Abstract:
The present invention provides poly(ureaurethane)s including a reaction product of components including: (a) at least one isocyanate functional ureaurethane prepolymer including the reaction product of: (1) at least one isocyanate functional urethane prepolymer including the reaction product of: (i) a first amount of at least one polyisocyanate; and (ii) a first amount of at least one branched polyol; and (2) water, to form an isocyanate functional ureaurethane prepolymer; and (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
The present invention provides polyurethanes including a reaction product of components including: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) about 0.1 to about 0.95 equivalents of at least one diol having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol and the reaction components are maintained at a temperature of at least about 100°C for at least about 10 minutes, compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
The present invention provides poly(ureaurethane)s including a reaction product of components including: (a) at least one isocyanate functional ureaurethane prepolymer including the reaction product of: (1) at least one isocyanate functional urethane prepolymer including the reaction product of: (i) a first amount of at least one polyisocyanate; and (ii) a first amount of at least one branched polyol; and (2) water, to form an isocyanate functional ureaurethane prepolymer; and (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
The present invention provides poly(ureaurethane)s including a reaction product of components including: (a) at least one isocyanate functional ureaurethane prepolymer including the reaction product of: (1) at least one isocyanate functional urethane prepolymer including the reaction product of: (i) a first amount of at least one polyisocyanate; and (ii) a first amount of at least one branched polyol; and (2) water, to form an isocyanate functional ureaurethane prepolymer; and (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
The present invention provides polyurethane materials including a first portion of crystalline particles having self-orientation and bonded together to fix their orientation along a first crystallographic direction and a second portion of crystalline particles having self-orientation and bonded together to fix their orientation along a second crystallographic direction, the first crystallographic direction being different from the second crystallographic direction, wherein said crystalline particles comprise greater than about 30% of the total volume of the polyurethane material; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.3 to about 0.4 equivalents of butanediol or pentanediol; and (b) about 0.3 to about 0.7 equivalents of trimethylolpropane; and (c) up to about 0.4 equivalents of butanediol or pentanediol, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
The present invention provides polyurethanes including a reaction product of components including: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) about 0.1 to about 0.95 equivalents of at least one diol having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol and the reaction components are maintained at a temperature of at least about 100°C for at least about 10 minutes, compositions, coatings and articles made therefrom and methods of making the same.