公开(公告)号：WO2014107725A1

公开(公告)日：2014-07-10

申请号：PCT/US2014010497

申请日：2014-01-07

Applicant: TORAY INDUSTRIES ,  HUGHES JOHNATHAN C ,  SAKATA HIROAKI

Inventor： HUGHES JOHNATHAN C ,  SAKATA HIROAKI

IPC: C08J5/24

CPC classification number: C08G59/1477 ,  C08G59/3227 ,  C08G59/38 ,  C08G59/4021 ,  C08G59/686 ,  C08J5/24 ,  C08J2363/00 ,  C08K3/04 ,  C08K7/02 ,  C08L63/00

Abstract: An embodiment relates to a resin composition containing a tetraglycidyl amine; a bisphenol epoxy; a dicyandiamide; and an aromatic urea; wherein the tetraglycidyl amine has a EEW of 110 g/eq to 140 g/eq and is an amount of 30 to 60 PHR per 100 PHR of total epoxy resin in the resin composition; wherein the resin composition has a Tg of at least 160°C when cured at 143°C for 3 min and also maintains a Tg of greater than 160°C when cured at 177C for 1 min or longer.

Abstract translation: 一个实施方案涉及含有四缩水甘油胺的树脂组合物; 双酚环氧树脂; 双氰胺 和芳香族脲; 其中所述四缩水甘油胺的EEW为110g / eq至140g / eq，并且在树脂组合物中的总环氧树脂的总PHR为30至60PHR / 100PHR; 其中当在143℃固化3分钟时，该树脂组合物具有至少160℃的Tg，并且当在177℃下固化1分钟或更长时，其Tg保持在160℃以上。

公开(公告)号：WO2014004900A3

公开(公告)日：2014-04-03

申请号：PCT/US2013048305

申请日：2013-06-27

Applicant: TORAY INDUSTRIES

Inventor： ARAI ATSUHITO ,  SATTERWHITE JEFFREY A ,  HUGHES JOHNATHAN C ,  SAKATA HIROAKI ,  YOSHIOKA KENICHI

IPC: C08L79/04

CPC classification number: C08L79/04 ,  C08G73/0233 ,  C08J5/24 ,  C08J2377/00 ,  C08J2379/04 ,  C08J2481/06 ,  C08L63/00 ,  C08L79/02 ,  C08L2203/12 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2207/04 ,  C08L81/06 ,  C08L81/04 ,  C08L63/04

Abstract: The embodiments herein relate to a benzoxazine resin composition, a prepreg, and a carbon fiber-reinforced composite material. More specifically, the embodiments herein relate to a benzoxazine resin composition that provides a carbon fiber-reinforced composite material that is suitable for use as a manufacture material due to its superior mechanical strength in extreme use environments, such as high temperature and high moisture, as well as a prepreg, and a carbon fiber-reinforced composite material. An embodiment comprises a benzoxazine resin composition having a multifunctional benzoxazine resin; a multifunctional epoxy resin that is a liquid at 40°C and has three or more glycidyl groups; a sulfonate ester; and optionally at least one thermoplastic resin. The resin may include an interpenetrating network structure after curing.

Abstract translation: 本文的实施方案涉及苯并恶嗪树脂组合物，预浸料和碳纤维增强复合材料。 更具体地说，本文的实施方案涉及苯并恶嗪树脂组合物，其提供适用于制造材料的碳纤维增强复合材料，因为其在极端使用环境（例如高温和高湿度）下具有优异的机械强度，如 以及预浸料，以及碳纤维增强复合材料。 一个实施方案包括具有多官能苯并恶嗪树脂的苯并恶嗪树脂组合物; 在40℃下为液体并具有三个以上缩水甘油基的多官能环氧树脂; 磺酸酯; 和任选的至少一种热塑性树脂。 树脂可以在固化后包括互穿网络结构。