公开(公告)号：WO2009020906A2

公开(公告)日：2009-02-12

申请号：PCT/US2008072082

申请日：2008-08-04

Applicant: DU PONT ,  TAYLOR CHARLES KENNETH ,  MICHALCZYK MICHAEL JOSEPH ,  ACOSTA ERICK JOSE

Inventor： TAYLOR CHARLES KENNETH ,  MICHALCZYK MICHAEL JOSEPH ,  ACOSTA ERICK JOSE

IPC: C07F7/18 ,  C07C43/13 ,  C07C309/65 ,  C07F9/09 ,  C11D1/34

CPC classification number: C07C69/675 ,  C07C43/137 ,  C07C309/65 ,  C07F7/0852 ,  C07F7/1804 ,  C07F9/091 ,  C11D1/004

Abstract: A surfactant of formula (1) A surfactant of formula 1 (Rf-A)a- Q- ([B]k-R)b Formula 1 wherein a and b are each independently 1 or 2; Rf is a linear or branched perfluoroalkyl radical having from 2 to about 20 carbon atoms, optionally interrupted with at least one oxygen; R is a C1 to C20 linear, branched or cyclic alkyl, or a C6 to C10 aryl; B is -(CH2CHR1O)x-, k is 0 or 1, x is 1 to about 20, A is -(CH2)m[(CHR1 CH2O)]S - [(CH2)m (CH)tCHOH(CH2)m]e-, wherein each m is independently 0 to 3, s is 0 to about 30, t is 0 or 1, and e is 0 or 1, R1 is H or CH3, Q is: -OP(O)(O-M+)(O)-, -O-, -S-(CH2)m-C(O)-O-, -SO2-O- -CH2CH2O-C(O)CH2C(OH)(V)CH2C(O)O-; -(CH2CH2O)xCH2CH(OH)-(CH2CH2O)?-(CH2)m- Si[OSi(R2)3]2 -, -SO2NR2- -(CH2CH2O)ZC(O)CH(SO3-M+)CH2C(O)(OCH2CH2)Z - wherein z is 1 to about 15, or a bond when s is a positive integer, V is -C(O)OR3and R3 is H, CH3 or Rf; R2 is C1 to C4 alkyl, and M+ is a Group 1 metal or an ammonium (NHxR2y)+ cation wherein x + y = 4, and R2 is C1 to C4 alkyl, provided that when Q is -OP(O)(O-M+)(O)- or when Q is - (CH2CH2O)Z-C(O)CH(SO3-M+)CH2C(O)(OCH2CH2)Z- then at least one of s or e is a positive integer.

Abstract translation: 式（1）的表面活性剂式1的表面活性剂（Rf-A）a-Q-（[B] k-R）b式1其中a和b各自独立地为1或2; R f是具有2至约20个碳原子的直链或支链全氟烷基，任选地被至少一个氧中断; R为C1至C20直链，支链或环状烷基或C6至C10芳基; B是 - （CH 2 CHR 10）x - ，k是0或1，x是1至约20，A是 - （CH 2）m - [（CH 2 CH 2 O） 其中每个m独立地为0至3，s为0至约30，t为0或1，并且e为0或1，R 1为H或CH 3，Q为：-OP（O）（O- （O）-O-，-S-（CH 2）m -C（O）-O-，-SO 2 -O- -CH 2 CH 2 O-C（O）CH 2 C（OH） ; - （CH 2 CH 2 O）x CH 2 CH（OH） - （CH 2 CH 2 O）2 - （CH 2）m -Si [OSi（R 2）3] 2 - ， - SO 2 NR 2 - （CH 2 CH 2 O）ZC（O）CH（SO 3 - M +）CH 2 C ）（OCH 2 CH 2）z - ，其中z为1至约15，或者当s为正整数时为键，V为-C（O）OR 3且R 3为H，CH 3或R f; 条件是当Q为-OP（O）（O-甲基）时，R2为C1-C4烷基，M +为1族金属或铵（NHxR2y）+阳离子，其中x + y = 4，R2为C1- （O） - 或当Q是 - （CH2CH2O）ZC（O）CH（SO3-M +）CH2C（O）（OCH2CH2）Z-时，则s或e中的至少一个是正整数。

