公开(公告)号：WO2012066572A2

公开(公告)日：2012-05-24

申请号：PCT/IN2011/000793

申请日：2011-11-16

Applicant: INDIAN OIL CORPORATION LTD. ,  KUMAR, Sarvesh ,  SHARMA, Alok ,  KIMAR, Brijesh ,  CHOPRA Dr. Anju ,  RAJAGOPAL, Santnam ,  MALHOTRA, Ravinder, Kumar

Inventor： KUMAR, Sarvesh ,  SHARMA, Alok ,  KIMAR, Brijesh ,  CHOPRA Dr. Anju ,  RAJAGOPAL, Santnam ,  MALHOTRA, Ravinder, Kumar

CPC classification number: C10G67/06 ,  C10G19/02 ,  C10G25/00 ,  C10G27/06 ,  C10G45/02 ,  C10G45/32 ,  C10G61/08 ,  C10G65/043 ,  C10G65/06 ,  C10G65/16 ,  C10G67/00 ,  C10G67/0427 ,  C10G67/10 ,  C10G67/14 ,  C10G67/16 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/305 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/02

Abstract: The present invention provides a process for deep desulphurization of cracked gasoline with minimum octane loss of about 1-2 units. In this process full range cracked gasoline from FCC, Coker, Visbreaker etc is sent to Diolefin Saturation Reactor for selective saturation of diolefins. After saturation of diolefins, the stream is sent to Splitter for splitting into three cuts i.e Light Cut (IBP-70°C), Intermediate Cut (70 - 90°C) and Heavy Cut (90 -210°C). The Light Cut which contains majority of the high octane olefins and mercaptan sulfur is desulfurized with caustic treatment using Continuous Film Contactor (CFC). The sulfur in the Intermediate Cut is also predominantly mercaptans and the cut can be desulfurised by caustic treatment using CFC along with Light cut or separately desulfurised before being sent for isomerization. The Heavy Cut containing mainly thiophinic sulfur compounds is treated either by using conventional HDS process or reactive adsorption process.

Abstract translation: 本发明提供了一种使裂化汽油深度脱硫的方法，其中辛烷的最小损失量为约1-2个单位。 在这个过程中，来自FCC，Coker，Visbreaker等的全系列裂化汽油被送往Diolefin饱和反应器，以选择性饱和二烯烃。 在二烯烃饱和后，将该物流送至分离器以分裂成三个切口，即轻切（IBP-70℃），中切（70-90℃）和重切（90-210℃）。 包含大部分高辛烷值烯烃和硫醇硫的轻馏分使用连续膜接触器（CFC）通过苛性碱处理进行脱硫。 中间馏分中的硫也主要是硫醇，并且可以在送去异构化之前使用CFC和轻馏分或单独脱硫通过苛性处理将馏分脱硫。 主要含有硫代硫化合物的重馏分采用传统的HDS工艺或反应吸附工艺进行处理。

公开(公告)号：WO2002102940A1

公开(公告)日：2002-12-27

申请号：PCT/US2002/018901

申请日：2002-06-14

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  MERICHEM COMPANY

Inventor： GREANEY, Mark, A. ,  LE, Binh, N. ,  LETA, Daniel, P. ,  BEGASSE, John, N. ,  HUANG, Charles, T. ,  TURNER, Verlin, Keith

IPC: C10G67/10

CPC classification number: C10G19/04 ,  C10G19/02 ,  C10G19/08 ,  C10G21/06 ,  C10G21/08 ,  C10G21/28 ,  C10G45/02 ,  C10G67/04 ,  C10G67/10 ,  C10G67/12 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2400/02

Abstract: The invention relates to a method for desulfurizing naphtha boiling-range hydrocarbons such as cracked naphtha. More particularly, the invention relates to hydrotreating the naphtha under selective hydrotreating conditions, and then removing mercaptans from the hydrotreater effluent using a caustic extractant.

Abstract translation: 本发明涉及石脑油沸点烃类脱硫石脑油脱硫方法。 更具体地，本发明涉及在选择性加氢处理条件下加氢处理石脑油，然后使用苛性萃取剂从加氢处理器流出物中除去硫醇。

公开(公告)号：WO2014051944A1

公开(公告)日：2014-04-03

申请号：PCT/US2013/058113

申请日：2013-09-05

Applicant: UOP LLC

Inventor： BANERJEE, Soumendra, Mohan ,  VARADARAJAN, Srinivasa, Gopalan-Rajan ,  PANCHAPAKESAN, Rajaraman ,  BALAKRISHNAN, Babu

IPC: C10G19/02 ,  C10G45/02

CPC classification number: C10G19/00 ,  B01D3/143 ,  C10G21/16 ,  C10G21/20 ,  C10G53/12 ,  C10G67/04 ,  C10G67/10

Abstract: One exemplary embodiment can be a process for removing hydrogen sulfide from a fractionated hydroprocessed effluent. The process can include stripping a hydroprocessed effluent from a hydroprocessing zone, fractionating the stripped hydroprocessed effluent to obtain a naphtha cut, and sending the naphtha cut to a hydrogen sulfide removal zone. The hydrogen sulfide removal zone can include an amine wash settler, an amine contacting column, or a steam stripper.

