公开(公告)号：WO2006051053A1

公开(公告)日：2006-05-18

申请号：PCT/EP2005/055689

申请日：2005-11-02

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  TZIKAS, Athanassios ,  ROENTGEN, Georg ,  KLIER, Herbert

Inventor： TZIKAS, Athanassios ,  ROENTGEN, Georg ,  KLIER, Herbert

IPC: C09B62/09 ,  C09B62/513 ,  C09B62/475 ,  C09D11/02

CPC classification number: C09B62/4415

Abstract: Reactive dyes of formula (1) wherein R 1 is hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, R 2 is hydrogen; C 1 -C 4 alkyl; C 1 -C 4 alkoxy unsubstituted or substituted by sulfato, hydroxy or by C 1 -C 4 alkoxy; halogen; carboxy or sulfo, R 3 is hydrogen; C 1 -C 4 alkyl; C 1 -C 4 alkoxy unsubstituted or substituted by sulfato, hydroxy or by C 1 -C 4 alkoxy; halogen; nitro; C 2 -C 4 alkanoylamino; ureido; carboxy or sulfo, (R 4 ) k denotes k identical or different substituents selected from the group halogen, C 1 -C 4 -alkyl, C 1 -C 4 alkoxy, carboxy and sulfo, X is halogen and V is a radical of formula (2a), 2(b) wherein R 5 is unsubstituted or substituted C 1 -C 4 alkyl, (R 6 ) ι denotes I identical or different substituents from the group C1-C 4 alkyl, C 1 -C 4 alkoxy and sulfo, and I is the number O, 1 or 2, Y is vinyl or a -CH 2 -CH 2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(HaI)-CH 2 -HaI or -C(HaI)=CH 2 group, Hal is halogen and k is the number O, 1 , 2 or 3, are suitable especially for dyeing cotton and yield dyeings having good allround fastness properties.

Abstract translation: 式（1）的反应性染料，其中R 1是氢或未取代或取代的C 1 -C 4烷基，R 2， / SUB>是氢; ç _{1 -C 4 烷基; 未取代或被硫酸酯，羟基或C 1 -C 4烷氧基取代的C 1 -C 4烷氧基; 卤素; 羧基或磺基，R 3是氢; ç 1 -C 4 烷基; 未取代或被硫酸酯，羟基或C 1 -C 4烷氧基取代的C 1 -C 4烷氧基; 卤素; 硝基; ç 2 -C 4 链烷酰氨基; 脲; 羧基或磺基，（R 4）N表示k个相同或不同的选自卤素，C 1 -C 4烷基的取代基 C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基，X是卤素，V是式（2a），2（b）的基团， 其中R 5是未取代或取代的C 1 -C 4烷基，（R 6） 表示与C 1 -C 4烷基，C 1 -C 4烷氧基和磺基相同或不同的取代基，以及 I是数字O，1或2，Y是乙烯基或-CH 2 CH 2 -CH 2 - 基团，U是在碱性条件下可除去的基团， Q是-CH（H 1）-CH 2 -H a或-C（H 1）= CH 2 H 2基，Hal是卤素，k是数字O， 2或3，特别适用于染色棉和具有良好耐环牢性的产量染色。}

公开(公告)号：WO0006652A3

公开(公告)日：2001-07-26

申请号：PCT/EP9905020

申请日：1999-07-15

Applicant: CIBA SC HOLDING AG ,  TZIKAS ATHANASSIOS ,  KLIER HERBERT

Inventor： TZIKAS ATHANASSIOS ,  KLIER HERBERT

IPC: C09B62/09 ,  C09B62/44 ,  C09B62/453 ,  C09B62/475 ,  C09B62/513 ,  C09B67/22 ,  D06P1/384 ,  D06P3/66 ,  C09B62/01

CPC classification number: C09B62/513 ,  C09B62/09 ,  C09B62/4415 ,  C09B62/453 ,  C09B62/475 ,  Y10S8/918 ,  Y10S8/924

