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    IONIC LIQUIDS AND IONIC LIQUID ACIDS WITH HIGH TEMPERATURE STABILITY FOR FUEL CELL AND OTHER HIGH TEMPERATURE APPLICATIONS, METHOD OF MAKING AND CELL EMPLOYING SAME
    2.
    发明申请
    IONIC LIQUIDS AND IONIC LIQUID ACIDS WITH HIGH TEMPERATURE STABILITY FOR FUEL CELL AND OTHER HIGH TEMPERATURE APPLICATIONS, METHOD OF MAKING AND CELL EMPLOYING SAME 审中-公开
    用于燃料电池和其他高温应用的具有高温稳定性的离子液体和离子液体酸，其制备方法和使用其的细胞

    公开(公告)号：WO2004114445A1

    公开(公告)日：2004-12-29

    申请号：PCT/US2004/013719

    申请日：2004-05-03

    Applicant: ARIZONA BOARD OF REGENTS a body corporate acting On behalf of ARIZONA STATE UNIVERSITY ,  ANGELL, C., Austen ,  XU, Wu ,  BELIERES, Jean-Philippe ,  YOSHIZAWA, Masahiro

    Inventor： ANGELL, C., Austen ,  XU, Wu ,  BELIERES, Jean-Philippe ,  YOSHIZAWA, Masahiro

    IPC: H01M8/00

    CPC classification number: H01M8/144 ,  H01M8/1016 ,  H01M8/14 ,  H01M2300/0005 ,  H01M2300/0022 ,  H01M2300/0048 ,  H01M2300/0054 ,  H01M2300/0062 ,  H01M2300/0085 ,  H01M2300/0091 ,  Y02P70/56

    Abstract: Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H 2 (g)electrolyte/O 2 (g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200°C are achieved. Both neutral proton transfer salts and the acid salts with HSO - 4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pK a value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.

    Abstract translation: 公开了高温燃料电池的发展，包括具有高温稳定性的离子液体和无机酸作为低挥发性的二阴离子盐的储存。 描述了具有前所未有的非水系统电导率的这种离子导电液体的形成。 二阴离子配置的稳定性显示出在非腐蚀性质子转移离子液体作为高温燃料电池电解质的高性能中起作用。 描述了具有新电解质的简单H 2（g）电解质/ O 2（g）燃料电池的性能。 在环境温度和高于和高于200℃的温度下都能实现卓越的性能。 两种中性质子转移盐和与HSO 4阴离子的酸式盐都能获得良好的结果，硫酸氢盐的情况在低温和非常高的温度下特别好。 所有电解质的性能通过在制造本体电解质的酸和碱之间添加少量pKa值的非挥发性碱而提高。 优选的情况是咪唑掺杂的硫酸氢铵，其产生的行为在所有方面都优于工业标准磷酸电解质。

    IONIC LIQUIDS AND IONIC LIQUID ACIDS WITH HIGH TEMPERATURE STABILITY FOR FUEL CELL AND OTHER HIGH TEMPERATURE APPLICATIONS, METHOD OF MAKING AND CELL EMPLOYING SAME
    4.
    发明申请
    IONIC LIQUIDS AND IONIC LIQUID ACIDS WITH HIGH TEMPERATURE STABILITY FOR FUEL CELL AND OTHER HIGH TEMPERATURE APPLICATIONS, METHOD OF MAKING AND CELL EMPLOYING SAME 审中-公开
    用于燃料电池和其他高温应用的具有高温稳定性的离子液体和离子液体酸，其制备方法和使用其的细胞

    公开(公告)号：WO2004114445B1

    公开(公告)日：2005-02-10

    申请号：PCT/US2004013719

    申请日：2004-05-03

    Applicant: UNIV ARIZONA STATE ,  ANGELL C AUSTEN ,  XU WU ,  BELIERES JEAN-PHILIPPE ,  YOSHIZAWA MASAHIRO

    Inventor： ANGELL C AUSTEN ,  XU WU ,  BELIERES JEAN-PHILIPPE ,  YOSHIZAWA MASAHIRO

    IPC: H01M8/00 ,  H01M8/10 ,  H01M8/14

    CPC classification number: H01M8/144 ,  H01M8/1016 ,  H01M8/14 ,  H01M2300/0005 ,  H01M2300/0022 ,  H01M2300/0048 ,  H01M2300/0054 ,  H01M2300/0062 ,  H01M2300/0085 ,  H01M2300/0091 ,  Y02P70/56

    Abstract: Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H2(g)electrolyte/O2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200°C are achieved. Both neutral proton transfer salts and the acid salts with HSO 4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pKa value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.

