公开(公告)号：WO2015108874A1

公开(公告)日：2015-07-23

申请号：PCT/US2015/011233

申请日：2015-01-13

Applicant: ELEVANCE RENEWABLE SCIENCES, INC.

Inventor： HATEGAN, Georgeta ,  FIRTH, Bruce ,  NGANTUNG, Frederyk ,  ERHAN, Selim ,  PURANIK, Dhananjay ,  COBURN, Charles

IPC: C10G2/00 ,  C10L1/00

CPC classification number: C09K8/524 ,  C11D3/2093 ,  C11D3/43 ,  C11D7/5022

Abstract: Compositions for treating high-molecular-weight components of a petroleum fluid are generally disclosed. In some embodiments, such compositions include olefinic ester compounds, such as alkyl esters of C 10-18 unsaturated fatty acids. In some embodiments, such compositions are added to a petroleum fluid to improve the rheological properties, e.g., breaking up or inhibiting the precipitation of high-molecular-weight components of petroleum fluids. In some other embodiments, such compositions are used for removing deposits of such high-molecular-weight components from the surfaces of equipment used for extracting or transporting petroleum or natural gas.

Abstract translation: 通常公开了用于处理石油流体的高分子量组分的组合物。 在一些实施方案中，这种组合物包括烯属酯化合物，例如C 10-18不饱和脂肪酸的烷基酯。 在一些实施方案中，将这种组合物加入到石油流体中以改善流变性能，例如破坏或抑制石油流体的高分子量组分的沉淀。 在一些其他实施方案中，这种组合物用于从用于提取或运输石油或天然气的设备的表面去除这些高分子量组分的沉积物。

公开(公告)号：WO2014058872A1

公开(公告)日：2014-04-17

申请号：PCT/US2013/063870

申请日：2013-10-08

Applicant: ELEVANCE RENEWABLE SCIENCES, INC.

Inventor： FIRTH, Bruce ,  PEASE, Brian, M. ,  ILSEMAN, Alexander, D. ,  ZOPP, Garrett ,  MURPHY, Timothy, A. ,  WEITKAMP, Robin ,  MORIE-BEBEL, Michelle

IPC: C10G45/00 ,  C07C67/333 ,  C07C67/343 ,  C07C69/533 ,  C10G3/00

CPC classification number: C07C67/343 ,  C10G3/44 ,  C10G45/00 ,  C11C3/00 ,  C11C3/003 ,  C11C3/14 ,  Y02E50/13 ,  Y02P30/20 ,  C07C69/533

Abstract: Methods and compositions are provided for refining natural oils and for producing high-weight esters, high-weight acids, and/or high-weight derivatives thereof, wherein the compositions are made by cross-metathesizing low-weight unsaturated esters or low-weight unsaturated acids having hydrocarbon chain lengths less than or equal to C24 with an olefin feedstock, thereby forming a metathesized product composition comprising high-weight esters or high-weight acids having hydrocarbon chain lengths greater than C18, wherein at least a portion of the hydrocarbon chain lengths in the metathesized product are larger than the hydrocarbon chain lengths in the starting feedstock. In certain embodiments, the low-weight unsaturated esters or low-weight unsaturated acids are derived by reacting a natural oil feedstock in a metathesis reactor in the presence of a metathesis catalyst to form a metathesized product composition comprising olefins and low-weight unsaturated esters, and then separating the olefins from the low-weight unsaturated esters. In some embodiments, the low-weight unsaturated ester compositions may be hydrolyzed to form the low-weight unsaturated acid compositions.

Abstract translation: 提供用于精制天然油和生产高重量酯，高重量酸和/或其高重量衍生物的方法和组合物，其中组合物通过将低重量不饱和酯或低重量不饱和度 具有烃链长度小于或等于C24的酸与烯烃原料反应，从而形成包含烃链长度大于C18的高重量酯或高重量酸的复分解产物组合物，其中烃链长度的至少一部分 在复分解产物中大于起始原料中的烃链长度。 在某些实施方案中，所述低重量不饱和酯或低重量不饱和酸是通过使复分解反应器中的天然油原料在复分解催化剂存在下反应形成包含烯烃和低重量不饱和酯的复分解产物组合而衍生的， 然后从低重量不饱和酯中分离烯烃。 在一些实施方案中，低重量不饱和酯组合物可以被水解以形成低重量不饱和酸组合物。

公开(公告)号：WO2015116442A1

公开(公告)日：2015-08-06

申请号：PCT/US2015/012148

申请日：2015-01-21

Applicant: ELEVANCE RENEWABLE SCIENCES, INC.