Abstract: The invention relates to colorants of formula (1), wherein R and R independently represent hydrogen or C1-C4-alkyl and D and D independently represent a radical of formula (2), wherein (R3)0-3 represents 0 to 3 identical or different substituents selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-alkoxy, carboxy, nitro or sulfo and X1 stands for a radical of formula (3a) -SO2-Z, (3b) -NH-CO-(CH2)m-SO2-Z, (3c) -CONH-(CH2)n-SO2-Z, (3d) -NH-CO-CH(Hal)-CH2-Hal, (3e) -NH-CO-C(Hal)=CH2 or (3f), wherein Y represents halogen, T independently has the meaning of Y and represents non-fiber reactive substituents or a fiber-reactive radical of formula (4a) -NH-(CH2)2-3-SO2-Z, (4b) -NH-(CH2)2-3-O-(CH2)2-3-SO2-Z, (4c), (4d) or (4e), wherein Z represents vinyl or a -CH2-CH2-U radical and U is an alkaline separable group, Z' represents a -CH(Hal)-CH2-Hal or -(Hal)=CH2 group, m and n independently represent 2, 3 or 4 and Hal is halogen. Said colorants are suitable for dying different fibrous materials, especially fibrous material containing cellulose and provide colorings exhibiting good overall fastness.

Abstract translation: 式（1）染料，其中R 1和R 2各自独立地为氢或C1-C4烷基，和D1和D2各自的基团，式（2）彼此独立地，其中（R 3）0-3为0至中的 选自卤素，C1-C4烷基，C1-C4烷氧基，羧基，硝基或磺基和X 1中选择3个相同或不同的取代基是下式基团-SO 2 Z（图3a）， - NH-CO-（的 CH 2）M-SO 2 Z（图3b）， - CONH-（CH 2）N-SO 2 Z（图3c）， - NH-CO-CH（哈尔）-CH2-哈尔（3D）， - NH-CO-C（ 哈尔）= CH 2（3E）或（3F），其中Y是卤素，T独立地具有Y的含义，对于非纤维反应性取代基或纤维反应性基团的式-NH-（CH 2）2-3 -SO 2 -Z（图4a）， - NH-（CH 2）2-3 -O-（CH 2）2-3-SO 2 Z（图4b），（4c）中，（4D）或（4E），其中Z是乙烯基或 自由基-CH2-CH2-U，U是在碱性的基团可移动，Z“为基团-CH（哈尔）-CH2-哈尔或-C（哈尔）= CH 2，m和n独立地为2号， 唱3或4，并且Hal是卤素我 ST适合于染色各种纤维材料，特别是纤维素纤维材料和产量的染色成具有良好总体性质。

公开(公告)号：WO2004069937A1

公开(公告)日：2004-08-19

申请号：PCT/EP2004/000676

申请日：2004-01-27

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  TZIKAS, Athanassios ,  ROENTGEN, Georg ,  KLIER, Herbert

Inventor： TZIKAS, Athanassios ,  ROENTGEN, Georg ,  KLIER, Herbert

IPC: C09B62/01

CPC classification number: D06P3/66 ,  D06P1/38 ,  D06P3/028 ,  D06P3/58 ,  D06P5/30

Abstract: Dye mixtures comprising a reactive dye having at least one structural unit of formula (1) together with a reactive dye of formula (2), wherein (Q 1 ) 0-3 and (Q 2 ) 0-3 each independently of the other denote from 0 to 3 identical or different substituents selected from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, carboxy and sulfo, Z 1 and Z 2 are each independently of the other a fibre-reactive radical, at least one fibre-reactive radical being contained in the dye of formula (1) and the dye of formula (2) containing at least one fibre-reactive radical Z 1 or Z 2 , are suitable for dyeing cellulosic or nitrogen-containing fibre materials.

Abstract translation: 包含具有式（1）的至少一个结构单元和式（2）的活性染料的活性染料的染料混合物，其中（Q1）0-3和（Q2）0-3各自独立地表示0 至3个相同或不同的选自卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基，Z 1和Z 2的取代基各自独立地为纤维反应性基团，至少一个纤维反应性基团包含在 含有至少一种纤维反应性基团Z 1或Z 2的式（1）染料和式（2）的染料适用于染色纤维素或含氮纤维材料。

公开(公告)号：WO2011018274A1

公开(公告)日：2011-02-17

申请号：PCT/EP2010/059292

申请日：2010-06-30

Applicant: HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH ,  TZIKAS, Athanassios ,  KLIER, Herbert ,  ROENTGEN, Georg

