optical film layer including having a coefficient of hygroscopic expansion of less than about 30 ppm per percent relative humidity; and a reflective layer having a coefficient of hygroscopic expansion.

Abstract translation: 本公开总体上涉及耐久的太阳镜镜片，制造耐用的太阳镜膜的方法以及包括耐用的太阳镜膜的结构。 在一个实施方案中，本公开涉及一种太阳能镜膜，其包括：多层光学膜层，其包含相对湿度小于约30ppm的吸湿膨胀系数; 以及具有吸湿膨胀系数的反射层。

公开(公告)号：WO2012129366A3

公开(公告)日：2013-01-03

申请号：PCT/US2012030042

申请日：2012-03-22

Applicant: 3M INNOVATIVE PROPERTIES CO ,  TRAN THU-VAN T ,  ALOSHYNA EP LESUFFLEUR MARIE ,  ROSS RICHARD B ,  PYUN EUMI ,  PLEPYS ANTHONY R ,  HARRISON PETER J ,  CLAPPER JASON D ,  JING NAIYONG ,  BHARTI VIVEK ,  SHARMA NEERAJ

Inventor： TRAN THU-VAN T ,  ALOSHYNA EP LESUFFLEUR MARIE ,  ROSS RICHARD B ,  PYUN EUMI ,  PLEPYS ANTHONY R ,  HARRISON PETER J ,  CLAPPER JASON D ,  JING NAIYONG ,  BHARTI VIVEK ,  SHARMA NEERAJ

IPC: C09J7/02 ,  C08J5/18 ,  C09J133/04

CPC classification number: C09J7/0217 ,  B05D1/00 ,  C08K3/013 ,  C08K5/0066 ,  C08K5/521 ,  C08L2201/02 ,  C09J5/06 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J153/00 ,  C09J2205/102 ,  C09J2453/00 ,  Y10T428/2891

Abstract: Pressure sensitive adhesive tapes having flame retarding properties include a backing and a pressure sensitive adhesive layer. The pressure sensitive adhesive layer includes a (meth)acrylate-based block copolymer, and may also include at least 10% by weight of a halogen-free flame retarding agent. The adhesive layer may contain additional optional additives such as tackifying resins, plasticizers, and the like. The tapes are prepared by coating the flame retarding pressure sensitive adhesive onto the backing, either in solvent or by a solventless process.

Abstract translation: 具有阻燃性的压敏粘合带包括背衬和压敏粘合剂层。 压敏粘合剂层包括（甲基）丙烯酸酯类嵌段共聚物，并且还可以包含至少10重量％的无卤阻燃剂。 粘合剂层可以含有额外的任选的添加剂，例如增粘树脂，增塑剂等。 通过将溶剂或无溶剂方法将阻燃压敏粘合剂涂布在背衬上来制备胶带。

公开(公告)号：WO2012067937A2

公开(公告)日：2012-05-24

申请号：PCT/US2011/060178

申请日：2011-11-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  SHEFELBINE, Terri A. ,  ADAIR, Eric W. ,  GROOTAERT, Werner M.A. ,  JING, Naiyong

Inventor： SHEFELBINE, Terri A. ,  ADAIR, Eric W. ,  GROOTAERT, Werner M.A. ,  JING, Naiyong

IPC: C08L27/12 ,  C08K3/00 ,  C08K9/00 ,  C08J5/00 ,  C08F14/18

CPC classification number: C08L27/18 ,  B82Y30/00 ,  C08J3/16 ,  C08J5/005 ,  C08J2327/18 ,  C08K3/36 ,  C08K9/04 ,  C08L71/02

Abstract: Described herein is a method of coagulating a fluoropolymer latex comprising: providing an amorphous fluoropolymer latex; providing modified inorganic nanoparticles; and contacting the amorphous fluoropolymer latex with a sufficient amount of modified inorganic nanoparticles to coagulate the amorphous fluoropolymer latex.

