公开(公告)号：WO2007067890A2

公开(公告)日：2007-06-14

申请号：PCT/US2006/061602

申请日：2006-12-05

申请人： MONOSOL, LLC ,  RATH, Christian ,  VERRALL, Andrew, P.

发明人： RATH, Christian ,  VERRALL, Andrew, P.

IPC分类号： C09K3/22 ,  C09K17/20

CPC分类号： C09K3/22 ,  C09K17/20

摘要： A method of dust abatement, including applying and reapplying to a surface having particulate material a single-phase solution including a water-soluble polymer selected from the group consisting of polyvinyl alcohol, derivatives thereof, and combinations thereof, at a rate of 0.1 g/m to 6 g/m 2 , on a dry basis, and suitable solutions for the method optionally including surfactants, plasticizers, tackifying agents, and nanoclays, are disclosed.

摘要翻译： 一种粉尘消除方法，包括将具有选自聚乙烯醇，其衍生物及其组合的水溶性聚合物的单相溶液和其组合的单相溶液施用并重新施用于具有颗粒材料的表面，速率为0.1g / 公开了以干燥为基础的m至6g / m 2，以及适用于任选包括表面活性剂，增塑剂，增粘剂和纳米粘土的方法的合适溶液。

公开(公告)号：WO2007027224A3

公开(公告)日：2007-03-08

申请号：PCT/US2006/016023

申请日：2006-04-26

申请人： MONOSOL, LLC ,  VERRALL, Andrew, P.

发明人： VERRALL, Andrew, P.

IPC分类号： C08J5/18 ,  C08J5/00 ,  C08K3/36 ,  C08L29/04

摘要： A plasticized water-soluble composition and structure (e.g., film) including a water-soluble polymer, a hydrophilic nanoscale particulate, a plasticizer, and, optionally, one or more auxiliary agents such as a crosslinking agent for the polymer, plasticizers, surfactants, extenders, and release agents, is disclosed. Also disclosed are containers made from such compositions and films, and methods of making and using such items.

公开(公告)号：WO2004089593A2

公开(公告)日：2004-10-21

申请号：PCT/US2004/010335

申请日：2004-04-02

申请人： MONOSOL, LLC ,  SZOPINSKI, Alex ,  VERRALL, Andrew, P. ,  STULL, Terry ,  SZUMLANSKI, Andrew ,  STEELE, John ,  SCHEST, Larry ,  SHIMKUS, William ,  KNOOP, Henry, E.

发明人： SZOPINSKI, Alex ,  VERRALL, Andrew, P. ,  STULL, Terry ,  SZUMLANSKI, Andrew ,  STEELE, John ,  SCHEST, Larry ,  SHIMKUS, William ,  KNOOP, Henry, E.

IPC分类号： B29C41/28

CPC分类号： B29C41/28 ,  B29C41/34

摘要： A solvent band casting system is disclosed which contains a tank for mixing and/or storing a polymer solution for a band casting machine having at least a first and a second rotating drums about which a continuous metal band is tensioned to travel with the rotation of the drums. A sheeting die applies the polymer solution from the tank to the metal band where a drying chamber, enclosing a least a portion of the metal band downline of the sheeting die, is used to remove solvent from the polymer solution as it travels in a thin sheet on the metal band. A surfactant applicator in communication with a supply of surfactant and a portion of the metal band is disclosed. In addition, the use of a surfactant to substantially reduce or eliminate bubbles in the polymer film product is disclosed, as well as the mechanisms by which the surfactant is believed to facilitate bubble reduction. Finally, a system controller can be connected to monitor and/or control at least one component of the system.

摘要翻译： 公开了一种溶剂带浇注系统，其包含用于混合和/或储存用于带式铸造机的聚合物溶液的罐，该罐具有至少第一和第二旋转滚筒，连续的金属带被拉紧在该第一和第二旋转滚筒上， 鼓。 片材模具将聚合物溶液从罐中施加到金属带，其中包围片材模头的金属带下线的至少一部分的干燥室用于在聚合物溶液沿薄片移动时从聚合物溶液中除去溶剂 在金属带上。 公开了一种与表面活性剂供应和金属带的一部分连通的表面活性剂施加器。 此外，公开了使用表面活性剂来显着降低或消除聚合物膜产品中的气泡，以及认为表面活性剂促进气泡还原的机理。 最后，可以连接系统控制器以监视和/或控制系统的至少一个组件。

公开(公告)号：WO2007130817A1

公开(公告)日：2007-11-15

申请号：PCT/US2007/067311

申请日：2007-04-24

申请人： MONOSOL, LLC ,  VERRALL, Andrew, P. ,  GOODRICH, Stephen, D.