公开(公告)号：WO2009020912A3

公开(公告)日：2009-04-09

申请号：PCT/US2008072090

申请日：2008-08-04

Applicant: DU PONT ,  ACOSTA ERICK JOSE ,  TAYLOR CHARLES KENNETH

Inventor： ACOSTA ERICK JOSE ,  TAYLOR CHARLES KENNETH

IPC: C07F9/09 ,  C11D1/34

CPC classification number: C07F9/091 ,  C11D1/004 ,  C11D1/345

Abstract: A compound of Formula 1 Rf-A-OP(O)(O" M +)(O-RH) Formula 1 wherein Rf is a C2 to CQ linear or branched perfluoroalkyl optionally interrupted by one, two or three ether oxygen atoms; A is (CH2CF2)m(CH2)n-, (CH2)OSO2N(CH3)(CH2)P-, O(CF2)q(CH2)n or OCHFCF2OE-; m is 1 to 4; n, o, p, and r are each independently 2 to 20; q is 2; E is a C2 to C2Q linear or branched alkyl group optionally interrupted by oxygen, sulfur, or nitrogen atoms; a cyclic alkyl group, or a CQ to Ci o ary' group; M is a Group I metal or an ammonium cation (NHxR^y)+ wherein R2 is a Ci to C4 alkyl, x is 1 to 4, y is O to 3 and x + y is 4; and RH is a Ci to C2o linear, branched, or cyclic alkyl, or a CQ to C10 aryl, and its use as a surfactant is disclosed.

Abstract translation: 式1的化合物Rf-A-OP（O）（O“M +）（O-RH）式1其中Rf是任选被一个，两个或三个醚氧原子间隔的C2至CQ直链或支链全氟烷基; A 是（CH 2 CF 2）m（CH 2）n - ，（CH 2）OSO 2 N（CH 3）（CH 2）P - ，O（CF 2）q（CH 2）n或OCHFCF 2 OE-; m是1至4; n，o，p和 r各自独立地为2至20; q为2; E为任选被氧，硫或氮原子间隔的C2至C2Q直链或支链烷基;环状烷基或C 1 -C 10芳基; M 是I族金属或铵阳离子（NH x R y y）+，其中R 2是C 1至C 4烷基，x为1至4，y为0至3，x + y为4;且RH为C 1至C 20直链 ，支链或环状烷基，或C 10〜C 10芳基，及其作为表面活性剂的用途。

公开(公告)号：WO2009020912A2

公开(公告)日：2009-02-12

申请号：PCT/US2008/072090

申请日：2008-08-04

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  ACOSTA, Erick, Jose ,  TAYLOR, Charles, Kenneth

Inventor： ACOSTA, Erick, Jose ,  TAYLOR, Charles, Kenneth

IPC: C07F9/09 ,  C11D1/34

CPC classification number: C07F9/091 ,  C11D1/004 ,  C11D1/345

Abstract: A compound of Formula 1 Rf-A-OP(O)(O" M +)(O-RH) Formula 1 wherein Rf is a C2 to CQ linear or branched perfluoroalkyl optionally interrupted by one, two or three ether oxygen atoms; A is (CH2CF2)m(CH2)n-, (CH2)OSO2N(CH3)(CH2)P-, O(CF2)q(CH2)n or OCHFCF2OE-; m is 1 to 4; n, o, p, and r are each independently 2 to 20; q is 2; E is a C2 to C2Q linear or branched alkyl group optionally interrupted by oxygen, sulfur, or nitrogen atoms; a cyclic alkyl group, or a CQ to Ci o ary' group; M is a Group I metal or an ammonium cation (NHxR^y)+ wherein R2 is a Ci to C4 alkyl, x is 1 to 4, y is O to 3 and x + y is 4; and RH is a Ci to C2o linear, branched, or cyclic alkyl, or a CQ to C10 aryl, and its use as a surfactant is disclosed.

Abstract translation: 式1的化合物式1其中R f为C 2 -C 6直链或支链全氟烷基，其任选被一个，一个或多个C 1 -C 6烷基， 两个或三个醚氧原子; A是（CH 2 CF 2）m（CH 2）n - ，（CH 2）OSO 2 N（CH 3）（CH 2）p - ，O（CF 2）q（CH 2）n或OCHFCF 2 O- m是1至4; n，o，p和r各自独立地为2至20; q是2; E是任选被氧，硫或氮原子间隔的C2至C2Q直链或支链烷基; 环状烷基或C 1 -C 10芳基; M是第I族金属或铵阳离子（NH x R y）+，其中R 2是C 1 -C 4烷基，x是1至4，y是0至3且x + y是4; RH是C 1 -C 20直链，支链或环状烷基或C 6 -C 10芳基，并且公开了其作为表面活性剂的用途。

