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1.发明申请PROCESS FOR METHYLATING NAPHTHALENIC COMPOUNDS USING A ZEOLITE CATALYST WHEREIN A PART OF THE AL ATOM HAS BEEN REPLACED BY FE, THE CATALYST AND A METHOD FOR PREPARING THE CATALYST 审中-公开使用沸石催化剂甲基化的方法，其中一部分原子被FE，催化剂和制备催化剂的方法替代
公开(公告)号：WO02060581A3
公开(公告)日：2003-03-20
申请号：PCT/US0202044
申请日：2002-01-22
Applicant: BP CORP NORTH AMERICA INC , PENN STATE RES FOUND
Inventor： SONG CHUNSHAN , SHEN JIAN-PING , LILLWITZ LAWRENCE D
CPC classification number: C07C2/864 , B01J29/04 , C07C2/865 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/70 , C07C15/24
Abstract: Novel catalysts and processes in accordance with the invention can accomplish high selectivity and conversion of naphthalenic compounds such as the conversion of methylnaphthalene (2-MN) or naphthalene to 2,6-dimethylnaphthalene (2,6-DMN). The catalysts are prepared by treating, for example, a ZSM-5-type material with iron in the presence of a halogen such as a fluoride. The resulting catalyst includes iron, as well as a significant portion of aluminium present in the ZSM-5-type starting material. Processes for using the catalysts also are disclosed.
Abstract translation: 根据本发明的新型催化剂和方法可以实现萘化合物的高选择性和转化率，例如将甲基萘（2-MN）或萘转化为2,6-二甲基萘（2,6-DMN）。 催化剂通过在诸如氟化物的卤素存在下用铁处理例如ZSM-5型材料来制备。 所得催化剂包括铁，以及存在于ZSM-5型起始原料中的大部分铝。 还公开了使用催化剂的方法。
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2.发明申请SYNTHESIS AND USE OF DIMETHYL-1,5-NAPHTHALENEDICARBOXYLATES AND INTERMEDIATES THEREFROM 审中-公开二甲基-1,5-萘二甲酸酯的合成和用途及其中间体
公开(公告)号：WO0151450A3
公开(公告)日：2003-07-10
申请号：PCT/US0101071
申请日：2001-01-12
Applicant: BP CORP NORTH AMERICA INC
Inventor： MACEK JOHN A , ROSEN BRUCE I , HOLZHAUER JUERGEN K , BRAMLET JOHN S , LILLWITZ LAWRENCE D , SCHNEIDER DAVID J , LANG LAWRENCE L , PASCHKE EDWARD E , WEIS JOHN M , VISWANATH YENAMANDRA , SAKELLARIDES STEFANOS L
IPC: C07B61/00 , C07C2/56 , C07C5/22 , C07C5/367 , C07C7/04 , C07C7/14 , C07C13/48 , C07C15/24 , C07C15/44 , C07C51/265 , C07C63/38 , C07C67/08 , C07C69/76 , C08G63/181 , C08G63/189 , C08G69/26
CPC classification number: C08G69/265 , C07C5/367 , C07C67/08 , C08G63/189 , C08G69/26 , C07C15/24 , C07C69/76
Abstract: The synthesis of dimethyl-1,5-naphthalenedicarboxylate and polymers and articles formed therefrom is disclosed, as well as applications for dimethyl-1,5-naphthalenedicarboxylate, its corresponding acid 1,5-NDA, and various synthesis intermediates.
Abstract translation: 公开了1,5-萘二甲酸二甲酯及其形成的聚合物和制品的合成，以及1,5-萘二羧酸二甲酯，其相应的酸1,5-萘二甲酸和各种合成中间体的应用。
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