发明人： VERRALL, Andrew, P. ,  GOODRICH, Stephen, D.

IPC分类号： C08K5/00 ,  C08K5/138 ,  C08K5/5317 ,  C08L29/04 ,  C02F1/76

CPC分类号： A61K9/7015 ,  A61K47/10 ,  C08K5/0008 ,  C08K5/13 ,  C08K5/5317 ,  C08L29/04 ,  C08L71/02 ,  Y10T428/31855 ,  Y10T442/2525 ,  C08L2666/02

摘要： A water-soluble, halogen-resistant film-forming composition useful for packaging water treatment products is disclosed. The film can include an acid-stable, water-soluble polyvinyl alcohol polymer, an oxidizable organic material, a chelating agent, a free radical scavenger, and secondary additives such as plasticizers, lubricants, and surfactants. The resulting film has favorable solubility properties after having been exposed to halogenated (e.g., chlorinated and brominated) compositions such as water treatment and agricultural products for prolonged periods of time.

摘要翻译： 公开了一种用于包装水处理产品的水溶性，耐卤素成膜组合物。 该膜可以包括酸稳定的水溶性聚乙烯醇聚合物，可氧化有机材料，螯合剂，自由基清除剂和辅助添加剂如增塑剂，润滑剂和表面活性剂。 在经过卤化（例如氯化和溴化）组合物如水处理和农产品长时间暴露后，所得膜具有良好的溶解性能。

公开(公告)号：WO2007112154A1

公开(公告)日：2007-10-04

申请号：PCT/US2007/061343

申请日：2007-01-31

申请人： MONOSOL, LLC ,  VERRALL, Andrew, P. ,  GOODRICH, Stephen, D. ,  BROWN, Solomon, E.

发明人： VERRALL, Andrew, P. ,  GOODRICH, Stephen, D. ,  BROWN, Solomon, E.

IPC分类号： A23L1/22 ,  C09D101/28 ,  C08K5/00

CPC分类号： C08L1/284 ,  A23L27/79 ,  C08J5/18 ,  C08J2300/16 ,  C08K5/0008 ,  C08L1/28 ,  C08L3/04 ,  C08L59/02 ,  C08L2666/14 ,  C08L2666/26

摘要： An edible film useful for packaging food additives is disclosed. The film generally includes an edible film-forming resin, a plasticizer, a compatibilizer, and optional secondary additives. The resulting edible film has favorable heat seal properties, being able to form an acceptable heat seal over temperature ranges of at least about 10°C.

摘要翻译： 公开了一种可用于包装食品添加剂的可食用膜。 膜通常包括可食用的成膜树脂，增塑剂，增容剂和任选的二级添加剂。 所得的可食用膜具有良好的热封性能，能够在至少约10℃的温度范围内形成可接受的热封。

公开(公告)号：WO2004074351A3

公开(公告)日：2004-09-02

申请号：PCT/US2004/004048

申请日：2004-02-12

申请人： MONOSOL, LLC ,  VERRALL, Andrew, P. ,  BENING, Scott, P. ,  KUGLER, Karen, A.

发明人： VERRALL, Andrew, P. ,  BENING, Scott, P. ,  KUGLER, Karen, A.

IPC分类号： C08J5/18

摘要： A water-soluble film for packaging a non-liquid product, a package employing the film, and methods of making the same, are disclosed. The film is made from a hydrolyzed copolymer of vinyl acetate and methyl acrylate in a range of from about 30 to about 95 percent by weight, modified starch in a range of from about 4 to about 30 percent by weight, plasticizer in a range of from about 5 to about 30 percent by weight, lubricant/release agent in a range of from about 0.0 to about 1.5 percent by weight, and surfactant in a range of from about 0.01 to about 1.5 percent by weight.

