公开(公告)号：WO2010104214A3

公开(公告)日：2010-09-16

申请号：PCT/JP2010/054718

申请日：2010-03-12

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED ,  KAWABATA, Tomonori ,  YAKO, Makoto

Inventor： KAWABATA, Tomonori ,  YAKO, Makoto

IPC: C07D301/12

Abstract: The invention provides a method for producing an olefin oxide which comprises reacting hydrogen peroxide and an olefin in a solvent containing water, a nitrile compound and a cyclic secondary amine compound, in the presence of a titanosilicate having a pore composed of a 12- or more-membered oxygen ring.

公开(公告)号：WO2010104214A2

公开(公告)日：2010-09-16

申请号：PCT/JP2010054718

申请日：2010-03-12

Applicant: SUMITOMO CHEMICAL CO ,  KAWABATA TOMONORI ,  YAKO MAKOTO

Inventor： KAWABATA TOMONORI ,  YAKO MAKOTO

CPC classification number: C07D301/12

Abstract: The invention provides a method for producing an olefin oxide which comprises reacting hydrogen peroxide and an olefin in a solvent containing water, a nitrile compound and a cyclic secondary amine compound, in the presence of a titanosilicate having a pore composed of a 12- or more-membered oxygen ring.

Abstract translation: 本发明提供了一种制备烯烃氧化物的方法，该方法包括在具有由12个或更多个孔组成的孔的钛硅酸盐存在下，使过氧化氢和烯烃在含有水，腈化合物和环状仲胺化合物的溶剂中反应 记录氧环。

公开(公告)号：WO2010067855A1

公开(公告)日：2010-06-17

申请号：PCT/JP2009/070721

申请日：2009-12-04

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED ,  KAWABATA, Tomonori ,  YAKO, Makoto

Inventor： KAWABATA, Tomonori ,  YAKO, Makoto

IPC: B01J29/89 ,  C01B37/00 ,  C07D301/03 ,  B01J37/06 ,  C07D301/04 ,  C07D301/12 ,  C07C37/60

CPC classification number: B01J29/89 ,  B01J37/06 ,  B01J2229/183 ,  B01J2229/34 ,  B01J2229/37 ,  C01B37/005

Abstract: The present invention relates to a method for producing a Ti-MWW precursor comprising: a first step of heating a mixture to prepare a solid, said mixture comprising a structure-directing agent, a compound containing a Group 13 element of the periodic table, a titanium-containing compound (1), a silicon-containing compound and water; and a second step of contacting the solid with a titanium-containing compound (2) and an inorganic acid.

Abstract translation: 本发明涉及一种生产Ti-MWW前体的方法，包括：加热混合物以制备固体的第一步骤，所述混合物包含结构导向剂，含有周期表第13族元素的化合物， 含钛化合物（1），含硅化合物和水; 和使固体与含钛化合物（2）和无机酸接触的第二步骤。

公开(公告)号：WO2009110635A1

公开(公告)日：2009-09-11

申请号：PCT/JP2009/054589

申请日：2009-03-03

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED ,  KAWABATA, Tomonori ,  ABEKAWA, Hiroaki ,  YAKO, Makoto

Inventor： KAWABATA, Tomonori ,  ABEKAWA, Hiroaki ,  YAKO, Makoto

IPC: B01J29/89 ,  B01J29/90 ,  C07D301/02

CPC classification number: C07D301/02 ,  B01J29/89 ,  B01J29/90 ,  B01J38/50 ,  Y02P20/584 ,  Y02P20/588

Abstract: The present invention provides a regeneration method of a titanosilicate catalyst, specifically provides a regeneration method of a titanosilicate catalyst which comprises contacting the titanosilicate catalyst deteriorated in catalytic ability with a nitrile compound or a mixture of water and a nitrile compound at a temperature from 25°C to 200°C.

Abstract translation: 本发明提供钛硅酸盐催化剂的再生方法，具体提供钛硅酸盐催化剂的再生方法，该方法包括使催化性能劣化的钛硅酸盐催化剂与腈化合物或水与腈化合物的混合物在25℃ C至200°C。

公开(公告)号：WO2008156205A1

公开(公告)日：2008-12-24

申请号：PCT/JP2008/061592

申请日：2008-06-19

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED ,  ABEKAWA, Hiroaki ,  KAWABATA, Tomonori ,  YAKO, Makoto

Inventor： ABEKAWA, Hiroaki ,  KAWABATA, Tomonori ,  YAKO, Makoto

IPC: C07D301/06

CPC classification number: C07D301/06 ,  Y02P20/52

Abstract: There is disclosed a method for producing propylene oxide, which includes: reacting propylene, oxygen, and hydrogen in the presence of a noble metal catalyst and a titanosilicate catalyst in a liquid phase containing a polycyclic compound, which is unsubstituted or substituted with at least one substituent selected from Group B below, wherein the polycyclic compound is composed of two or more identical or different ring compounds selected from Group A below and the ring compounds are fused, directly bonded, or bonded by a linkage group selected from the group consisting of an oxygen atom, carbon chain, and a group composed of oxygen atom(s) and a carbon chain, provided that said polycyclic compound is not a polycyclic compound having hydroxy groups or oxo groups at para or. ortho positions. Group A consisting of benzene, cyclopentadiene, cycloheptatriene, furane, pyrane, cyclopentene, cyclopentane, cyclohexane, cyclohexene, cyclohexadiene, cycloheptane, cycloheptene, and cycloheptadiene. Group B consisting of halogen atom, alkyl group, alkenyl group, alkoxy group, hydroxyalkyl group, acyl group, oxo group, hydroxy group, and cyano group.

Abstract translation: 公开了一种生产环氧丙烷的方法，其包括：在贵金属催化剂和钛硅酸盐催化剂存在下，在含有多环化合物的液相中使丙烯，氧和氢反应，该多环化合物是未取代的或被至少一个 取代基，其中所述多环化合物由两种或更多种相同或不同的选自下述A组的环化合物组成，并且所述环化合物通过选自以下的连接基团进行稠合，直接键合或键合： 氧原子，碳链和由氧原子和碳链组成的基团，条件是所述多环化合物不是在对位或具有羟基或氧代基的多环化合物。 邻位。 A组由苯，环戊二烯，环庚三烯，呋喃，吡喃，环戊烯，环戊烷，环己烷，环己烯，环己二烯，环庚烷，环庚烯和环庚二烯组成。 B族由卤素原子，烷基，烯基，烷氧基，羟基烷基，酰基，氧代基，羟基和氰基组成。