Abstract translation: 一个示例性实施方案可以是从分馏的加氢处理流出物中除去硫化氢的方法。 该方法可以包括从加氢处理区中除去加氢处理的流出物，对汽提的加氢处理流出物进行分馏以获得石脑油馏分，并将石脑油馏分送入硫化氢去除区。 硫化氢去除区可以包括胺洗涤沉淀器，胺接触塔或蒸汽汽提器。

公开(公告)号：WO2005019387A1

公开(公告)日：2005-03-03

申请号：PCT/US2004/024832

申请日：2004-08-03

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  STUNTZ, Gordon, F.

Inventor： STUNTZ, Gordon, F.

IPC: C10G29/00

CPC classification number: C10G67/12 ,  C10G29/205 ,  C10G45/08 ,  C10G67/10 ,  C10G69/123

Abstract: Naphtha streams, preferably cracked naphtha streams containing both olefinic compounds and mercaptans, are first treated to convert at least a portion of the mercaptans to disulfides followed by thiophene alkylation. This results in a sufficient change in boiling range to allow for separation of at least a portion of the alkylated sulfur species and disulfides from the light naphtha. This results in a low sulfur light naphtha stream with little loss in octane number.

Abstract translation: 首先处理含有烯烃化合物和硫醇的裂解石脑油流的石脑油流，将至少一部分硫醇转化为二硫化物，然后进行噻吩烷基化。 这导致沸程的充分变化，使得至少一部分烷基化硫物质和二硫化物与轻石脑油分离。 这导致低硫辛烷值的少量的轻质石脑油流。

公开(公告)号：WO2002102936A1

公开(公告)日：2002-12-27

申请号：PCT/US2002/018840

申请日：2002-06-14

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  MERICHEM COMPANY

Inventor： GREANEY, Mark, A. ,  LE, Binh, N. ,  LETA, Daniel, P. ,  BEGASSE, John, N. ,  HUANG, Charles, T. ,  TURNER, Verlin, Keith

IPC: C10G19/02

CPC classification number: C10G19/04 ,  C10G19/02 ,  C10G19/08 ,  C10G21/06 ,  C10G21/08 ,  C10G21/28 ,  C10G45/02 ,  C10G67/04 ,  C10G67/10 ,  C10G67/12 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2400/02

Abstract: The invention relates to a method for treating and upgrading a hydrocarbon containing acidic species such as mercaptans, comprising: (a) contacting the hydrocarbon, in the essential absence of oxygen, with a first phase of a treatment composition containing water, dissolved alkali metal hydroxide, cobalt phthalocyanine sulfonate, and dissolved alkylphenylates and having at least two phases, (i) the first phase containing water, alkali metal alkylphenylate, dissolved alkali metal hydroxide, and dissolved sulfonated cobalt phthalocyanine, and (ii) the second phase containing wate r and dissolved alkali metal hydroxide; and then (b) separating an upgraded hydrocarbon.

Abstract translation: 本发明涉及一种用于处理和升级含有酸性物质如硫醇的烃的方法，其包括：（a）在基本不存在氧的情况下使烃与第一相接触，所述处理组合物含有水，溶解的碱金属氢氧化物 ，钴酞菁磺酸盐和溶解的烷基苯基化物，并且具有至少两相，（i）第一相含有水，碱金属烷基苯基盐，溶解的碱金属氢氧化物和溶解的磺化钴酞菁，和（ii）含有第二相的水分r和 溶解碱金属氢氧化物; 然后（b）分离升级的烃。

公开(公告)号：WO2017141097A1

公开(公告)日：2017-08-24

申请号：PCT/IB2017/000101

申请日：2017-02-13

Applicant: NA+S GMBH

Inventor： HÖLSCHER, Christian ,  SEIKEL, Klaus ,  BILGER, Edgar

IPC: C10G19/073 ,  C10G29/04

CPC classification number: C10G19/073 ,  C10G29/04 ,  C10G67/02 ,  C10G67/10 ,  C10G2300/202

Abstract: Ein Verfahren zur Entschwefelung eines organische Schwefelverbindungen enthaltenden Kohlenwasserstoffgemisches, umfasst die folgenden Schritte: a) Herstellen einer Natriumdispersion b) Zugabe der Natriumdispersion zu dem zu entschwefelnden Kohlenwasserstoffgemisch c) Durchleiten der Mischung aus Natriumdispersion und Kohlenwasserstoffgemisch durch einen Reaktor, wobei die Reaktionsbedingungen, insbesondere Druck und Temperatur so gewählt sind, dass es zu einer Reaktion des Natriums mit den organischen Schwefelverbindungen kommt, bei der Schwefelatome aus den organischen Schwefelverbindungen herausgelöst werden und sich mit dem Natrium verbinden. Der Reaktor ist ein turbulent durchströmter Reaktor, bevorzugt ein Rohrreaktor oder ein oszillierender Pfropfen reaktor mit innenliegender Transportschnecke.