公开(公告)号：WO2011046793A1

公开(公告)日：2011-04-21

申请号：PCT/US2010/051733

申请日：2010-10-07

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  PENG, Sheng ,  SEVERAC, Romain ,  TAYLOR, Charles, Kenneth

Inventor： PENG, Sheng ,  SEVERAC, Romain ,  TAYLOR, Charles, Kenneth

IPC: C07C311/09 ,  C07C311/24 ,  C11D1/00 ,  A62D1/00

CPC classification number: C07C311/24 ,  A62D1/0071 ,  A62D1/0085 ,  C07C311/09

Abstract: A compound of Formula (I), wherein R a is linear or branched F(CF 2 ) n (CH 2 CF 2 ) m -, or linear or branched F(CF 2 )o interrupted by 1 to 6 catenary oxygen atoms, each oxygen bonded to two carbon atoms, m is 1 to 4, n is 2 to 6, o is 2 to 7, A is O or (CH 2 ) k -COO, R 1 is hydrogen or a methyl, R 2 and R 3 are each independently alkyl having 1 to 6 carbon atoms, and p, q and k are each independently integers from 1 to 10, which is suitable for use as a surfactant and in fire fighting formulations.

Abstract translation: 式（I）的化合物，其中R a是直链或支链的F（CF 2）n（CH 2 CF 2）m - 或被1至6个链状氧原子间隔的直链或支链的F（CF 2）o，每个氧键连接到两个碳原子 ，m为1至4，n为2至6，o为2至7，A为O或（CH 2）k-COO，R 1为氢或甲基，R 2和R 3各自为具有1至6个碳原子的烷基 ，p，q和k各自独立地为1至10的整数，其适合用作表面活性剂和消防制剂。

公开(公告)号：WO2009020906A3

公开(公告)日：2009-02-12

申请号：PCT/US2008/072082

申请日：2008-08-04

Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  TAYLOR, Charles, Kenneth ,  MICHALCZYK, Michael, Joseph ,  ACOSTA, Erick, Jose

Inventor： TAYLOR, Charles, Kenneth ,  MICHALCZYK, Michael, Joseph ,  ACOSTA, Erick, Jose

IPC: C07F7/18 ,  C07F9/09 ,  C07C43/13 ,  C07C309/65 ,  C11D1/34

Abstract: A surfactant of formula (1) A surfactant of formula 1 (Rf-A)a- Q- ([B]k-R)b Formula 1 wherein a and b are each independently 1 or 2; R f is a linear or branched perfluoroalkyl radical having from 2 to about 20 carbon atoms, optionally interrupted with at least one oxygen; R is a C 1 to C 20 linear, branched or cyclic alkyl, or a C 6 to C 10 aryl; B is -(CH 2 CHR 1 O) x-, k is 0 or 1, x is 1 to about 20, A is -(CH 2 ) m [(CHR 1 CH 2 O)] S - [(CH 2 ) m (CH) t CHOH(CH 2 )m] e -, wherein each m is independently 0 to 3, s is 0 to about 30, t is 0 or 1, and e is 0 or 1, R 1 is H or CH 3, Q is: -OP(O)(O-M + )(O)-, -O-, -S-(CH 2 ) m -C(O)-O-, -SO 2 -O- -CH 2 CH 2 O-C(O)CH 2 C(OH)(V)CH 2 C(O)O-; -(CH 2 CH 2 O) x CH 2 CH(OH)-(CH 2 CH 2 O) χ -(CH 2 ) m - Si[OSi(R 2 ) 3 ] 2 -, -SO 2 NR 2 - -(CH 2 CH 2 O) Z C(O)CH(SO 3 -M + )CH 2 C(O)(OCH 2 CH 2 ) Z - wherein z is 1 to about 15, or a bond when s is a positive integer, V is -C(O)OR 3 and R 3 is H, CH 3 or R f ; R 2 is C 1 to C 4 alkyl, and M + is a Group 1 metal or an ammonium (NH x R 2 y) + cation wherein x + y = 4, and R 2 is C 1 to C 4 alkyl, provided that when Q is -OP(O)(O - M + )(O)- or when Q is - (CH 2 CH 2 O) Z -C(O)CH(SO 3 -M+)CH 2 C(O)(OCH 2 CH 2 ) Z - then at least one of s or e is a positive integer.