公开(公告)号：WO2008064014A2

公开(公告)日：2008-05-29

申请号：PCT/US2007/084566

申请日：2007-11-13

申请人： MONOSOL, LLC ,  VERRALL, Andrew, P. ,  BROWN, Solomon, E. ,  BECKHOLT, Dennis, Allen

发明人： VERRALL, Andrew, P. ,  BROWN, Solomon, E. ,  BECKHOLT, Dennis, Allen

IPC分类号： C08J5/18 ,  C08L29/04 ,  C11D17/04 ,  C08L5/08 ,  C08K3/30

CPC分类号： C08J5/18 ,  C08J2329/04 ,  C08K3/30 ,  C08L5/08 ,  C08L29/04 ,  C11D17/042 ,  C08L2666/26

摘要： A film-forming composition made from a mixture of PVOH, chitosan, an alkali metal or ammonium bisulfite or metabi sulfite, and optional ingredients such as plasticizers, antioxidants, UV stabilizers, surfactants, crosslinking agents, lubricants, and extenders, is disclosed. Also disclosed are a method of making a film from the composition, a resulting film, and a packet made from the film and containing a cleaning composition such as a rinse additive. The composition can be formulated to yield an article such as a film which is soluble only below a predetermined pH threshold.

摘要翻译： 由PVOH，脱乙酰壳多糖，碱金属或亚硫酸氢铵或偏亚硫酸盐的混合物制成的成膜组合物，以及任选的成分如增塑剂，抗氧化剂，UV稳定剂，表面活性剂，交联剂，润滑剂 ，和扩展，被披露。 还公开了由该组合物制备薄膜的方法，所得薄膜以及由该薄膜制成并且包含清洁组合物如冲洗添加剂的包装袋。 该组合物可以配制成产品，例如仅在预定的pH阈值以下可溶的膜。

公开(公告)号：WO2007047231A1

公开(公告)日：2007-04-26

申请号：PCT/US2006/039470

申请日：2006-10-11

申请人： MONOSOL, LLC ,  ROYLE, Timothy, J. ,  SZOPINSKI, Alex ,  VERRALL, Andrew, P.

发明人： ROYLE, Timothy, J. ,  SZOPINSKI, Alex ,  VERRALL, Andrew, P.

IPC分类号： B29D7/01 ,  B32B27/26 ,  C08J5/18 ,  C08J3/24

CPC分类号： C08J5/18 ,  B29C39/14 ,  B29K2029/04 ,  C08J3/215 ,  C08J3/24 ,  C08J2329/04

摘要： A method and system for continuously preparing a crosslinked, solvent-cast film are disclosed. The method includes continuously providing a pressurized stream of polymer solution, continuously combining a fluid stream including a crosslinking agent with the pressurized stream of polymer solution, mixing the combination of polymer solution and fluid stream in-line, continuously applying the resulting mixture to a continuously moving surface, and then evaporating solvent from the mixture to form a polymeric film. The system includes: (i) a continuous polymer solution casting system, including a first pump in fluid communication with a supply of polymer solution, a casting die for continuously depositing polymer solution disposed in proximity to a moving casting surface, and a first conduit providing a flow path for the polymer solution from the pump to the casting die; (ii) a secondary liquid component injection system, including a second reservoir for holding a supply of a secondary liquid component including a crosslinking agent, a variable-speed second pump in fluid communication with the supply of secondary liquid component, a needle valve, and a second conduit providing a flow path for the secondary liquid component from the reservoir, through the second pump, then through the needle valve, and to an outlet; (iii) a conduit junction connecting the outlet of the secondary liquid component injection system to the first conduit of the continuous polymer solution casting system, the junction disposed downstream of the first pump; and (iv) an in-line mixer disposed between the casting die and the conduit junction.

摘要翻译： 公开了一种用于连续制备交联的溶剂浇铸膜的方法和系统。 该方法包括连续地提供聚合物溶液的加压流，将包含交联剂的流体流与加压的聚合物溶液流连续地混合，将聚合物溶液和流体流的组合在线混合，将所得混合物连续地连续地连续 移动表面，然后从混合物蒸发溶剂以形成聚合物膜。 该系统包括：（i）连续聚合物溶液流延系统，包括与聚合物溶液供应流体连通的第一泵，用于连续沉积设置在活动铸件表面附近的聚合物溶液的铸模，以及提供 用于从泵到铸模的聚合物溶液的流动路径; （ii）第二液体成分注入系统，包括用于保持包括交联剂的二次液体组分的供应的第二储存器，与辅助液体组分的供给流体连通的可变速的第二泵，针阀和 第二管道，其通过第二泵提供来自储存器的二次液体部件的流动路径，然后通过针阀和出口; （iii）连接第二液体部件喷射系统的出口到连续聚合物溶液流延系统的第一管道的导管接头，该连接处设置在第一泵的下游; 和（iv）设置在铸模和导管结之间的在线混合器。

公开(公告)号：WO2011094472A1

公开(公告)日：2011-08-04

申请号：PCT/US2011/022828

申请日：2011-01-28

申请人： MONOSOL, LLC ,  DENOME, Frank, William ,  FRIEDRICH, Steven, G. ,  LABEQUE, Regine ,  LEE, David, M. ,  ROSMANIHO, Roxane ,  SHI, Jichun ,  VERRALL, Andrew, P.

