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公开(公告)号：WO2018182982A3
公开(公告)日：2018-10-04
申请号：PCT/US2018/022534
申请日：2018-03-15
IPC分类号： C08F110/14 , C08F4/6592 , C08F8/04
摘要： Unsaturated and hydrogenated polyalpha-olefin products can be made with a high selectivity toward vinylidenes and tri-substituted vinylenes combined, a high selectivity toward vinylidenes, and a low selectivity toward 1,2-di-substituted vinylenes by using a catalyst system comprising a metallocene compound having the following structure in the polymerization reaction: In formula (F-MC), Rl and R4 are each independently a hydrogen or a C1-C30 hydrocarbyl group, R2 and R3 are each independently a C1-C50 hydrocarbyl group, R5, R6, R7 and R8 are each independently a hydrogen or a C1-C30 hydrocarbyl group, provided that R6 and R7 are not both hydrogen. The first Cp ring and the second Cp ring may be annelated but not simultaneously.
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2.发明申请
公开(公告)号：WO2020264154A1
公开(公告)日：2020-12-30
申请号：PCT/US2020/039608
申请日：2020-06-25
发明人： KRAMER, Anatoly I. , WEBER, Jorg F.W. , RAPP, Jennifer L. , LEWIS, Kyle G. , CHEN, Patrick C. , ENGHETA Behrouz , BRAUN, Heinrich R. , LOTFIZADEHDEHKORDI, Babak
摘要： Methyl paraffins formed by hydrogenating one or more LAO dimers comprising a vinylidene moiety or a trisubstituted olefin moiety may have advantageous heat transfer properties, particularly when incorporated within an electric vehicle. For example, methyl paraffins produced upon hydrogenating LAO dimers formed from one or more C6-C12 LAOs, particularly in the presence of a Hf metallocene catalyst system, may contain 12-24 carbon atoms, and collectively have a flash point of about 130°C or above, a pour point of about -42°C or lower, a thermal conductivity at 80°C of about 0.165W/m·K or higher, and a Mouromtseff number ranging from about 17,000 to about 27,000 kg/(s2.2 ·m0.6·K) at 80°C. Heat transfer fluids comprising such methyl paraffins may be placed in contact with a heat-generating component, such as a battery and/or motor of an electric vehicle, or within a similar type of battery system, including immersive configurations for a battery.
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公开(公告)号：WO2018182982A2
公开(公告)日：2018-10-04
申请号：PCT/US2018/022534
申请日：2018-03-15
IPC分类号： C08F110/14
CPC分类号： C08F110/14 , B01J31/1608 , B01J31/2243 , B01J31/2295 , B01J2231/122 , B01J2231/20 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F8/04 , C08F4/65927
摘要： Unsaturated and hydrogenated polyalpha-olefin products can be made with a high selectivity toward vinylidenes and tri-substituted vinylenes combined, a high selectivity toward vinylidenes, and a low selectivity toward 1,2-di-substituted vinylenes by using a catalyst system comprising a metallocene compound having the structure (F-MC) in the polymerization reaction.
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公开(公告)号：WO2021029939A1
公开(公告)日：2021-02-18
申请号：PCT/US2020/035812
申请日：2020-06-03
摘要： The present disclosure provides processes and apparatus for producing poly alpha olefins. In at least one embodiment, a process to produce a poly alpha olefin includes introducing a first olefin monomer to a first catalyst and an activator in a first reactor to form a first reactor effluent comprising olefin dimers and olefin timers. The process includes heating the first reactor effluent to form an isomerized product and introducing the isomerized product to a filtration unit to form a filtration effluent. The process may include introducing the filtration effluent to a first distillation unit to form a first distillation effluent. The process may include introducing the first distillation effluent to a second distillation unit to form a second distillation effluent. The process includes introducing the first distillation effluent and/or the second distillation effluent to a second catalyst in a second reactor to form a second reactor effluent comprising the olefin timers.
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