公开(公告)号：WO2013096827A1

公开(公告)日：2013-06-27

申请号：PCT/US2012/071350

申请日：2012-12-21

Applicant: PELLION TECHNOLOGIES INC.

Inventor： DOE, Robert, Ellis ,  HAN, Ruoban ,  GOFER, Yossef ,  AURBACH, Doron ,  POUR, Nir ,  STERENBERG, Evgeny

IPC: H01M6/14 ,  H01M4/46 ,  H01M8/10 ,  H01M10/054

CPC classification number: C25D3/66 ,  C25D3/42 ,  C25D3/665 ,  H01M4/466 ,  H01M10/054 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025

Abstract: A non-aqueous Magnesium electrolyte comprising: (a) at feast one organic solvent; (b) at least one electrolytically active, soluble, inorganic Magnesium (Mg) salt complex represented by the formula: Mg a Z b -X c wherein a, b, and c are selected to maintain neutral charge of the molecule, and Z and X are selected such that Z and X form a Lewis Acid, and 1 ≤ a ≤ 10, 1 ≤ b ≤ 5, and 2 ≤ c ≤ 30. Further Z is selected from a group consisting of aluminum, boron, phosphorus, titanium, iron, and antimony; X is selected from the group consisting of I, Br, Cl, F and mixtures thereof. Rechargeable, high energy density Magnesium cells containing an cathode, an Mg metal anode, and an electrolyte of the above-described type are also disclosed.

Abstract translation: 一种非水性镁电解质，包括：（a）盛装一种有机溶剂; （b）至少一种电解活性的，可溶解的无机镁（Mg）盐络合物，其由下式表示：Mg a Z b -X c其中a，b和c被选择以保持分子的中性电荷，Z和 X选择为使得Z和X形成路易斯酸，并且1 <= a <= 10,1 <= b <= 5和2 <= c <30。另外Z选自铝， 硼，磷，钛，铁和锑; X选自I，Br，Cl，F及其混合物。 可充电的高能量密度还公开了含有阴极，Mg金属阳极和上述类型的电解质的镁电池。