公开(公告)号：WO2004063288A1

公开(公告)日：2004-07-29

申请号：PCT/US2004/000323

申请日：2004-01-07

Applicant: APS LABORATORY

Inventor： RYANG, Hong-Son

IPC: C09C1/36

CPC classification number: C09C3/06 ,  C01P2002/50 ,  C09C1/40

Abstract: Disclosed are metal oxide sols made by mixing at least one metal alkoxide, wherein the metal is a transition metal, a post-transition metal, an alkali metal, or alkaline earth metal; at least one organosilane; at least one boron oxide compound selected from the group consisting of boric acid, alkoxy boron compounds, hydrocarbyl boric acids, hydrocarbyl hydroxy boron alkoxides, and hydroxy boron alkoxides; and a liquid. Also disclosed are composites containing a polymer and the metal oxide sols.

Abstract translation: 公开了通过混合至少一种金属醇盐制备的金属氧化物溶胶，其中金属是过渡金属，后过渡金属，碱金属或碱土金属; 至少一种有机硅烷; 至少一种选自硼酸，烷氧基硼化合物，烃基硼酸，烃基羟基硼醇盐和羟基硼醇盐的氧化硼化合物; 和液体。 还公开了含有聚合物和金属氧化物溶胶的复合材料。

公开(公告)号：WO2006069087A3

公开(公告)日：2006-06-29

申请号：PCT/US2005/046235

申请日：2005-12-21

Applicant: APS LABORATORY ,  RYANG, Hong-Son

Inventor： RYANG, Hong-Son

IPC: B32B5/16

Abstract: Disclosed are metal chalcogenide nanocomposites made of guest metal chalcogenide precursors and host metal oxide sols made by mixing at least one metal alkoxide, at least one organosilane, at least one boron oxide compound, and a liquid, and chalcogenizing the mixture. Also disclosed are dielectric nano-composites containing a dielectric material such as a polymer and the metal chalcogenide nanocomposites.

公开(公告)号：WO2006093799A2

公开(公告)日：2006-09-08

申请号：PCT/US2006/006444

申请日：2006-02-24

Applicant: APS LABORATORY ,  RYANG, Hong-Son

Inventor： RYANG, Hong-Son

CPC classification number: C08K5/521 ,  C01B25/36 ,  C01B25/37 ,  C01B25/372 ,  C01B25/377 ,  C08K5/057 ,  C08K5/5419 ,  C08L25/06

Abstract: Disclosed are metal phosphate sols made by mixing at least one metal oxide, at least one phosphate precursor, at least one organosilane, and a liquid. Also disclosed are nanocomposites containing the metal phosphate sols and at least one of metal nanoparticle and metal-chalcogenide nanoparticle. The nanocomposites containing metal nanoparticles may be chalcogenized to provide nanocomposites containing metal-chalcogenide nanoparticles. Also disclosed are composites containing a dielectric material such as a polymer and at least one of the metal phosphate sol and the nanocomposite.

Abstract translation: 公开了通过混合至少一种金属氧化物，至少一种磷酸盐前体，至少一种有机硅烷和液体制备的金属磷酸盐溶胶。 还公开了含有金属磷酸盐溶胶和金属纳米颗粒和金属硫族化物纳米颗粒中的至少一种的纳米复合材料。 含有金属纳米颗粒的纳米复合材料可以被硫化，以提供含有金属 - 硫族化物纳米颗粒的纳米复合材料。 还公开了包含介电材料如聚合物和至少一种金属磷酸盐溶胶和纳米复合材料的复合材料。

公开(公告)号：WO2007021965A2

公开(公告)日：2007-02-22

申请号：PCT/US2006/031429

申请日：2006-08-10

Applicant: APS LABORATORY ,  RYANG, Hong-Son

Inventor： RYANG, Hong-Son

IPC: C08G63/49

CPC classification number: B01J21/08 ,  B82Y30/00 ,  C01B33/14

Abstract: Disclosed are silica sols made by combining at least one hydrolysable silane, at least one organofunctional silane, at least one boron oxide compound, and a liquid, or silica sols made by combining at least one hydrolysable silane, at least one organofunctional silane, at least one acid catalyst, and a liquid to provide an intermediate sol and combining at least one base catalyst with the intermediate sol. Also disclosed are nanocomposites containing the silica sols and at least one of metal nanoparticle, metal-chalcogenide nanoparticle, metal oxide nanoparticle, and metal phosphate nanoparticle. Further disclosed are composites containing a polymer material and at least one of the silica sol and the nanocomposite.

Abstract translation: 公开了通过组合至少一种可水解硅烷，至少一种有机官能硅烷，至少一种氧化硼化合物和液体或二氧化硅溶胶制成的二氧化硅溶胶，所述溶胶通过将至少一种可水解硅烷， 至少一种有机官能硅烷，至少一种酸催化剂和液体以提供中间体溶胶并将至少一种碱催化剂与中间体溶胶结合。 还公开了含有硅溶胶和金属纳米颗粒，金属硫属化物纳米颗粒，金属氧化物纳米颗粒和金属磷酸盐纳米颗粒中的至少一种的纳米复合材料。 还公开了包含聚合物材料和硅溶胶和纳米复合材料中的至少一种的复合材料。

公开(公告)号：WO2005035668A2

公开(公告)日：2005-04-21

申请号：PCT/US2004/013066

申请日：2004-04-28

Applicant: APS LABORATORY

Inventor： RYANG, Hong-Son

IPC: C09C

CPC classification number: C09C3/00 ,  B82Y30/00 ,  C01P2002/52 ,  C01P2004/64 ,  C03C1/008 ,  C03C17/02 ,  C03C2218/113 ,  C09C1/40 ,  C09C3/006 ,  C09C3/06 ,  C09C3/10 ,  C09C3/12

Abstract: Disclosed are nanocomposites made of guest metal nanoparticles and metal oxide sols made by mixing at least one metal alkoxide, at least one organosilane, at least one boron oxide compound, and a liquid. Also disclosed are dielectric composites containing a dielectric material such as a polymer and the nanocomposites.

Abstract translation: 公开了由客体金属纳米颗粒和通过混合至少一种金属醇盐，至少一种有机硅烷，至少一种氧化硼化合物和液体制成的金属氧化物溶胶制成的纳米复合材料。 还公开了包含介电材料如聚合物和纳米复合材料的介电复合材料。