公开(公告)号：WO2014145775A1

公开(公告)日：2014-09-18

申请号：PCT/US2014030597

申请日：2014-03-17

申请人： CDTI ,  NAZARPOOR ZAHRA

IPC分类号： F01N3/28 ,  B01D53/94 ,  B01J23/50

CPC分类号： B01J23/83 ,  B01D53/944 ,  B01D53/945 ,  B01D2255/104 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20761 ,  B01D2255/65 ,  B01D2255/9022 ,  B01D2255/908 ,  B01J23/002 ,  B01J23/688 ,  B01J29/06 ,  B01J37/0244 ,  B01J37/03 ,  B01J2523/00 ,  Y02A50/2341 ,  Y02T10/22 ,  B01J2523/18 ,  B01J2523/36 ,  B01J2523/48 ,  B01J2523/72 ,  B01J2523/31 ,  B01J2523/3706

摘要： Oxidation ZPGM catalyst systems and three way ZPGM catalyst systems are disclosed. ZPGM catalyst systems may oxidize toxic gases, such as carbon monoxide and hydrocarbons, optionally some ZPGM catalyst systems may as well reduce nitrogen oxides that may be included in exhaust gases. ZPGM catalyst systems may include: a substrate, a washcoat, and an overcoat. The washcoat may include at least one ZPGM catalyst and carrier material oxides. Similarly, overcoat may include at least one ZPGM catalyst, carrier material oxides and OSMs. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM catalyst systems.

摘要翻译： 公开了氧化ZPGM催化剂体系和三向ZPGM催化剂体系。 ZPGM催化剂体系可以氧化有毒气体，例如一氧化碳和烃类，任选地一些ZPGM催化剂体系也可以还原废气中可能包含的氮氧化物。 ZPGM催化剂体系可以包括：基材，修补基面涂层和外涂层。 修补基面涂层可以包括至少一种ZPGM催化剂和载体材料氧化物。 类似地，外涂层可以包括至少一种ZPGM催化剂，载体材料氧化物和OSM。 为了形成所公开的ZPGM催化剂体系，可采用本领域已知的合适的化学技术，沉积方法和处理系统。

公开(公告)号：WO2016081341A1

公开(公告)日：2016-05-26

申请号：PCT/US2015/060807

申请日：2015-11-16

申请人： CLEAN DIESEL TECHNOLOGIES, INC. ,  NAZARPOOR, Zahra ,  YAGLIDERE, Oguzhan, Selim ,  GOLDEN, Stephen, J.

发明人： NAZARPOOR, Zahra ,  YAGLIDERE, Oguzhan, Selim ,  GOLDEN, Stephen, J.

IPC分类号： B01J23/75 ,  B01J23/10 ,  B01J23/745 ,  B01J23/889 ,  B01J35/00 ,  B01J23/00

CPC分类号： B01J23/75 ,  B01D53/945 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20761 ,  B01D2255/405 ,  B01D2255/65 ,  B01D2255/908 ,  B01J23/005 ,  B01J23/745 ,  B01J23/8892 ,  B01J35/0006 ,  B01J37/0201 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/17 ,  B01J2523/3718 ,  B01J2523/48 ,  B01J2523/845 ,  B01J2523/842 ,  B01J2523/72

摘要： Variations of bulk powder catalyst material including Cu-Co, Fe-Co, and Co-Mn spinel systems for ZPGM TWC applications are disclosed. The disclosed bulk powder catalyst samples include stoichiometric and nonstoichiometric Cu-Co, Fe-Co, and Co-Mn spinels on Pr 6 O 11 -ZrO 2 support oxide, prepared using incipient wetness method. Activity measurements under isothermal steady state sweep test condition may he performed rich to lean condition. Catalytic activity of bulk powder samples may be compared to analyze the influence that different bimetallic spinel compositions may have on TVVC performance, including ZPGM materials for a plurality of TWC applications. Stoichiometric Cu-Co, Fe-Co, and Co-Mn spinel systems exhibit higher catalytic activity than non-stoichiometric Cu-Co, Fe-Co, and Co-Mn spinel systems. The influence of stoichiometric Cu-Co, Fe-Co, and Co-Mn spinel systems may lead into cost effective manufacturing solutions for ZPGM TWC systems.

摘要翻译： 公开了包括用于ZPGM TWC应用的Cu-Co，Fe-Co和Co-Mn尖晶石系统的散装粉末催化剂材料的变化。 所公开的本体粉末催化剂样品包括使用初始湿度法制备的Pr6O11-ZrO2载体氧化物上的化学计量和非化学计量的Cu-Co，Fe-Co和Co-Mn尖晶石。 在等温稳态扫描测试条件下的活动测量可能会执行丰富到精益状态。 可以比较散装粉末样品的催化活性，分析不同的双金属尖晶石组合物对TVVC性能的影响，包括用于多个TWC应用的ZPGM材料。 化学计量Cu-Co，Fe-Co和Co-Mn尖晶石体系表现出比非化学计量的Cu-Co，Fe-Co和Co-Mn尖晶石体系更高的催化活性。 化学计量Cu-Co，Fe-Co和Co-Mn尖晶石系统的影响可能导致ZPGM TWC系统的成本有效的制造解决方案。

公开(公告)号：WO2016081394A1

公开(公告)日：2016-05-26

申请号：PCT/US2015/060966

申请日：2015-11-17

申请人： CLEAN DIESEL TECHNOLOGIES, INC. ,  NAZARPOOR, Zahra ,  YAGLIDERE, Oguzhan, Selim ,  GOLDEN, Stephen, J.