Abstract translation:

烃混合物A用于有机含硫化合物的脱硫方法，其包括以下步骤：a）制备的分散体钠b）加入钠分散到脱硫烃混合物C）使分散钠和碳氢化合物的混合物的混合物通过反应器 其中选择反应条件，特别是压力和温度，使得钠与有机硫化合物反应，其中硫原子从有机硫化合物中浸出并与钠结合。 反应器是湍流流过式反应器，优选管式反应器或具有内部运输螺杆的振荡式活塞流反应器。

公开(公告)号：WO2007008464A1

公开(公告)日：2007-01-18

申请号：PCT/US2006/025724

申请日：2006-06-29

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  ELLIS, Edward, S. ,  HALBERT, Thomas, R. ,  STUNTZ, Gordon, F.

Inventor： ELLIS, Edward, S. ,  HALBERT, Thomas, R. ,  STUNTZ, Gordon, F.

IPC: C10G75/00 ,  C10G67/06 ,  C10G67/10 ,  B01J35/10 ,  C10G45/08

CPC classification number: C10G25/00 ,  B01J23/882 ,  B01J35/002 ,  B01J35/1061 ,  B01J37/20 ,  C10G19/02 ,  C10G45/08 ,  C10G67/06 ,  C10G67/10 ,  C10G2400/02

Abstract: This invention relates to a process for selectively desulfurizing naphtha. More particularly, a low sulfur naphtha feed containing less than 500 wppm sulfur is hydrodesulfurized using a hydrodesulfurization catalyst and a hydrogen treat gas containing at least 50 vppm hydrogen sulfide followed by mercaptan removal or conversion.

Abstract translation: 本发明涉及一种选择性脱硫石脑油的方法。 更具体地说，含有少于500wppm硫的低硫石脑油原料使用加氢脱硫催化剂和含有至少50vppm硫化氢的氢处理气体进行加氢脱硫，随后除去硫醇或转化。

公开(公告)号：WO2002102935A1

公开(公告)日：2002-12-27

申请号：PCT/US2002/018839

申请日：2002-06-14

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  MERICHEM COMPANY

Inventor： GREANEY, Mark, A. ,  LE, Binh, N. ,  LETA, Daniel, P. ,  BEGASSE, John, N. ,  HUANG, Charles, T. ,  TURNER, Verlin, Keith

IPC: C10G19/02

CPC classification number: C10G19/04 ,  C10G19/02 ,  C10G19/08 ,  C10G21/06 ,  C10G21/08 ,  C10G21/28 ,  C10G45/02 ,  C10G67/04 ,  C10G67/10 ,  C10G67/12 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2400/02

Abstract: The invention relates to a method for treating and upgrading a hydrocarbon containing acidic species such as mercaptans, comprising: (a) contacting the hydrocarbon, in the essential absence of oxygen, with a first phase of a treatment composition containing water, dissolved alkali metal hydroxide, cobalt phthalocyanine sulfonate, and dissolved alkylphenylates and having at least two phases, (i) the first phase containing water, alkali metal alkylphenylate, dissolved alkali metal hydroxide, and dissolved sulfonated cobalt phthalocyanine, and (ii) the second phase containing water and dissolved alkali metal hydroxide; and then (b) separating an upgraded hydrocarbon.

Abstract translation: 本发明涉及一种用于处理和升级含有酸性物质如硫醇的烃的方法，其包括：（a）在基本不存在氧的情况下使烃与第一相接触，所述处理组合物含有水，溶解的碱金属氢氧化物 ，钴酞菁磺酸盐和溶解的烷基苯基酯，并且具有至少两相，（i）第一相含有水，碱金属烷基苯基酯，溶解的碱金属氢氧化物和溶解的磺化钴酞菁，和（ii）含有水和溶解的第二相 碱金属氢氧化物; 然后（b）分离升级的烃。

公开(公告)号：WO2012066572A3

公开(公告)日：2012-07-26

申请号：PCT/IN2011000793

申请日：2011-11-16

Applicant: INDIAN OIL CORP LTD ,  KUMAR SARVESH ,  SHARMA ALOK ,  KIMAR BRIJESH ,  CHOPRA DR ANJU ,  RAJAGOPAL SANTNAM ,  MALHOTRA RAVINDER KUMAR

