公开(公告)号：WO2014088820A1

公开(公告)日：2014-06-12

申请号：PCT/US2013/071152

申请日：2013-11-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： HINTZER, Klaus ,  KASPAR, Harald ,  KOENIGSMANN, Herbert ,  TRAUNSPURGER, Helmut ,  ZIPPLIES, Tilman C.

IPC: C08F214/26

CPC classification number: C08L27/18 ,  C08F214/262

Abstract: A method of making a highly fluorinated polymers and resulting aqueous mixtures. The method comprising polymerizing one or more perfluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a perfluorinated polymer. The polymerizable fluorinated emulsifier has the formula X 2 C=CX(CF 2 ) m (CH 2 ) n [O-(CX 2 ) p ] q -[O-(CX 2 ) r ] s -[O-(CX 2 -CX 2 )] t -[(O) w -(CX 2 ) u ] v -[CH 2 ] z -Y. The method also provides for isolating the highly fluorinated polymer and post-fluorinating the isolated highly fluorinated polymer.

Abstract translation: 制备高度氟化聚合物和所得含水混合物的方法。 该方法包括在可聚合的氟化乳化剂的存在下在水乳液聚合中聚合一种或多种全氟化单体以形成全氟化聚合物。 可聚合的氟化乳化剂具有式X2C = CX（CF2）m（CH2）n [O-（CX2）p] q- [O-（CX2）r] s- [O-（CX2-CX2）] t- [ （O）w - （CX 2）u] v - [CH 2] z Y。 该方法还提供了分离高度氟化的聚合物和后氟化分离的高度氟化的聚合物。

公开(公告)号：WO2016028539A1

公开(公告)日：2016-02-25

申请号：PCT/US2015/044555

申请日：2015-08-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： CHEN, Lisa P. ,  HINTZER, Klaus ,  KASPAR, Harald ,  LOCHHAAS, Kai H. ,  MUGGLI, Mark W. ,  SCHROOTEN, Jens ,  SOHLO, Allen M. ,  TRAUNSPURGER, Helmut ,  WEILANDT, Karl D. ,  ZIPPLIES, Tilman C.

IPC: C08F214/26 ,  B32B27/28 ,  C08L27/18

CPC classification number: C08F214/26 ,  B32B27/08 ,  B32B27/20 ,  B32B27/304 ,  B32B27/308 ,  B32B27/322 ,  B32B2262/10 ,  B32B2264/102 ,  B32B2307/202 ,  B32B2307/7242 ,  B32B2597/00 ,  B32B2605/08 ,  C08F214/262

Abstract: Described herein is a composition comprising a fluorothermoplastic polymer, wherein the fluorothermoplastic polymer is derived from: (a) 60-85 mol% tetrafluoroethene; (b) 2-12 mol% hexafluoropropene; (c) 10-30 mol% vinylidene fluoride; (d) 0.2 to 5 mol% of a bromine-containing monomer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

Abstract translation: 本文描述的是包含氟热塑性聚合物的组合物，其中所述含氟热塑性聚合物衍生自：（a）60-85mol％四氟乙烯; （b）2-12mol％六氟丙烯; （c）10-30摩尔偏二氟乙烯; （d）0.2〜5摩尔％的含溴单体。 这种组合物可用于例如燃料软管应用中的多层结构中。

公开(公告)号：WO2017151935A1

公开(公告)日：2017-09-08

申请号：PCT/US2017/020473

申请日：2017-03-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： ZIPPLIES, Tilman, C. ,  HINTZER, Klaus ,  TRAUNSPURGER, Helmut ,  WEILANDT, Karl, D.

IPC: B01J41/14 ,  B01J47/00 ,  B01J49/00 ,  B01J20/26 ,  C07C51/08 ,  B01J41/05 ,  C08F6/16 ,  C02F1/28 ,  C02F1/42

Abstract: Provided are methods for removing a perfluorinated alkanoic acid from solutions containing the perfluorinated alkanoic acid and a fluorinated alkoxy acid. These methods include contacting the first solution with an anion-exchange resin to produce a second solution and a resultant anion-exchange resin having perfluorinated alkanoic acid adsorbed thereto, wherein the perfluorinated alkanoic acid is present in the first solution at a first concentration and is present in the second solution at a second concentration which is lower than the first concentration, and separating the second solution from the resultant anion-exchange resin.