Abstract translation: 本文描述了一种凝结含氟聚合物胶乳的方法，其包括：提供无定形含氟聚合物胶乳; 提供改性无机纳米粒子 并使无定形含氟聚合物胶乳与足够量的改性无机纳米粒子接触以凝结无定形含氟聚合物胶乳。

公开(公告)号：WO2011150103A2

公开(公告)日：2011-12-01

申请号：PCT/US2011/037966

申请日：2011-05-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  ALI, Mahfuza B. ,  JING, Naiyong ,  LIRINE, Valeri ,  NAGARKAR, Pradnya V. ,  YLITALO, Caroline M. ,  LENNHOFF, Nancy S. ,  SCHOLZ, Matthew T. ,  PARTHASARATHY, Ranjani V.

Inventor： ALI, Mahfuza B. ,  JING, Naiyong ,  LIRINE, Valeri ,  NAGARKAR, Pradnya V. ,  YLITALO, Caroline M. ,  LENNHOFF, Nancy S. ,  SCHOLZ, Matthew T. ,  PARTHASARATHY, Ranjani V.

IPC: C03C17/30

CPC classification number: C09D5/1637 ,  A61L29/085 ,  A61L29/16 ,  A61L2300/216 ,  A61L2300/404 ,  A61L2420/02 ,  B05D3/02 ,  B05D3/06 ,  C03C17/30 ,  C03C17/42 ,  C08F220/06 ,  C08F220/18 ,  C08F220/34 ,  C08F230/08 ,  C08G77/26 ,  C09D5/1675 ,  C09D5/1693 ,  C09D183/10 ,  G06F3/041 ,  G06F3/047 ,  Y10T428/31663

Abstract: The disclosure provides polymers having antimicrobial activity and articles with the polymers coated thereon. The polymers include a first pendant group comprising a first cationic component, a second pendant group comprising a nonpolar component, and a third pendant group comprising an organosilane component. The disclosure also includes methods of coating medical device articles and body fluid-receiving substrates with the antimicrobial polymers. The methods further include the use of adhesion-promoting components.

Abstract translation: 本公开提供具有抗微生物活性的聚合物和其上涂覆有聚合物的制品。 聚合物包括包含第一阳离子组分的第一侧基，包含非极性组分的第二侧基和包含有机硅烷组分的第三侧基。 本公开还包括用抗微生物聚合物涂覆医疗器械制品和体液接收基底的方法。 所述方法还包括使用粘附促进组分。

公开(公告)号：WO2011142956A2

公开(公告)日：2011-11-17

申请号：PCT/US2011/033723

申请日：2011-04-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  CHU, Yiwen ,  YU, Zhigang ,  JING, Naiyong ,  PAN, Rui

Inventor： CHU, Yiwen ,  YU, Zhigang ,  JING, Naiyong ,  PAN, Rui

IPC: C03C17/00 ,  C03C23/00 ,  C09D7/12 ,  C09D5/00 ,  H01L31/042

CPC classification number: H01L31/02168 ,  C03C17/007 ,  C03C2217/425 ,  C03C2217/465 ,  C03C2217/478 ,  C08K3/36 ,  C08K9/06 ,  C09D1/00 ,  C09D7/67 ,  C09D7/70 ,  Y02E10/50 ,  Y10T428/315 ,  Y10T428/31525 ,  Y10T428/31645 ,  Y10T428/31667

Abstract: There is provided a coating composition comprising nonspherical nanoparticles; spherical nanoparticles; optionally hydrophilic groups and optional an surfactant; and a liquid medium comprising water and no greater than 30 wt% organic solvent, if present, based on the total weight of liquid medium, where at least a portion of the nonspherical nanoparticles or at least a portion of the spherical nanoparticles comprises functional groups attached to their surface through chemical bonds, wherein the functional groups comprise at least one group selected from the group consisting of epoxy group, amine group, hydroxyl, olefin, alkyne, (meth) acrylato, mercapto group, or combinations thereof. There is also provided a method for modifying a substrate surface using the coating composition and articles made therefrom.

Abstract translation: 提供了包含非球形纳米颗粒的涂料组合物; 球形纳米粒子; 任选的亲水基团和任选的表面活性剂; 和包含水和不大于30重量％的有机溶剂（如果存在）的液体介质，基于液体介质的总重量，其中至少一部分非球形纳米颗粒或至少一部分球形纳米颗粒包含附着的官能团 其中所述官能团包含至少一种选自环氧基，胺基，羟基，烯烃，炔烃，（甲基）丙烯酸酯基，巯基或其组合的基团。 还提供了使用涂料组合物和由其制成的制品来改性基材表面的方法。