-
公开(公告)号:WO2020053191A1
公开(公告)日:2020-03-19
申请号:PCT/EP2019/074066
申请日:2019-09-10
Applicant: BASF CORPORATION , BASF SE
Inventor: MCGUIRE, Robert , OEZKIRIM, Faruk , MUELLER, Ulrich
Abstract: The present invention relates to a process for preparing a zeolitic material having framework type AEI and having a framework structure which comprises a tetravalent element Y, a trivalent element X, and O. Further, the present invention relates to a zeolitic material having framework type AEI and having a framework structure which comprises a tetravalent element Y, a trivalent element X, and O, preferably obtainable or obtained by said process, and further relates to the use of said zeolitic material as a catalytically active material, as a catalyst, or as a catalyst component.
-
公开(公告)号:WO2018210809A1
公开(公告)日:2018-11-22
申请号:PCT/EP2018/062518
申请日:2018-05-15
Applicant: BASF SE , BASF CORPORATION
Inventor: MCGUIRE, Robert , MOINI, Ahmad , MÜLLER, Ulrich
Abstract: A process for preparing a zeolitic material having framework type AEI and having a framework structure which comprises a tetravalent element Y, a trivalent element X, and oxygen, said process comprising (i) providing a zeolitic material having framework type CHA and having a framework structure comprising the tetravalent element Y, the trivalent element X, and oxygen; (ii) preparing a synthesis mixture comprising the zeolitic material provided in (i), water, a source of the tetravalent element Y other than the zeolitic material provided in (i), and an AEI framework structure directing agent; (iii) subjecting the synthesis mixture prepared in (ii) to hydrothermal synthesis conditions comprising heating the synthesis mixture to a temperature in the range of from 100 to 200 °C and keeping the synthesis mixture at a temperature in this range under autogenous pressure, obtaining the zeolitic material having framework type AEI; wherein Y is one or more of Si, Ge, Sn, Ti, Zr; wherein X is one or more of Al, B, Ga, In; wherein in the framework structure of the zeolitic material provided in (i), the molar ratio Y:X, calculated as YO 2 : X 2 O 3 , is at most 20:1.
-
3.
公开(公告)号:WO2018210815A1
公开(公告)日:2018-11-22
申请号:PCT/EP2018/062531
申请日:2018-05-15
Applicant: BASF SE , BASF CORPORATION
Inventor: MOINI, Ahmad , MCGUIRE, Robert , MÜLLER, Ulrich
Abstract: A process for preparing a zeolitic material comprising a metal M, having framework type AEI, and having a framework structure which comprises a tetravalent element Y, a trivalent element X, and oxygen, said process comprising (i) providing a zeolitic material comprising the metal M, having a framework type other than AEI, and having a framework structure comprising the trivalent element X, and oxygen; (ii) preparing a synthesis mixture comprising the zeolitic material provided in (i), water, a source of the tetravalent element Y, and an AEI framework structure directing agent; (iii) subjecting the synthesis mixture prepared in (ii) to hydrothermal synthesis conditions comprising heating the synthesis mixture to a temperature in the range of from 100 to 200 °C and keeping the synthesis mixture at a temperature in this range under autogenous pressure, obtaining the zeolitic material having framework type AEI; wherein Y is one or more of Si, Ge, Sn, Ti, Zr; wherein X is one or more of Al, B, Ga, In; wherein M is a transition metal of groups 7 to 12 of the periodic table of elements.
-
公开(公告)号:WO2018096171A1
公开(公告)日:2018-05-31
申请号:PCT/EP2017/080654
申请日:2017-11-28
Applicant: BASF SE
Inventor: MCGUIRE, Robert , JANKE, Christiane , MÜLLER, Ulrich , SCHWAB, Ekkehard
Abstract: The present invention relates to aatalyst comprising one or more metal oxides and/or metalloid oxides and a zeolitic material having the CHA framework structure comprising YO 2 and X 2 O 3 , wherein Y is a tetravalent element and X is a trivalent element, wherein the zeolitic material comprises one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof, and wherein the framework of the zeolitic material comprised in the catalyst contains substantially no phosphorous, as well as to a process for the preparation of a catalyst comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba, and combinations of two or more thereof and to a catalyst obtainable therefrom. Furthermore, the present invention relates to a method for the conversion of oxygenates to olefins employing the inventive catalyst, as well as to the use of the inventive catalyst in specific applications.
-
公开(公告)号:WO2019223761A1
公开(公告)日:2019-11-28
申请号:PCT/CN2019/088123
申请日:2019-05-23
Applicant: BASF SE , BASF (CHINA) COMPANY LIMITED
Inventor: PARVULESCU, Andrei-Nicolae , MCGUIRE, Robert , MUELLER, Ulrich , ZHANG, Weiping , MENG, Xiangju , XIAO, Feng-Shou , YOKOI, Toshiyuki , GIES, Hermann , MARLER, Bernd , KOLB, Ute , DE VOS, Dirk
IPC: B01J29/06
Abstract: The present invention relates to a rare earth element containing zeolitic material having a framework structure selected from the group consisting of AEI, AFT, AFV, AFX, AVL, CHA, EMT, GME, KFI, LEV, LTN, and SFW, including mixtures of two or more thereof, the framework structure of the zeolitic material comprising SiO 2 and X 2 O 3 , wherein X stands for a trivalent element, wherein the zeolitic material displays an SiO 2 : X 2 O 3 molar ratio in the range of from 2 to 20, and wherein the zeolitic material contains one or more rare earth elements as counter-ions at the ion exchange sites of the framework structure. Furthermore, the present invention relates to a process for the production of the inventive rare earth element containing zeolitic material as well as to the use of the inventive rare earth element containing zeolitic material as such and as obtainable and/or obtained according to the inventive process.
