公开(公告)号：WO2011046307A2

公开(公告)日：2011-04-21

申请号：PCT/KR2010/006619

申请日：2010-09-29

Applicant: SAM NAM PETROCHEMICAL CO., LTD. ,  KIM, Hyungjin ,  KIM, Han San ,  CHAI, Sung Wo

Inventor： KIM, Hyungjin ,  KIM, Han San ,  CHAI, Sung Wo

IPC: B01J19/18 ,  B01F7/16 ,  C07C51/265 ,  C07B61/00

CPC classification number: B01J19/18 ,  B01F3/04531 ,  B01F7/00158 ,  B01F7/00275 ,  B01F7/00633 ,  B01F7/186 ,  B01F2003/04709 ,  B01J19/006 ,  B01J19/0066 ,  B01J2219/00768 ,  B01J2219/00779 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed are an oxidation reactor for manufacturing an aromatic carboxylic acid and a method of manufacturing the aromatic carboxylic acid using the oxidation reactor. The oxidation reactor includes a reaction chamber, a stirring shaft disposed along a geometric vertical axis of the reaction chamber, and at least two stirrers, each including stirring blades, each stirring blade having either a curved portion or a bent portion formed on an end of the stirring blade to enable fluid to flow in the reaction chamber while preventing the fluid from remaining in the reaction chamber, and each stirring blade being extended radially along a direction perpendicular to the vertical axis to be rotated.

Abstract translation: 公开了用于制造芳族羧酸的氧化反应器和使用氧化反应器制备芳族羧酸的方法。 氧化反应器包括反应室，沿着反应室的几何垂直轴设置的搅拌轴和至少两个搅拌器，每个搅拌叶片包括搅拌叶片，每个搅拌叶片具有弯曲部分或弯曲部分形成在 搅拌叶片使得流体能够在反应室中流动，同时防止流体残留在反应室中，并且每个搅拌叶片沿着垂直于垂直轴线的方向径向延伸以旋转。

公开(公告)号：WO2009128608A3

公开(公告)日：2010-11-11

申请号：PCT/KR2009001391

申请日：2009-03-19

Applicant: SAM NAM PETROCHEMICAL CO LTD ,  KIM HYUNGJIN ,  KIM HANSAN ,  CHAI SUNGWO

Inventor： KIM HYUNGJIN ,  KIM HANSAN ,  CHAI SUNGWO

IPC: C07C51/16 ,  B01J19/18 ,  C07C63/26

CPC classification number: B01J4/008 ,  B01J19/0066 ,  B01J19/18 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed is an oxidation reactor for manufacturing terephthalic acid (CTA). In particular, in connection with manufacturing CTA by oxidizing para-xylene in the presence of air containing oxygen and acetic acid solvent, the present invention relates to location relationship among a gas reactant feeding location to feed air containing oxygen, a liquid reactant feeding location to feed para-xylene and a location of an impeller, and also relates to a new oxidation reactor, a structure of which is changed. The oxidation reactor of the present invention controls location relationship among a gas reactant feeding (120) location, a liquid reactant feeding (110) location, a product exhausting (140) location, a reflux (130) location and a location of an impeller (90) in consideration of a flowing pattern of gas reactant and liquid reactant and a distribution of formed CTA, thereby performing a reaction without a dead zone in the reactor, thus manufacturing CTA in a higher forming rate than before.

Abstract translation: 公开了用于制造对苯二甲酸（CTA）的氧化反应器。 特别地，关于通过在含氧气和乙酸溶剂的空气存在下氧化对二甲苯来制造CTA，本发明涉及气体反应物进料位置与含有氧气的进料空气之间的位置关系，液体反应物进料位置 进料对二甲苯和叶轮的位置，还涉及一种新的氧化反应器，其结构发生变化。 本发明的氧化反应器控制气体反应物进料（120）位置，液体反应物进料（110）位置，产物排出（140）位置，回流（130）位置和叶轮位置之间的位置关系 考虑到气体反应物和液体反应物的流动模式和形成的CTA的分布，从而在反应器中进行没有死区的反应，从而以比以前更高的形成速率制造CTA。