发明人： DENOME, Frank, William ,  FRIEDRICH, Steven, G. ,  LABEQUE, Regine ,  LEE, David, M. ,  ROSMANIHO, Roxane ,  SHI, Jichun ,  VERRALL, Andrew, P.

IPC分类号： C08F16/06 ,  C08F116/06 ,  C08F216/06

CPC分类号： C08L29/04 ,  B65D65/46 ,  C08J5/18 ,  C08J2329/04 ,  C08L2203/16 ,  C08L2205/025 ,  C11D17/042 ,  C11D17/045 ,  Y10T428/1334 ,  Y10T428/1341 ,  Y10T428/1345

摘要： Disclosed is a pouch having at least one sealed compartment containing a first composition. At least one wall of the at least one sealed compartment is made from a water- soluble film having any suitable thickness. The water-soluble film comprises PVOH polymer such that when the film has a thickness of about 76 microns the film is characterized by a Dissolution Index of about 620 to about 920, or of about 665 to about 920, or about 710 to about 920; and a Stress Index of about 145 to about 626, or about 155 to about 480, or about 165 to about 325.

摘要翻译： 公开了一种具有至少一个包含第一组合物的密封隔室的袋。 至少一个密封隔室的至少一个壁由具有任何合适厚度的水溶性膜制成。 该水溶性膜包含PVOH聚合物，使得当该膜的厚度为约76微米时，该膜的特征在于溶解指数为约620至约920，或约665至约920，或约710至约920; 和约145至约626，或约155至约480，或约165至约325的应力指数。

公开(公告)号：WO2011094470A1

公开(公告)日：2011-08-04

申请号：PCT/US2011/022825

申请日：2011-01-28

申请人： MONOSOL, LLC ,  DENOME, Frank, William ,  FRIEDRICH, Steven, G. ,  LABEQUE, Regine ,  LEE, David, M. ,  ROSMANIHO, Roxane ,  SHI, Jichun ,  VERRALL, Andrew, P.

发明人： DENOME, Frank, William ,  FRIEDRICH, Steven, G. ,  LABEQUE, Regine ,  LEE, David, M. ,  ROSMANIHO, Roxane ,  SHI, Jichun ,  VERRALL, Andrew, P.

IPC分类号： C08F16/06 ,  C08F116/06 ,  C08F216/06

CPC分类号： C08L29/04 ,  B65D65/46 ,  C08J5/18 ,  C08J2329/04 ,  C08L2203/16 ,  C08L2205/025 ,  C11D17/042 ,  C11D17/045 ,  Y10T428/1334 ,  Y10T428/1341 ,  Y10T428/1345

摘要： Disclosed are plasticized, water-soluble films having favorable cold-water solubility, wet handling, and thermoforming characteristics, and which can include a PVOH resin made up of blend of two or more PVOH polymers each having a monomodal molecular weight distribution, and the PVOH resin characterized by a viscosity in a range of about 13.5 cP to about 20 cP (or a corresponding weight average molecular weight), a degree of hydrolysis of about 84% to about 92%, a polydispersity index value in a range of about 1 to about 5, a residual water content of about 4 wt.% to about 10 wt.%, and a Resin Selection Index value in a range of 0.255 to 0.315; methods of making the films; compositions including PVOH resins for making the films; and pouch and packet articles made from the films.

摘要翻译： 公开了具有良好的冷水溶解度，湿处理和热成型特性的塑化水溶性膜，并且其可包括由两种或更多种PVOH聚合物的共混物构成的PVOH树脂，所述PVOH聚合物各自具有 单峰分子量分布，并且所述PVOH树脂的特征在于粘度范围为约13.5cP至约20cP（或相应的重均分子量），水解度为约84％至约92％，多分散指数 在约1至约5范围内的值，约4重量％至约10重量％的残余水含量和在0.255至0.315范围内的树脂选择指数值; 制作电影的方法; 包含用于制造该膜的PVOH树脂的组合物; 以及由这些电影制成的小袋和小包物品。