公开(公告)号：WO2007035936A3

公开(公告)日：2007-06-14

申请号：PCT/US2006037325

申请日：2006-09-22

Applicant: DU PONT ,  ACOSTA ERICK JOSE ,  MURPHY PETER MICHAEL ,  MCCALL ANDREW JOSEPH ,  SWOREN JOHN CHRISTOPHER

Inventor： ACOSTA ERICK JOSE ,  MURPHY PETER MICHAEL ,  MCCALL ANDREW JOSEPH ,  SWOREN JOHN CHRISTOPHER

IPC: C08G63/00 ,  C07D249/04

CPC classification number: C07D249/04 ,  C08F220/18 ,  C08F220/34

Abstract: A copolymer for imparting repellency and stain resistance to substrates is disclosed of Formula 1 [R f -X 1 -A-X 1 -Y-C(O)-CZCH 2 ]m-[W q ]p Formula 1 wherein R f is a straight or branched perfluoroalkyl group having from about 2 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, each X 1 is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing a triazole, oxygen, nitrogen, or sulfur, or a combination thereof., A is a 1, 2, 3-triazole, Y is O or N(R) 2 wherein R is H or C 1 to C 20 alkyl, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, m is a positive integer, q is zero or a positive integer, p is zero or a positive integer, and W is insert W here wherein X 1 , Y, and Z are as defined above, Rx is C(O)O(R 1 ), C(O)N(R 2 ) 2 , OC(O)(R 1 ), SO 2 (R 1 ), C 6 (R 3 ) 5 , O(R 1 ), halide, or R 1 ; each R 1 is independently H, C N H 2n+1 , C n H 2n -CH(O)CH 2 , [CH 2 CH 2 O] i R 4 , [C n C 2n ]N(R 4 ) 2 or [C n H 2n ]C n F 2n+1 , n is 1 to 40, R 4 is H or C s H 2s+1 , s = 0 to 40, i = 1 to 200, each R 2 is independently H, or C t H 2t+1 wherein t is 1 to 20, each R 3 is independently H, COOR 1 , halogen, N(R 1 ) 2 , OR 1 , SO 2 NHR 1 , CH=CH 2 , or SO 3 M, M is H, alkali metal salt, alkaline earth metal salt, or ammonium.

Abstract translation: 公开了一种用于赋予基材防排斥性和抗污染性的共聚物。式1 [R 1-X 1 -Z 1 -Y 1 -Y C（O） 其中R 1是直链或支链全氟烷基，其具有约2至约2个碳原子的直链或支链全氟烷基 20个碳原子或其混合物，其任选被至少一个氧原子间隔，每个X 1独立地为具有约1至约20个碳原子的有机二价连接基团，任选地含有 三唑，氧，氮或硫，或其组合，A是1,2,3,4-三唑，Y是O或N（R）2，其中R是H或C _{C 1至C 20烷基，Z为H，具有约1至约4个碳原子的直链或支链烷基或卤素，m为正整数，q为零 或正整数，p为零或正整数，W为插入W，其中X 1，Y和Z如上所定义，Rx为C（O）O（R 0 > 1 1），卤化物或R 1; 每个R 1独立地为H，C N H 2n + 1，C H n H 2n， -CH（O）CH 2，[CH 2 CH 2 CH 2 O] n R O > 4 ，N（R 4）2 N 2或[C n n 2n + 1 n，n为1至40，R 4为 H或C 2 H 2 s + 1，s = 0至40，i = 1至200，每个R 2 = 独立地是H或C 1 H 2t + 1，其中t为1至20，每个R 3独立地为H，COOR 1，卤素，N（R 1）2，或1，SO 2，NHR， CH 2 CH 2 CH 2，SO 3 M，M是H，碱金属盐，碱土金属盐或铵。}

公开(公告)号：WO2007035936A2

公开(公告)日：2007-03-29

申请号：PCT/US2006/037325

申请日：2006-09-22

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  ACOSTA, Erick, Jose ,  MURPHY, Peter, Michael ,  MCCALL, Andrew, Joseph ,  SWOREN, John, Christopher

Inventor： ACOSTA, Erick, Jose ,  MURPHY, Peter, Michael ,  MCCALL, Andrew, Joseph ,  SWOREN, John, Christopher

IPC: C08G63/00

CPC classification number: C07D249/04 ,  C08F220/18 ,  C08F220/34

Abstract: A copolymer for imparting repellency and stain resistance to substrates is disclosed of Formula 1 [R f -X 1 -A-X 1 -Y-C(O)-CZCH 2 ]m-[W q ]p Formula 1 wherein R f is a straight or branched perfluoroalkyl group having from about 2 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, each X 1 is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing a triazole, oxygen, nitrogen, or sulfur, or a combination thereof., A is a 1, 2, 3-triazole, Y is O or N(R) 2 wherein R is H or C 1 to C 20 alkyl, Z is H, a straight or branched alkyl group having from about 1 to about 4 carbon atoms, or halide, m is a positive integer, q is zero or a positive integer, p is zero or a positive integer, and W is insert W here wherein X 1 , Y, and Z are as defined above, Rx is C(O)O(R 1 ), C(O)N(R 2 ) 2 , OC(O)(R 1 ), SO 2 (R 1 ), C 6 (R 3 ) 5 , O(R 1 ), halide, or R 1 ; each R 1 is independently H, C N H 2n+1 , C n H 2n -CH(O)CH 2 , [CH 2 CH 2 O] i R 4 , [C n C 2n ]N(R 4 ) 2 or [C n H 2n ]C n F 2n+1 , n is 1 to 40, R 4 is H or C s H 2s+1 , s = 0 to 40, i = 1 to 200, each R 2 is independently H, or C t H 2t+1 wherein t is 1 to 20, each R 3 is independently H, COOR 1 , halogen, N(R 1 ) 2 , OR 1 , SO 2 NHR 1 , CH=CH 2 , or SO 3 M, M is H, alkali metal salt, alkaline earth metal salt, or ammonium.

Abstract translation: 公开了一种用于赋予基材防水性和耐污染性的共聚物：式1 [R 1 -X 1 -AX 1] YC（O）-CZCH 2] m- [W qq] p式1其中R f为直链或支链 具有约2至约20个碳原子的全氟烷基或其混合物，其任选被至少一个氧原子间隔，每个X 1独立地为具有约1至约20个碳原子的有机二价连接基团， 约20个碳原子，任选地含有三唑，氧，氮或硫或其组合，A是1,2,3-三唑，Y是O或N（R）2， 其中R是H或C 1至C 20烷基，Z是H，具有约1至约4个碳原子的直链或支链烷基或卤素，m 是正整数，q是零或正整数，p是零或正整数，并且W是插入W，其中X 1，Y和Z如上所定义，R x是C （O ）O（R 1）2，C（O）N（R 2）2，OC（O）（R 1） ），SO 2（R 1），C（R 3）5，S 5（R 1） O（R 1），卤化物或R 1; 每个R 1独立地为H，C≡NH 2n + 1，C≡H2n， -CH（O）CH 2，[CH 2 CH 2 O] i R ^{4，[C≡C2 N 1] N（R 4）2或[C n = 1至40，R 4 = n-1，n = 1至40，R 4 = 是H或C≡H2s + 1，s = 0到40，i = 1到200，每个R 2 = 独立地为H或C≡tH 2t + 1其中t为1至20，每个R 3独立地为H，COOR 1， 1，卤素，N（R 1）2，OR 1，SO 2，NHR 1， CH = CH 2或SO 3 M，M为H，碱金属盐，碱土金属盐或铵。 p>}