Inventor： KUMAR SARVESH ,  SHARMA ALOK ,  KIMAR BRIJESH ,  CHOPRA DR ANJU ,  RAJAGOPAL SANTNAM ,  MALHOTRA RAVINDER KUMAR

IPC: C10G67/04 ,  C10G25/00 ,  C10G27/06 ,  C10G45/32 ,  C10G67/06 ,  C10G67/10 ,  C10G67/14

CPC classification number: C10G67/06 ,  C10G19/02 ,  C10G25/00 ,  C10G27/06 ,  C10G45/02 ,  C10G45/32 ,  C10G61/08 ,  C10G65/043 ,  C10G65/06 ,  C10G65/16 ,  C10G67/00 ,  C10G67/0427 ,  C10G67/10 ,  C10G67/14 ,  C10G67/16 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/305 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/02

Abstract: The present invention provides a process for deep desulphurization of cracked gasoline with minimum octane loss of about 1-2 units. In this process full range cracked gasoline from FCC, Coker, Visbreaker etc is sent to Diolefin Saturation Reactor for selective saturation of diolefins. After saturation of diolefins, the stream is sent to Splitter for splitting into three cuts i.e Light Cut (IBP-70°C), Intermediate Cut (70 - 90°C) and Heavy Cut (90 -210°C). The Light Cut which contains majority of the high octane olefins and mercaptan sulfur is desulfurized with caustic treatment using Continuous Film Contactor (CFC). The sulfur in the Intermediate Cut is also predominantly mercaptans and the cut can be desulfurised by caustic treatment using CFC along with Light cut or separately desulfurised before being sent for isomerization. The Heavy Cut containing mainly thiophinic sulfur compounds is treated either by using conventional HDS process or reactive adsorption process.

Abstract translation: 本发明提供一种以约1-2单位的最小辛烷值损失深度脱硫裂化汽油的方法。 在这个过程中，将FCC，Coker，Visbreaker等全系列裂化汽油送至二烯烃饱和反应器，以选择性饱和二烯烃。 饱和二烯烃后，将该流送至分离器分解成三个切割，即切割（IBP-70℃），中间切割（70-90℃）和重切割（90-210℃）。 含有大部分高辛烷值烯烃和硫醇硫的轻馏分用连续膜接触器（CFC）进行苛性碱处理脱硫。 中间馏分中的硫也主要是硫醇，切割可以通过苛性碱处理，使用CFC和轻馏分或单独脱硫进行脱硫，然后进行异构化。 含有主要硫代硫代硫化合物的重馏分是通过使用常规的HDS法或反应性吸附法来处理的。

公开(公告)号：WO2006039125A1

公开(公告)日：2006-04-13

申请号：PCT/US2005/033282

申请日：2005-09-16

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  DYSARD, Jeffrey, M. ,  HOU, Zhiguo ,  McCONNACHIE, Jonathan, M. ,  MALEK, Andrzej ,  GUPTA, Ramesh ,  LEWIS, William, E.

Inventor： DYSARD, Jeffrey, M. ,  HOU, Zhiguo ,  McCONNACHIE, Jonathan, M. ,  MALEK, Andrzej ,  GUPTA, Ramesh ,  LEWIS, William, E.

IPC: C10G19/073 ,  C10G29/04 ,  C10G45/02 ,  C10G65/04 ,  C10G67/10

CPC classification number: C10G45/02 ,  C10G19/073 ,  C10G29/04 ,  C10G65/04 ,  C10G67/10

Abstract: Refractory or hard sulfur found in a hydrocarbon stream containing refractory sulfur heterocycle compounds, particularly those exhibiting steric hindrance, is removed from the stream by contacting it with a sodium reagent comprising a sodium component, having free sodium, supported on a solid support component. If the hydrocarbon stream contains more labile or easy sulfur, then it is treated, typically by hydrodesulfurization, to remove at least most of the labile sulfur before it is contacted with the sodium reagent. This is useful for bringing the sulfur level of middle distillate fuel streams, such as diesel and jet fuel fractions, down to a level of less than 10 wppm, employing conventional hydrodesulfurizing catalysts and conditions.

Abstract translation: 在含有难溶性硫杂环化合物的烃流中，特别是那些表现出空间位阻的烃流中发现的耐火或硬硫通过与包含负载在固体支持组分上的具有游离钠的钠组分的钠试剂接触而从流中除去。 如果烃流含有更多的不稳定或易硫化物，则通常通过加氢脱硫处理，以便在与钠试剂接触之前至少除去大部分不稳定的硫。 这对于使用常规的加氢脱硫催化剂和条件将中等馏出物燃料流（例如柴油和喷气燃料馏分）的硫含量降低到低于10wppm的水平是有用的。