公开(公告)号：WO2014009882A1

公开(公告)日：2014-01-16

申请号：PCT/IB2013/055634

申请日：2013-07-09

Applicant: COUNCIL OF SCIENTIFIC INDUSTRIAL RESEARCH

Inventor： GHOSE, Pushpito Kumar ,  CHAKRABORTY, Supratim ,  DINDA, Milan ,  MAITI, Subarna ,  BHATT, Chitrangi Bankimbhai ,  BHARADIA, Jitendra Narsinhbhai ,  PATEL, Pankaj Arvindbhai ,  BAPAT, Pratap Shashikant

IPC: B01J19/12 ,  C07C201/12 ,  C07B39/00 ,  C07D263/34 ,  C07C17/10 ,  C07C17/14 ,  F24J2/07

CPC classification number: B01J19/18 ,  B01J19/127 ,  B01J2219/00051 ,  C07B39/00 ,  C07C17/013 ,  C07C17/04 ,  C07C17/10 ,  C07C17/14 ,  C07C201/12 ,  C07C2601/18 ,  C07C2602/42 ,  C07D263/32 ,  F24S20/20 ,  H02S10/40 ,  H02S40/22 ,  Y02E10/41 ,  Y02E10/52 ,  C07C25/02 ,  C07C25/13 ,  C07C22/04 ,  C07C19/075 ,  C07C23/14 ,  C07C23/16 ,  C07C23/28 ,  C07C23/02 ,  C07C205/11

Abstract: The invention demonstrates a process for conducting organic reactions in a standalone laboratory scale solar photo thermo chemical reactor for conducting organic reactions requiring elevated temperature, light and mechanical agitation, where all three energy forms are simultaneously derived from solar radiation. Organic synthesis such as bromination of toluene derivatives (benzylic bromination), bromination of cyclic acyclic hydrocarbon and oxidative cyclization of N-phenylethyl benzamide through bromination were successfully conducted in such reactors.

Abstract translation: 本发明证实了在独立的实验室规模的太阳光热化学反应器中进行有机反应的方法，用于进行需要高温，轻和机械搅拌的有机反应，其中所有三种能量形式同时来自太阳辐射。 在这样的反应器中成功地进行了甲苯衍生物的溴化（苄基溴化），环状无环烃的溴化和溴化N-苯基苯甲酰胺的氧化环化等有机合成。