发明人： NAZARPOOR, Zahra ,  YAGLIDERE, Oguzhan, Selim ,  GOLDEN, Stephen, J.

IPC分类号： B01J23/889 ,  B01J23/10 ,  B01J23/00 ,  B01D53/94

CPC分类号： B01J23/8892 ,  B01D53/945 ,  B01D2255/2066 ,  B01D2255/207 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20746 ,  B01D2255/20761 ,  B01D2255/40 ,  B01D2255/405 ,  B01D2255/908 ,  B01J23/005 ,  B01J23/10 ,  B01J37/035 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/17 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/3718 ,  B01J2523/48 ,  B01J2523/56

摘要： Variations of ZPGM bulk powder catalyst materials, including Cu-Co-Mn ternary spinel systems for TWC applications are disclosed. Bulk powder catalyst samples are prepared employing a plurality of molar ratio variations, including disclosed Cu-Co-Mn spinel on Praseodymium-Zirconia support oxide made by incipient wetness method, or Cu-Co-Mn spinel on Niobium-Zirconia support oxide, which may be synthesized by co-precipitation method. A plurality of bulk powder catalyst samples may be tested by performing isothermal steady state sweep test, employing a flow reactor at inlet temperature of about 450 ºC, and testing a gas stream from lean to rich condition and influence on TWC performance measured/analyzed, which may lead into significant improvements in the manufacturing of ZPGM bulk powder catalyst materials for TWC applications.

摘要翻译： 公开了ZPGM散装粉末催化剂材料的变化，包括用于TWC应用的Cu-Co-Mn三元尖晶石系统。 使用多个摩尔比变化制备散装粉末催化剂样品，包括在初始润湿方法制备的镨 - 氧化锆载体氧化物上公开的Cu-Co-Mn尖晶石或在铌 - 氧化锆载体氧化物上的Cu-Co-Mn尖晶石， 通过共沉淀法合成。 可以通过进行等温稳态扫描试验来测试多个散装粉末催化剂样品，使用流入反应器，入口温度为约450℃，并测试从贫到富状态的气流，并测量/分析对TWC性能的影响， 可能导致用于TWC应用的ZPGM散装粉末催化剂材料的制造的显着改进。

公开(公告)号：WO2016069833A1

公开(公告)日：2016-05-06

申请号：PCT/US2015/057942

申请日：2015-10-29

申请人： CLEAN DIESEL TECHNOLOGIES, INC. (CDTI) ,  NAZARPOOR, Zahra ,  ABKEN, Anke, Elizabeth ,  GOLDEN, Stephen, J.

发明人： NAZARPOOR, Zahra ,  ABKEN, Anke, Elizabeth ,  GOLDEN, Stephen, J.

IPC分类号： B01J23/34 ,  B01J37/02 ,  B01J37/08

CPC分类号： B01J23/8892 ,  B01D53/945 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20746 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/405 ,  B01D2255/65 ,  B01J23/005 ,  B01J37/0242 ,  B01J37/0244 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/17 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/31 ,  B01J2523/3718 ,  B01J2523/48

摘要： Effect of the type of ZPGM material composition to improve thermal stability of ZPGM catalyst systems for TWC application is disclosed. ZPGM catalyst system samples are prepared and configured with washcoat on ceramic substrate, overcoat including doped Zirconia support oxide, and impregnation layer including either Cu 1 Mn 2 O 4 spinel or Cu 1 Co 1 Mn 1 O 4 spinel. Testing of ZPGM catalyst samples including variations of aging temperatures and different impregnation layer materials are developed under isothermal steady state sweep test condition for ZPGM catalyst systems to evaluate performance especially NOx conversions and level of thermal stability. As a result disclosed ZPGM catalyst systems with most suitable spinel that includes Cu 1 Co 1 Mn 1 O 4 in impregnation layer exhibit high NOx conversion and significant improved thermal stability compare to Cu 1 Mn 2 O 4 spinel, which is suitable for under floor and close coupled TWC application. The effect of adding Co to Cu-Mn spinel composition to improve thermal stability confirmed by TPR measurement.

摘要翻译： 公开了ZPGM材料组成的类型，以提高ZPGM催化剂体系对TWC应用的热稳定性的影响。 ZPGM催化剂体系样品在陶瓷基体上制备并配置有涂层，外涂层包括掺杂的氧化锆载体氧化物，以及包含Cu1Mn2O4尖晶石或Cu1Co1Mn1O4尖晶石的浸渍层。 ZPGM催化剂样品的测试包括老化温度和不同浸渍层材料的变化，在ZPGM催化剂体系的等温稳态扫描试验条件下开发，以评估性能，特别是NOx转化率和热稳定性水平。 结果表明，与Cu1Mn2O4尖晶石相比，在浸渍层中包含Cu1Co1Mn1O4的最合适的尖晶石的ZPGM催化剂体系表现出高的NOx转化率和显着的改善的热稳定性，适用于底层和紧耦合的TWC应用。 通过TPR测量证实，添加Co对Cu-Mn尖晶石组合物以提高热稳定性的效果。