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    COMPOSITIONS OF IONISABLE FLUOROPOLYMERS
    3.
    发明申请
    COMPOSITIONS OF IONISABLE FLUOROPOLYMERS 审中-公开
    无离子型含氟聚合物的组成

    公开(公告)号：WO2013017470A1

    公开(公告)日：2013-02-07

    申请号：PCT/EP2012064462

    申请日：2012-07-24

    Applicant: SOLVAY SPECIALTY POLYMERS IT ,  TONELLI CLAUDIO ADOLFO PIETRO ,  BARBIERI SOLANGE

    Inventor： TONELLI CLAUDIO ADOLFO PIETRO ,  BARBIERI SOLANGE

    IPC: C08G18/08 ,  C08G18/50 ,  C08G65/00 ,  C08L27/12 ,  C08L33/16 ,  C08L75/04

    CPC classification number: C08L75/08 ,  C08F220/18 ,  C08G18/0823 ,  C08G18/283 ,  C08G18/3206 ,  C08G18/3275 ,  C08G18/5015 ,  C08G18/73 ,  C08G65/007 ,  C08L33/02 ,  C08L33/16 ,  C08L71/02 ,  C09D175/08 ,  C08F2220/1891 ,  C08F220/22 ,  C08F220/34 ,  C08F220/06 ,  C08L33/14

    Abstract: The invention relates to a composition of ionisable fluoropolymers, in particular to polymer compositions comprising: a) at least one fluorinated ionisable polymer (A), which comprises recurring fluorinated blocks and recurring functional blocks, each of said recurring functional blocks comprising at least one ionisable anionic group, and in which polymer (A) at least one of the said recurring functional blocks is comprised between two fluorinated blocks; b) at least one fluorinated ionisable polymer (B), which comprises recurring fluorinated blocks and recurring functional blocks, each of said recurring functional blocks comprising at least one ionisable cationic group, and in which polymer (B) at least one of the said recurring functional blocks is comprised between two fluorinated blocks; wherein the ratio between the ionic equivalents of polymer (A) and the ionic equivalents of polymer (B) ranges from 1.1 to 0.9.

    Abstract translation: 本发明涉及可电离含氟聚合物的组合物，具体涉及包含以下物质的聚合物组合物：a）至少一种氟化可电离聚合物（A），其包含重复氟化嵌段和重复官能嵌段，每个所述重复官能嵌段包含至少一个可电离 阴离子基团，并且其中聚合物（A）至少一个所述重复功能性嵌段包含在两个氟化嵌段之间; b）至少一种氟化可电离聚合物（B），其包含重复氟化嵌段和重复官能团，每个所述重复官能团包含至少一个可电离阳离子基团，并且其中聚合物（B）至少一种所述重复 功能性嵌段包含在两个氟化嵌段之间; 其中聚合物（A）的离子当量与聚合物（B）的离子当量之间的比率为1.1-0.9。

    METHOD FOR MANUFACTURING PERFLUOROVINYLETHERS
    4.
    发明申请
    METHOD FOR MANUFACTURING PERFLUOROVINYLETHERS 审中-公开
    制备全氟尿嘧啶的方法

    公开(公告)号：WO2012104365A3

    公开(公告)日：2012-10-04

    申请号：PCT/EP2012051730

    申请日：2012-02-02

    Applicant: SOLVAY SPECIALTY POLYMERS IT ,  MILLEFANTI STEFANO ,  TORTELLI VITO ,  MARCHIONNI GIUSEPPE ,  ALBONETTI STEFANIA ,  GREGORI MANUEL ,  FORNASARI GIUSEPPE

    Inventor： MILLEFANTI STEFANO ,  TORTELLI VITO ,  MARCHIONNI GIUSEPPE ,  ALBONETTI STEFANIA ,  GREGORI MANUEL ,  FORNASARI GIUSEPPE