Inventor： KIRK, Sharon ,  PEASE, Brian ,  FIRTH, Bruce ,  DREYER, Bradon

IPC: C02F1/72

CPC classification number: C02F1/725 ,  B01J31/2265 ,  B01J31/4015 ,  B01J2231/54 ,  B01J2531/821 ,  C02F1/66 ,  C02F1/72 ,  C02F1/722 ,  C02F2101/105 ,  C02F2101/30 ,  C02F2101/34 ,  C02F2103/36 ,  C02F2305/02 ,  C07F9/5004 ,  C07F9/5304 ,  C07F9/5407 ,  C10G45/58 ,  C10G50/00 ,  C10G2300/705

Abstract: Methods and systems for treating an aqueous effluent from a metathesis reactor, such as a metathesis-based biorefinery, are generally disclosed. In some embodiments, the aqueous effluent is generated from washing the metathesized product with an aqueous medium. In some embodiments, such wash streams are chemically treated to reduce their toxicity and to facilitate disposal. In some embodiments, such wash streams are treated to recover at least a portion of the catalyst residue, so as to facilitate catalyst recovery.

Abstract translation: 通常公开了用于处理复分解反应器（例如基于复分解的生物炼制）的含水流出物的方法和系统。 在一些实施方案中，水性流出物是通过用水性介质洗涤复分解产物而产生的。 在一些实施方案中，这种洗涤流被化学处理以降低其毒性并便于处理。 在一些实施方案中，处理这种洗涤流以回收至少一部分催化剂残余物，以促进催化剂回收。

公开(公告)号：WO2015108872A1

公开(公告)日：2015-07-23

申请号：PCT/US2015/011224

申请日：2015-01-13

Applicant: ELEVANCE RENEWABLE SCIENCES, INC.

Inventor： LITTICH, Ryan ,  HATEGAN, Georgeta ,  FIRTH, Bruce ,  PURANIK, Dhananjay ,  BLOCK, Steven ,  CORR, Andrew ,  ZOPP, Garrett ,  ILSEMAN, Alexander

IPC: C11D7/50

CPC classification number: C09K8/524 ,  C11D3/2093 ,  C11D3/43 ,  C11D7/5022

Abstract: Compositions including olefinic ester compounds are generally disclosed. In some embodiments, such compositions are cleaning compositions, and can be used to clean various surfaces (e.g., hard surfaces, etc.) and/or materials (e.g., textiles, fibers, etc.). In some embodiments, the olefinic ester compounds are derived from a natural oil or a natural oil derivative, for example, by catalytic olefin metathesis.

Abstract translation: 通常公开了包含烯属酯化合物的组合物。 在一些实施方案中，这样的组合物是清洁组合物，并且可以用于清洁各种表面（例如硬表面等）和/或材料（例如纺织品，纤维等）。 在一些实施方案中，烯烃酯化合物衍生自天然油或天然油衍生物，例如通过催化烯烃复分解。

公开(公告)号：WO2014153406A1

公开(公告)日：2014-09-25

申请号：PCT/US2014/031219

申请日：2014-03-19

Applicant: ELEVANCE RENEWABLE SCIENCES, INC.

Inventor： FIRTH, Bruce ,  HATEGAN, Georgeta ,  DIBIASE, Stephen, A. ,  LITTICH, Ryan ,  WEITKAMP, Robin ,  COHEN, Steven, A.

IPC: C07C67/347 ,  C07C69/593 ,  C07C69/602 ,  C07C69/604 ,  C07C69/608 ,  C07C51/353 ,  C07C57/13 ,  C07C57/26

CPC classification number: C07C69/608 ,  C07C51/353 ,  C07C57/02 ,  C07C57/13 ,  C07C57/26 ,  C07C67/347 ,  C07C69/593 ,  C07C69/602 ,  C07C69/604 ,  C11C3/08

Abstract: The oligomerization of certain carboxylic acids and alkyl esters derived from natural oils is disclosed. This includes the oligomerization of C 10-17 unsaturated carboxylic acids such as 9-decenoic acid, where the oligomerization yields a mixture of mono-, di- and tri-carboxylic acids. This also includes the oligomerization of certain alkyl esters, including the oligomerization of C 10-17 unsaturated alkyl esters such as methyl 9-decenoate (9-DAME), where the oligomerization yields a mixture of mono-, di- and tri-carboxylic acid esters. Various end use applications for the oligomerized carboxylic acids and oligomerized alkyl esters are also disclosed.

Abstract translation: 公开了某些衍生自天然油的羧酸和烷基酯的低聚。 这包括C10-17不饱和羧酸如9-癸烯酸的低聚，其中低聚产生单 - ，二 - 和三 - 羧酸的混合物。 这还包括某些烷基酯的低聚，包括C 10-17不饱和烷基酯如9-癸烯酸甲酯（9-DAME）的低聚，其中低聚产生单 - ，二 - 和三 - 羧酸酯的混合物 。 还公开了低聚羧酸和低聚烷基酯的各种最终应用。