-
公开(公告)号:WO2019030279A1
公开(公告)日:2019-02-14
申请号:PCT/EP2018/071495
申请日:2018-08-08
Applicant: BASF SE
Inventor: MCGUIRE, Robert , WECHSUNG, Achim , KURETSCHKA, Christiane , JEVTOVIKJ, Ivana , KUSCHEL, Andreas , SCHUNK, Stephan
IPC: B01J37/03 , B01J37/04 , B01J23/26 , B01J29/78 , B01J29/85 , B01J37/00 , C07C1/04 , C10G2/00 , B01J35/00
Abstract: The present invention relates to a composition comprising a) a molding comprising a zeolitic material having framework type CHA, wherein the zeolitic material comprises one or more alkaline earth metals M and b) a mixed metal oxide comprising chromium, zinc, and aluminium. It also relates to the use of the composition in a process for producing C2 to C4 olefins from syngas.
-
公开(公告)号:WO2019243420A1
公开(公告)日:2019-12-26
申请号:PCT/EP2019/066202
申请日:2019-06-19
Applicant: BASF SE
Inventor: KURETSCHKA, Christiane , MCGUIRE, Robert , JEVTOVIKJ, Ivana , REINING, Sven , LIPP, Stefan , PARVULESCU, Andrei-Nicolae , NIEDERLE, Astrid Elisa , GESKE, Michael
Abstract: The present invention relates to a composition comprising a) a molding comprising a zeolitic material having an AEI-type framework structure, wherein the zeolitic material has a framework structure comprising Si, a trivalent element X, and oxygen, wherein the zeolitic material further comprises one or more alkali metals AM and/or one or more alkaline earth metals AEM; and b) a mixed metal oxide comprising chromium, zinc, and aluminum; and to a process for its production, as well as to the molding and the mixed metal oxide as such, respectively, as obtainable or obtained according to the inventive production process, as well as to the composition as obtainable or obtained according to the inventive production process. In addition to these, the present invention further relates to the use of the inventive composition as a catalyst or as a catalyst component, as well as to a process for preparing C2 to C4 olefins from a synthesis gas comprising hydrogen and carbon monoxide.
-
公开(公告)号:WO2019242618A1
公开(公告)日:2019-12-26
申请号:PCT/CN2019/091745
申请日:2019-06-18
Applicant: BASF SE , BASF (CHINA) COMPANY LIMITED
Inventor: PARVULESCU, Andrei-Nicolae , MCGUIRE, Robert , MUELLER, Ulrich , MENG, Xiangju , XIAO, Feng-Shou , YOKOI, Toshiyuki , DE VOS, Dirk , MARLER, Bernd , GIES, Hermann , KOLB, Ute , ZHANG, Weiping
Abstract: The present invention relates to a process for the preparation of a zeolitic material SiO 2 and X 2 O 3 in its framework structure, wherein X stands for a trivalent element, wherein said process comprises interzeolitic conversion of a first zeolitic material comprising SiO 2 and X 2 O 3 in its framework structure, wherein the first zeolitic material has an FER-, TON-, MTT-, BEA-, MEL-, MWW-, MFS-, and/or M FI-type framework structure to a second zeolitic material comprising SiO 2 and X 2 O 3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material. Furthermore, the present invention relates to a zeolitic material per se as obtainable and/or obtained according to the inventive process and to its use, in particular as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.
-
公开(公告)号:WO2018197471A1
公开(公告)日:2018-11-01
申请号:PCT/EP2018/060444
申请日:2018-04-24
Applicant: BASF SE
Inventor: MCGUIRE, Robert , JANKE, Christane , TITLBACH, Sven , SCHWAB, Ekkehard , MÜLLER, Ulrich
Abstract: The present invention relates to a process for the conversion of methanol in p-xylene comprising the use a molding which comprises a zeolitic material, phosphorous, one or more metals M of the groups 3, 6, 10 to 14 of the periodic system of the elements, and a binder material.
-
10.
公开(公告)号:WO2021104264A1
公开(公告)日:2021-06-03
申请号:PCT/CN2020/131162
申请日:2020-11-24
Applicant: BASF SE , BASF ADVANCED CHEMICALS CO., LTD.
Inventor: PARVULESCU, Andrei-Nicolae , MCGUIRE, Robert , MUELLER, Ulrich , ZHANG, Weiping , SHI, Chuan
Abstract: A rare earth element containing zeolitic material having an AEI-type framework structure, the framework structure of the zeolitic material comprising SiO 2 and X 2O 3, X being a trivalent element, wherein the zeolitic material contains one or more rare earth elements as counter-ions at the ion exchange sites of the framework structure, and wherein the zeolitic material is obtainable and/or obtained according to a process involving the hydrothermal treatment of the rare earth element containing zeolitic material at a temperature in the range of from 400 to 1,000 ℃. A coated monolith substrate comprising a rare earth element containing zeolitic material having an AEI-type framework structure, wherein the zeolitic material is supported on the monolith substrate. A process for the production of a coated monolith substrate comprising a rare earth element containing zeolitic material having an AEI-type framework structure.
-
-
-
-
-
-
-
-
-