Abstract translation: 提供了用于从含有全氟化链烷酸和氟化烷氧基酸的溶液中除去全氟化链烷酸的方法。 这些方法包括使第一溶液与阴离子交换树脂接触以产生第二溶液和所得到的吸附有全氟化链烷酸的阴离子交换树脂，其中全氟化链烷酸以第一浓度存在于第一溶液中并且存在 在第二溶液中以低于第一浓度的第二浓度进行分离，并将第二溶液与所得到的阴离子交换树脂分离。

公开(公告)号：WO2016137851A1

公开(公告)日：2016-09-01

申请号：PCT/US2016/018845

申请日：2016-02-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： JOCHUM, Florian D. ,  HINTZER, Klaus ,  LOCHHAAS, Kai Helmut ,  KASPAR, Harald ,  ZIPPLIES, Tilman C. ,  TRAUNSPURGER, Helmut

IPC: C08F214/22 ,  C08F214/26 ,  C08F216/12 ,  C08F259/08

CPC classification number: C08F214/222 ,  C08F214/22 ,  C08F214/282 ,  C08F259/08 ,  C08F214/26 ,  C08F216/125 ,  C08F216/1408

Abstract: Curable fluoropolymer containing repeating units derived from VDF and TFE and at least one other fluorinated comonomer and further containing -CF 2 CH 2 I end groups and branching sites derived from one or more perfluorinated bisolefinic ether(s) used as modifier(s), wherein the one or more perfluorinated bisolefinic ether(s) used as modifier(s) correspond to the general formula: CF 2= CF-(CF 2 ) n -O-(R 1 )-O-(CF 2 ) m CF=CF 2 wherein n and m are independent from each other either 1 or 0 and wherein R 1 represents a perfluorinated linear or branched, cyclic or acyclic aliphatic or aromatic hydrocarbon residue that may be interrupted by one or more oxygen atoms and comprises up to 30 carbon atoms. Further provided are methods of making the curable fluoropolymers and for making an article containing the curable polymers.

Abstract translation: 含有衍生自VDF和TFE的重复单元和至少一种其它氟化共聚单体并且还含有-CF 2 CH 2 I端基和衍生自用作改性剂的一种或多种全氟化双烯烃醚的支化位点的可固化含氟聚合物，其中所述一种或多种 用作改性剂的全氟化双烯烃醚对应于通式CF2 = CF-（CF2）nO-（R1）-O-（CF2）mCF = CF2其中n和m彼此独立地为1 或0，并且其中R 1表示可以被一个或多个氧原子中断并且包含至多30个碳原子的全氟化的直链或支链，环状或无环脂族或芳族烃残基。 进一步提供制备可固化含氟聚合物和制备含有可固化聚合物的制品的方法。

公开(公告)号：WO2016028582A1

公开(公告)日：2016-02-25

申请号：PCT/US2015/044964

申请日：2015-08-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： CHEN, Lisa P. ,  HINTZER, Klaus ,  KASPAR, Harald ,  LOCHHAAS, Kai H. ,  MUGGLI, Mark W. ,  SCHROOTEN, Jens ,  SOHLO, Allen M. ,  TRAUNSPURGER, Helmut ,  WEILANDT, Karl D. ,  ZIPPLIES, Tilman C.

IPC: C08L27/18 ,  C08L27/16 ,  C08L27/20

CPC classification number: C08L27/18 ,  B32B1/08 ,  B32B7/12 ,  B32B25/08 ,  B32B25/12 ,  B32B25/14 ,  B32B27/18 ,  B32B27/20 ,  B32B27/304 ,  B32B27/322 ,  B32B2264/0242 ,  B32B2264/0257 ,  B32B2264/102 ,  B32B2270/00 ,  B32B2307/50 ,  B32B2307/7265 ,  B32B2597/00 ,  B32B2605/08 ,  C08F259/08 ,  C08L2205/025

Abstract: Described herein is a composition comprising (i) a hydrofluorothermoplastic polymer, wherein the hydrofluorothermoplastic polymer is derived from: (a) 50-85 mol% tetrafluoroethene; (b) 2-15 mol% hexafluoropropene; (c) 10-35 mol% vinylidene fluoride; and (d) 0.1 to 5 mol% of a bromine-containing monomer; and (ii) a perhalogenated thermoplastic polymer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

Abstract translation: 本文描述的是一种组合物，其包含（i）氢氟发热聚合物，其中所述氢氟热塑性聚合物衍生自：（a）50-85mol％四氟乙烯; （b）2-15摩尔％六氟丙烯; （c）10-35mol％偏二氟乙烯; 和（d）0.1〜5摩尔％的含溴单体; 和（ii）全卤代热塑性聚合物。 这种组合物可用于例如燃料软管应用中的多层结构中。

公开(公告)号：WO2015066166A1

公开(公告)日：2015-05-07

申请号：PCT/US2014/062878

申请日：2014-10-29

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LOCHHAAS, Kai Helmut ,  HINTZER, Klaus ,  ZIPPLIES, Tilman C. ,  KASPAR, Harald ,  JOCHUM, Florian D. ,  TRAUNSPURGER, Helmut ,  KURZ, Arnd ,  BISSINGER, Peter

