公开(公告)号：WO2021242485A1

公开(公告)日：2021-12-02

申请号：PCT/US2021/030661

申请日：2021-05-04

Applicant: PALO ALTO RESEARCH CENTER INCORPORATED

Inventor： CHINTAPALLI, Mahati ,  MECKLER, Stephen ,  IFTIME, Gabriel ,  PANDEY, Rahul ,  LOUIE, Mary ,  BEH, Eugene Shin Ming

IPC: B01J13/00 ,  B01J20/26 ,  B01J20/28

Abstract: A porous polymer aerogel, wherein the aerogel has greater than 5 wt% of amine containing vinyl monomers integrated into a polymer backbone. A method of fabrication of a porous polymer aerogel amine material, includes preparing a solution comprising at least a solvent, amine monomers having protected amino groups, one or more crosslinkers, one or more radical initiators, and a nitroxide mediator, removing oxygen from the solution, heating the solution to promote polymerization and to produce a polymerized material, performing solvent exchange with the polymerized material, causing a deprotection reaction in the polymerized material to remove groups protecting the amino groups, soaking and rinsing the material to remove excess reagents and any byproducts of the deprotection reaction, and drying the material to produce the amine sorbent. A system to separate CO2 from other gases, comprising a polymer porous aerogel sorbent having greater than 5 wt% of amine containing vinyl monomers integrated into a polymer backbone.

公开(公告)号：WO2019126631A1

公开(公告)日：2019-06-27

申请号：PCT/US2018/067066

申请日：2018-12-21

Applicant: PALO ALTO RESEARCH CENTER INCORPORATED

Inventor： IFTIME, Gabriel ,  KIM, Beomseok ,  SMITH, Clinton ,  COCKER, Eric ,  WEI, Junhua ,  SCHWARTZ, David Eric ,  MEYYAPPAN, Meyya ,  PANDEY, Rahul ,  ZHANG, Yong

IPC: C01B32/176 ,  C01B32/168 ,  G01N27/12

CPC classification number: C01B32/168 ,  C01B32/176 ,  G01N27/12 ,  G01N33/0036

Abstract: Disclosed are methods and systems of providing carbon nanotubes decorated with polymer coated metal nanoparticles. Then, annealing the metal coated carbon nanotubes to reduce a quantity of hydrophilic components of the polymer coating.