公开(公告)号：WO2017131972A1

公开(公告)日：2017-08-03

申请号：PCT/US2017/013433

申请日：2017-01-13

Applicant: OXYTEC LLC

Inventor： BALL, Raymond G. ,  MOORE, Alan T.

IPC: B09C1/08 ,  C02F1/72 ,  C02F1/78

CPC classification number: B09C1/08 ,  C02F1/02 ,  C02F1/04 ,  C02F1/26 ,  C02F1/28 ,  C02F1/72 ,  C02F1/722 ,  C02F1/78 ,  C02F2101/305 ,  C02F2101/32 ,  C02F2101/322 ,  C02F2101/327 ,  C02F2101/36 ,  C02F2101/363 ,  C02F2101/366 ,  C02F2303/26

Abstract: Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

Abstract translation: 公开了使用试剂组合修复污染土壤，地下水，水和/或废物的方法，设备和系统。 所公开的方法可以用于处理各种顽固性卤化物质，例如全氟烷基和多氟烷基。 可以在所公开的方法中使用的试剂的特定组合包括但不限于：（1）过硫酸盐，氧气和臭氧; （2）过硫酸盐，盐，氧和臭氧; （3）过硫酸盐，磷酸盐和/或氧气; （4）过硫酸盐，磷酸盐，氧气和臭氧; （5）过硫酸盐，磷酸盐，盐和氧（6）过硫酸盐，磷酸盐，盐，氧和臭氧; （7）氧和盐; 和（8）空气和盐。 所公开的方法可以增强液相中有机污染物的破坏，并且还可以相对于化学氧化和/或还原/转移的速率来控制气溶胶或泡沫形成的速率。