IPC: C08F214/22

CPC classification number: C08K5/1545 ,  C08F214/22 ,  C08F214/222 ,  C08K3/30 ,  C08K5/14 ,  C08K5/175 ,  C08K2003/3054

Abstract: Described are methods of making a curable fluoropolymer having repeating units derived from vinylidenfluoride (VDF) and at least one perfluorinated monomer selected from hexafluoropropene (HFP), tetrafluoroethene (TFE), a perfluorovinyl ether (PAVE), a perfluoroallylether (PAAVE) or a combination thereof. The method includes polymerising the monomers in an aqueous medium in a radical reaction containing one or more reaction initiators, one or more chain transfer agent containing one or more halogens selected from iodine, bromine or a combination thereof and one or more non-fluorinated aliphatic polyhydroxy emulsifiers. The polymerization is carried out without adding a fluorinated emulsifier. Also provided are curable fluoropolymers obtainable by such methods and cured fluoropolymers obtainable by curing the curable fluoropolymers, and their applications.

Abstract translation: 描述了制备具有衍生自偏氟乙烯（VDF）的重复单元和至少一种选自六氟丙烯（HFP），四氟乙烯（TFE），全氟乙烯基醚（PAVE），全氟烯烃（PAAVE）或组合物）的全氟化单体的可固化含氟聚合物的方法 它们。 该方法包括在包含一个或多个反应引发剂的自由基反应中在水性介质中聚合单体，一种或多种含有一种或多种选自碘，溴或其组合的卤素的链转移剂和一种或多种非氟化脂族多羟基 乳化剂。 在不加入氟化乳化剂的情况下进行聚合。 还提供了可通过这些方法获得的可固化含氟聚合物和通过固化可固化含氟聚合物获得的固化的氟聚合物及其应用。

公开(公告)号：WO2014088804A1

公开(公告)日：2014-06-12

申请号：PCT/US2013/070886

申请日：2013-11-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： HINTZER, Klaus ,  KASPAR, Harald ,  KOENIGSMANN, Herbert ,  TRAUNSPURGER, Helmut ,  ZIPPLIES, Tilman C.

IPC: C08F214/18 ,  C08F214/26

CPC classification number: C08F214/262 ,  C08F214/184 ,  C08L27/18 ,  C08L2201/54

Abstract: A method of making a partially fluorinated polymer dispersions and resulting aqueous mixtures. The method comprising polymerizing one or more fluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a fluorinated polymer. The polymerizable fluorinated emulsifier has the formula X 2 C=CX(CF 2 )m(CH 2 )n[0-(CX 2 )p]q-[O-(CX 2 ) r ] s - [O-(CX 2 -CX 2 )] t -[(O) w -(CX 2 )u]v -[CH 2 ] z -Y.

Abstract translation: 制备部分氟化聚合物分散体和所得含水混合物的方法。 该方法包括在可聚合的氟化乳化剂的存在下在水乳液聚合中聚合一种或多种氟化单体以形成氟化聚合物。 可聚合的氟化乳化剂具有式X2C = CX（CF2）m（CH2）n [0-（CX2）p] q- [O-（CX2）r] s- [O-（CX2-CX2）] t- [ （O）w - （CX 2）u] v - [CH 2] z Y。

公开(公告)号：WO2007120348A1

公开(公告)日：2007-10-25

申请号：PCT/US2006/062312

申请日：2006-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： HINTZER, Klaus ,  KASPAR, Harald ,  TRAUNSPURGER, Helmut ,  ZIPPLIES, Tilman

IPC: C08F14/22 ,  C08F14/20 ,  C08F2/30 ,  C08J3/02

CPC classification number: D06M15/277 ,  C08F14/18 ,  C08F2/24

Abstract: A method for polymerizing, in an aqueous medium, at least one fluorinated monomer in the presence of a non-copolymerizable, non-fluorinated surfactant. The surfactant is generally selected from a non-ionic surfactant, a primary anionic surfactant, or a combination thereof. Fluorinated surfactants are not utilized. The resulting partially fluorinated polymer in the aqueous medium is either a semi-crystalline polymer or a crystalline polymer.

Abstract translation: 一种在水性介质中在不可共聚的非氟化表面活性剂存在下聚合至少一种氟化单体的方法。 表面活性剂通常选自非离子表面活性剂，初级阴离子表面活性剂或其组合。 不使用氟化表面活性剂。 在水性介质中得到的部分氟化的聚合物是半结晶聚合物或结晶聚合物。