Inventor： TZIKAS, Athanassios ,  KLIER, Herbert ,  ROENTGEN, Georg

IPC: C09B62/44 ,  C09D11/00

CPC classification number: C09B62/4415 ,  C09D11/328

Abstract: Reactive dyes of the formula (1) wherein B is an aliphatic bridging member, G is a sulfo naphthalene group or a sulfo benzene group of the formula (2a) or a pyridone radical of the formula (2b), R 1 , R 2 , R 3 and R 4 are each independently of the others hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, (R 5 ) h denotes h identical or different substituents selected from the group sulfo, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, R 6 is hydrogen, sulfo, halogen, carboxy, C 1 -C 4 alkyl, C 1 -C 4 alkoxy or a fibre-reactive group Z 1 of the formula -SO 2 -Y (3a), -NH-CO-(CH 2 ) l -SO 2 -Y (3b), -CONH-(CH 2 ) m -SO 2 -Y (3c), -NH-CO-CH(Hal)-CH 2 -Hal (3d) or -NH-CO-C(Hal)=CH 2 (3e), R 7 is amino, C 1 -C 4 alkyl or a fibre-reactive group Z 2 of the formula -NH-(CH 2 ) n -SO 2 -Y (3a), (R 8 ) j denotes j identical or different substituents selected from the group sulfo, C 2 -C 4 alkanoylamino, ureido, C 1 -C 4 alkyl and C 1 -C 4 alkoxy, R 9 is hydrogen, C 1 -C 4 alkyl or C 1 -C 4 alkoxy, R 10 is hydrogen or C 1 -C 4 alkyl, R 11 is hydrogen, cyano, carbamoyl or sulfomethyl, and R 12 is hydrogen, C 1 -C 4 alkyl, or phenyl which is unsubstituted or substituted by C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 2 -C 4 alkanoylamino, ureido, halogen or sulfo, X 1 and X 2 are halogen, Hal is chlorine or bromine, h and j are each independently of the other a number 0, 1 or 2; k is a number 1, 2 or 3; I, m and n are each independently of the other a number 2, 3 or 4, and Y is vinyl or a radical -CH 2 -CH 2 -U and U is a group removable under alkaline conditions, with the proviso that the dye of formula (1) contains at least one fibre-reactive group Z 1 or Z 2 are suitable for dyeing cellulosic or amide-group-containing fibre materials.

Abstract translation: 式（1）的活性染料其中B是脂族桥连构件，G是式（2a）的磺基萘基或磺基苯基或式（2b）的吡啶酮基，R1，R2，R3和 R 4各自独立地为氢或未取代的或取代的C 1 -C 4烷基，（R 5）h表示相同或不同的选自磺基，C 1 -C 4烷基和C 1 -C 4烷氧基的取代基，R 6为氢，磺基，卤素，羧基， C1-C4烷基，C1-C4烷氧基或式-SO2-Y（3a）的纤维反应性基团Z1，-NH-CO-（CH2）1-SO2-Y（3b），-CONH-（CH2）m- SO2-Y（3c），-NH-CO-CH（Hal）-CH2-Hal（3d）或-NH-CO-C（Hal）= CH2（3e），R7是氨基，C1-C4烷基或纤维 - 式-NH-（CH 2）n -SO 2 -Y（3a）的反应性基团Z 2，（R 8）j表示相同或不同的选自磺基，C 2 -C 4烷酰基氨基，脲基，C 1 -C 4烷基和C 1 -C 4烷氧基 R 9是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 10是氢或C 1 -C 4烷基，R 11是氢，氰基，氨基甲酰基或磺基甲基，和 R 12是氢，C 1 -C 4烷基或被C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，脲基，卤素或磺基取代的苯基，X 1和X 2是卤素，Hal是氯或溴，h和j是 每个独立于另一个数字0,1或2; k是数字1,2或3; I，m和n各自独立地为数2，3或4，Y为乙烯基或基团-CH 2 -CH 2 -U，U为在碱性条件下可除去的基团，条件是式 （1）含有至少一种纤维反应性基团Z 1或Z 2适用于染色含纤维素或含酰胺基的纤维材料。