公开(公告)号：WO2011046307A3

公开(公告)日：2011-10-06

申请号：PCT/KR2010006619

申请日：2010-09-29

Applicant: SAM NAM PETROCHEMICAL CO LTD ,  KIM HYUNGJIN ,  KIM HAN SAN ,  CHAI SUNG WO

Inventor： KIM HYUNGJIN ,  KIM HAN SAN ,  CHAI SUNG WO

IPC: B01J19/18 ,  B01F7/16 ,  C07B61/00 ,  C07C51/265

CPC classification number: B01J19/18 ,  B01F3/04531 ,  B01F7/00158 ,  B01F7/00275 ,  B01F7/00633 ,  B01F7/186 ,  B01F2003/04709 ,  B01J19/006 ,  B01J19/0066 ,  B01J2219/00768 ,  B01J2219/00779 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed are an oxidation reactor for manufacturing an aromatic carboxylic acid and a method of manufacturing the aromatic carboxylic acid using the oxidation reactor. The oxidation reactor includes a reaction chamber, a stirring shaft disposed along a geometric vertical axis of the reaction chamber, and at least two stirrers, each including stirring blades, each stirring blade having either a curved portion or a bent portion formed on an end of the stirring blade to enable fluid to flow in the reaction chamber while preventing the fluid from remaining in the reaction chamber, and each stirring blade being extended radially along a direction perpendicular to the vertical axis to be rotated.

Abstract translation: 公开了一种用于制造芳族羧酸的氧化反应器以及使用氧化反应器制造芳族羧酸的方法。 氧化反应器包括反应室，沿着反应室的几何垂直轴设置的搅拌轴以及至少两个搅拌器，每个搅拌器包括搅拌叶片，每个搅拌叶片具有形成在反应室的端部上的弯曲部分或弯曲部分 搅拌叶片，使流体能够在反应室中流动，同时防止流体留在反应室中，并且每个搅拌叶片沿垂直于垂直轴线的方向径向延伸以旋转。

公开(公告)号：WO2009128608A2

公开(公告)日：2009-10-22

申请号：PCT/KR2009/001391

申请日：2009-03-19

Applicant: SAM NAM PETROCHEMICAL CO., LTD. ,  KIM, Hyungjin ,  KIM, Hansan ,  CHAI, Sungwo

Inventor： KIM, Hyungjin ,  KIM, Hansan ,  CHAI, Sungwo

IPC: C07C51/16 ,  C07C63/26 ,  B01J19/18

CPC classification number: B01J4/008 ,  B01J19/0066 ,  B01J19/18 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed is an oxidation reactor for manufacturing terephthalic acid (CTA). In particular, in connection with manufacturing CTA by oxidizing para-xylene in the presence of air containing oxygen and acetic acid solvent, the present invention relates to location relationship among a gas reactant feeding location to feed air containing oxygen, a liquid reactant feeding location to feed para-xylene and a location of an impeller, and also relates to a new oxidation reactor, a structure of which is changed. The oxidation reactor of the present invention controls location relationship among a gas reactant feeding location, a liquid reactant feeding location and a location of an impeller in consideration of a flowing pattern of gas reactant and liquid reactant and a distribution of formed CTA, thereby performing a reaction without a dead zone in the reactor, thus manufacturing CTA in a higher forming rate than before.

Abstract translation: 公开了用于制造对苯二甲酸（CTA）的氧化反应器。 特别地，关于通过在含氧气和乙酸溶剂的空气存在下氧化对二甲苯来制造CTA，本发明涉及气体反应物进料位置与含有氧气的进料空气之间的位置关系，液体反应物进料位置 进料对二甲苯和叶轮的位置，还涉及一种新的氧化反应器，其结构发生变化。 考虑到气体反应物和液体反应物的流动图案和形成的CTA的分布，本发明的氧化反应器控制气体反应物进料位置，液体反应物进料位置和叶轮的位置之间的位置关系，从而执行 在反应器中没有死区的反应，因此以比以前更高的形成速率制造CTA。