    Abstract translation: 公开了高温燃料电池的发展，包括具有高温稳定性的离子液体和无机酸作为低挥发性的二阴离子盐的储存。 描述了具有前所未有的非水系统电导率的这种离子导电液体的形成。 显示出二阴离子构型的稳定性在高腐蚀性质子转移离子液体作为高温燃料电池电解质的高性能中起作用。 描述了具有新电解质的简单H 2（g）电解质/ O 2（g）燃料电池的性能。 在环境温度和高于和高于200℃的温度下都能实现卓越的性能。 两种中性质子转移盐和具有HSO 4阴离子的酸式盐都具有良好的结果，硫酸氢盐的情况在低温和非常高的温度下特别好。 通过在制造大容量电解质的酸和碱之间添加少量pKa值的非挥发性碱，提高了所有电解质的性能。 优选的情况是咪唑掺杂的硫酸氢铵，其产生在所有方面优于工业标准磷酸电解质的行为。

    LITHIUM-AIR BATTERY FOR ELECTRIC VEHICLES AND OTHER APPLICATIONS USING MOLTEN NITRATE ELECTROLYTES
    5.
    发明申请
    LITHIUM-AIR BATTERY FOR ELECTRIC VEHICLES AND OTHER APPLICATIONS USING MOLTEN NITRATE ELECTROLYTES 审中-公开
    电动汽车用锂离子电池及其他使用硝酸锂电解质的应用

    公开(公告)号：WO2014165068A1

    公开(公告)日：2014-10-09

    申请号：PCT/US2014/024288

    申请日：2014-03-12

    Applicant: MILES, Melvin, H.

    Inventor： MILES, Melvin, H.

    IPC: H01M4/131

    CPC classification number: H01M12/02 ,  H01M2/1646 ,  H01M4/382 ,  H01M12/08 ,  H01M2220/20 ,  H01M2300/0062 ,  Y02E60/128

    Abstract: A optionally rechargeable molten nitrate electrolyte battery having an anode comprising lithium, a cathode substrate comprising a conductive metal that is compatible with the nitrate melt, an electrolyte comprising lithium nitrate or lithium nitrate mixtures with other nitrates which is capable of becoming an ionic conductive liquid upon being heated above its melting point, a source of oxygen to provide oxygen for reaction at the cathode or within the melt wherein the oxygen is introduced into the battery through the electrolyte.

    Abstract translation: 一种具有包含锂的阳极的可选择地可再充电的熔融硝酸盐电解质电池，包含与硝酸盐熔体相容的导电金属的阴极衬底，包含硝酸锂或硝酸锂混合物的电解质，其能够成为离子导电液体 被加热到高于其熔点的氧气源，以在阴极或熔体内提供氧气用于反应，其中通过电解质将氧气引入电池中。

    ALKALI METAL/OXYGEN BATTERIES EMPLOYING MOLTEN NITRATE ELECTROLYTES
    6.
    发明申请
    ALKALI METAL/OXYGEN BATTERIES EMPLOYING MOLTEN NITRATE ELECTROLYTES 审中-公开
    使用硝酸镍电解质的碱性金属/氧气电池

    公开(公告)号：WO2014153551A1

    公开(公告)日：2014-09-25

    申请号：PCT/US2014/031516

    申请日：2014-03-21

    Applicant: LIOX POWER, INC.

    Inventor： UDDIN, Jasim ,  ADDISON, Dan, D. ,  GIORDANI, Vincent ,  CHASE, Gregory, V. ,  WALKER, Wesley

    IPC: H01M8/22 ,  H01M4/36 ,  H01M4/88

    CPC classification number: H01M12/08 ,  H01M4/134 ,  H01M4/366 ,  H01M4/381 ,  H01M4/8605 ,  H01M10/0562 ,  H01M12/06 ,  H01M2300/0062

    Abstract: High capacity alkali metal/oxygen batteries, e.g. Li/O 2 batteries, employing molten salt electrolytes comprising alkali metal cations and nitrate anions are disclosed. Batteries of the present invention operate at an intermediate temperature ranging from 80° C to 250° C. Molten alkali metal nitrate electrolytes employed in O 2 electrodes within this temperature range provide alkali metal/oxygen batteries having significantly improved efficiency and rechargeability compared to prior art systems.

    Abstract translation: 高容量碱金属/氧气电池，例如 公开了使用包含碱金属阳离子和硝酸根阴离子的熔盐电解质的Li / O 2电池。 本发明的电池在80℃至250℃的中间温度下操作。在该温度范围内在O 2电极中使用的熔融碱金属硝酸盐电解质提供了与现有技术系统相比显着提高的效率和再充电能力的碱金属/氧电池 。

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