    IPC: C07C41/24 ,  C07C43/17

    CPC classification number: C07C41/24 ,  C07C43/17

    Abstract: The invention pertains to a process for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HFE) having general formula (l-A) or (l-B): RfO-CRf'X-CRf"Rf"'X' (l-A) wherein Rf represents a C1-C6 perfluoro(oxy)alkyl group; Rf', Rf" and Rf'", equal or different from each other, independently represent fluorine atoms or C1-C5 perfluoro(oxy)alkyl groups; X and X', equal or different from each other, are independently chosen among CI, Br or I; formula (I-B) wherein Rf* and Rf*', equal or different from each other, independently represent fluorine atoms or C1-C3 perfluoro(oxy)alkyl groups; Y1 and Y2, equal or different from each other, independently represent fluorine atoms or C1-C3 perfluoroalkyl groups; X and X' are as above defined; said process comprising contacting said halofluoroether (HFE) with hydrogen in the presence of a catalyst comprising palladium and at least one transition metal (M) selected from the group consisting of the metals of group VIIIB, other than palladium, and of group IB.

    Abstract translation: 本发明涉及通过具有通式（1A）或（1B）的卤代氟醚（HFE）的加氢脱卤制备全氟乙烯基醚的方法：RfO-CRf'X-CRf“Rf”'X'（1A）其中Rf代表 C1-C6全氟（氧）烷基; Rf'，Rf“和Rf”“彼此相同或不同，独立地表示氟原子或C1-C5全氟（氧）烷基; X和X'彼此相同或不同，独立地选自CI，Br或I; 式（I-B）其中Rf *和Rf *'彼此相同或不同，独立地表示氟原子或C1-C3全氟（氧）烷基; Y1和Y2彼此相同或不同，独立地表示氟原子或C1-C3全氟烷基; X和X'如上所定义; 所述方法包括在催化剂存在下使所述卤代氟醚（HFE）与氢气接触，所述催化剂包含钯和至少一种选自除钯以外的第VIIIB族金属和IB族的过渡金属（M）。

    (PER)FLUOROPOLYETHERS WITH bi- OR ter-PHENYL END GROUPS
    5.
    发明申请
    (PER)FLUOROPOLYETHERS WITH bi- OR ter-PHENYL END GROUPS 审中-公开
    （PER）具有双 - 三苯基末端基团的氟代醇醚

    公开(公告)号：WO2013120827A2

    公开(公告)日：2013-08-22

    申请号：PCT/EP2013052739

    申请日：2013-02-12

    Applicant: SOLVAY SPECIALTY POLYMERS IT

    Inventor： BASKARAN DURAIRAJ ,  WADGAONKAR PRAKASH ,  MENON SHAMAL ,  TONELLI CLAUDIO ADOLFO PIETRO

    CPC classification number: C10M107/44 ,  C07C41/30 ,  C08G65/007 ,  C08G65/33386 ,  C08G65/337

    Abstract: The present invention relates (per)fluoropolyether compounds comprising a (per)fluoropolyether chain (Rf) having at least two chain ends, wherein at least one of said chain ends have a bi- or ter-phenyl group bearing at least one nitro group and, optionally one or more further substituents. The invention also relates to processes for the preparation of such compounds and to their use for the preparation of lubricant compositions in the form of oils or greases.

    Abstract translation: 本发明涉及包含具有至少两个链端的（全）氟聚醚链（Rf）的（全）氟聚醚化合物，其中至少一个所述链端具有带有至少一个硝基的双 - 或三苯基， ，任选的一个或多个其它取代基。 本发明还涉及制备这些化合物的方法及其用于制备油或油脂形式的润滑剂组合物的用途。

    FLUOROPOLYMER COMPOSITION FOR MULTILAYER ASSEMBLIES
    6.
    发明申请
    FLUOROPOLYMER COMPOSITION FOR MULTILAYER ASSEMBLIES 审中-公开
    用于多层组件的含氟聚合物组合物

    公开(公告)号：WO2013010854A3

    公开(公告)日：2013-08-15

    申请号：PCT/EP2012063487

    申请日：2012-07-10

    Applicant: SOLVAY SPECIALTY POLYMERS IT ,  MORTARA STEFANO ,  ABUSLEME JULIO A

    Inventor： MORTARA STEFANO ,  ABUSLEME JULIO A

    IPC: C08K3/22

    CPC classification number: C08K3/22 ,  B29C47/065 ,  C08K3/30 ,  Y10T29/49826 ,  Y10T428/1352 ,  Y10T428/1393 ,  Y10T428/31515 ,  Y10T428/3154

    Abstract: The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5 % wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.

