公开(公告)号：WO2021202655A1

公开(公告)日：2021-10-07

申请号：PCT/US2021/025076

申请日：2021-03-31

申请人： CARBON, INC.

发明人： CARMEAN, R. Nicholas ,  MENYO, Matthew S.

IPC分类号： C08G18/32 ,  B33Y10/00 ,  C08G18/50 ,  C08G18/66 ,  C08G18/73 ,  C08G18/75 ,  C08L75/16 ,  B33Y40/20 ,  B33Y70/00 ,  B33Y80/00 ,  C08G18/3234 ,  C08G18/5024 ,  C08G18/6685 ,  C08G18/755

摘要： Provided herein according to some embodiments is a polymerizable liquid useful for the production of an energy absorbing three-dimensional object comprising polyurethane, polyurea, or a copolymer thereof by additive manufacturing. The polymerizable liquid may include components having soft segments (e.g., polyol/polyamine midblocks, chain extenders) of different number average molecular weights.

公开(公告)号：WO2020131675A1

公开(公告)日：2020-06-25

申请号：PCT/US2019/066479

申请日：2019-12-16

申请人： CARBON, INC.

发明人： MENYO, Matthew S. ,  CARMEAN, R. Nicholas ,  HEIST, Leah Marie ,  LI, Yongqiang ,  MACKAY, Nickolaus ,  GUTIERREZ, Clarissa

IPC分类号： B29C64/00 ,  C08G18/12 ,  C08G18/32 ,  C08G18/48 ,  C08G18/50 ,  C08G18/67 ,  C08G18/73 ,  C08G18/75

摘要： Provided herein according to some embodiments is a polymerizable liquid useful for the production of an energy absorbing three-dimensional object comprising polyurethane, polyurea, or a copolymer thereof by additive manufacturing. The polymerizable liquid may include components having soft segments ( e.g. , polyol/polyamine midblocks, chain extenders) of different number average molecular weights.

公开(公告)号：WO2020023823A1

公开(公告)日：2020-01-30

申请号：PCT/US2019/043573

申请日：2019-07-26

申请人： CARBON, INC.

发明人： POELMA, Justin ,  CARMEAN, R. Nicholas ,  MENYO, Matthew S.

IPC分类号： C08G18/75 ,  C08G18/79 ,  C08G18/48 ,  C08G18/67 ,  C08G18/10 ,  C08G18/12 ,  C08G18/32 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y80/00 ,  C08G18/72 ,  C08G18/81

摘要： Provided according to some embodiments is a polymerizable liquid useful for the production of a three-dimensional object comprised of polyurethane, polyurea, or a copolymer thereof by additive manufacturing, the polymerizable liquid comprising a mixture of: (a) a first blocked or reactive blocked prepolymer comprising a compound of the formula X(A) n , where X is a hydrocarbyl group, n is at least 3, and each A is an independently selected substituent of Formula I: (I) where R is a hydrocarbyl group, R' is O or NH, and Z is a blocking group; (b) a polyol and/or polyamine chain extender; (c) optionally a reactive diluent; and (d) a photoinitiator. A method of use of the polymerizable liquid to make a three-dimensional object by additive manufacturing and prepolymer compounds useful for the same are also provided.