    Abstract translation: 本发明涉及包含至少一种衍生自包含衍生自偏二氟乙烯（VDF）单体的重复单元和至少一种亲水性（甲基）丙烯酸酯的重复单元的至少一种（甲基）丙烯酸改性VDF聚合物[聚合物（A） ）式（I）的丙烯酸单体（MA），其中R 1，R 2，R 3中的每一个彼此相同或不同，各自独立地为氢原子或C 1 -C 3烃基，并且ROH为氢或C1- C5烃部分，其包含至少一个羟基; 至少一种相对于聚合物（A）的重量不超过5重量％的无机UV阻断剂化合物，包含由所述组合物（C1）制成的一层的多层组件，至制造所述多层组件的方法和 在不同的使用领域中使用它们，包括光伏组件的保护。

    LIQUID COMPOSITIONS OF FLUORINATED ION EXCHANGE POLYMERS
    7.
    发明申请
    LIQUID COMPOSITIONS OF FLUORINATED ION EXCHANGE POLYMERS 审中-公开
    氟化离子交换聚合物的液体组合物

    公开(公告)号：WO2012069360A3

    公开(公告)日：2012-09-07

    申请号：PCT/EP2011070383

    申请日：2011-11-17

    Applicant: SOLVAY SPECIALTY POLYMERS IT ,  MERLO LUCA ,  OLDANI CLAUDIO ,  ARCELLA VINCENZO

    Inventor： MERLO LUCA ,  OLDANI CLAUDIO ,  ARCELLA VINCENZO

    IPC: C08J3/09 ,  C08F214/18 ,  C08J5/22

    CPC classification number: C08F14/04 ,  C08F8/12 ,  C08F214/18 ,  C08F214/242 ,  C08F216/1408 ,  C08J3/09 ,  C08J3/091 ,  C08J3/11 ,  C08J5/2237 ,  C08J2327/02 ,  C08J2327/18 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1039

    Abstract: A liquid composition comprising at least one aprotic organic solvent and at least one fluorinated ion exchange polymer which consists of recurring units derived from a chlorofluoroolefin of formula CF2=CCIY, wherein Y is F or CI, and from at least one fluorinated functional monomer selected among those of formula CF2 =CF-O-(CF2CF(CF3)O)m-(CF2)nSO2X, wherein m is an integer equal to 0 or 1, n is an integer from 0 to 10 and X is chosen among halogens (CI, F, Br, I), -O-M+, wherein M+ is a cation selected among H+, NH4 +, K+, Li+, Na+, or mixtures thereof is disclosed. The liquid composition is suitable for the preparation of ion exchange membranes, in particular composite membranes, for use in fuel cell applications.

    Abstract translation: 包含至少一种非质子传递有机溶剂和至少一种氟化离子交换聚合物的液体组合物，所述氟化离子交换聚合物由衍生自式CF 2 = CClY的氯氟烯烃（其中Y为F或Cl）的重复单元和选自以下的至少一种氟化官能单体 式CF 2 = CF-O-（CF 2 CF（CF 3）O）m - （CF 2）n SO 2 X的那些，其中m是等于0或1的整数，n是0-10的整数，X选自卤素 ，F，Br，I），-O-M +，其中M +是选自H +，NH 4 +，K +，Li +，Na +或其混合物的阳离子。 该液体组合物适用于制备用于燃料电池应用的离子交换膜，特别是复合膜。

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